天津地区表土PAHs含量的多尺度空间相关性

本文应用因子克立格分析方法,分析了天津表土16种PAHs之间多尺度空间结构特征。分析结果显示,天津表土PAHs在空间上可以划分三种尺度:块金尺度(0～5km),小空间尺度(5～10km)和大空间尺度(10～50km)。在不同的空间尺度上,16种PAHs之间表现出不同的空间相关性,具有空间尺度相关性。这种空间尺度相关性,是由于不同的空间污染过程造成的,有助于下一步的多尺度空间污染源的判断和污染物迁移转化规律的识别。     

Plio-Pleistocene mammals from Mille-Logya,Ethiopia, and the post-Hadar faunal change

We describe the non-primate mammalian fauna from the late Pliocene to earliest Pleistocene deposits of Mille-Logya in the Lower Awash Valley, Ethiopia, dated to c. 2.9–2.4 Ma, and divided into three successive units: Gafura, Seraitu, and Uraitele. We identify 41 mammalian taxa (including rodents), the most diverse group being the Bovidae, with 17 taxa. While the Gafura assemblage still resembles those from the earlier Hadar Formation, the younger Seraitu assemblage documents a major turnover. While there is little change in the species present across this interval, the relative abundances of various taxa change dramatically, with suids being largely replaced by open-country bovids (Alcelaphini and Antilopini). We interpret this faunal change as reflective of an environmental shift, contemporaneous with the replacement of Australopithecus afarensis by Homo in the area.     

The influence of coupled physical swelling and chemical reactions on deformable geomaterials

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.     

Three‐dimensional shakedown solutions for anisotropic cohesive‐frictional materials under moving surface loads

Previous work on three‐dimensional shakedown analysis of cohesive‐frictional materials under moving surface loads has been entirely for isotropic materials. As a result, the effects of anisotropy, both elastic and plastic, of soil and pavement materials are ignored. This paper will, for the first time, develop three‐dimensional shakedown solutions to allow for the variation of elastic and plastic material properties with direction. Melan's lower‐bound shakedown theorem is used to derive shakedown solutions. In particular, a generalised, anisotropic Mohr–Coulomb yield criterion and cross‐anisotropic elastic stress fields are utilised to develop anisotropic shakedown solutions. It is found that shakedown solutions for anisotropic materials are dominated by Young's modulus ratio for the cases of subsurface failure and by shear modulus ratio for the cases of surface failure. Plastic anisotropy is mainly controlled by material cohesion ratio, the rise of which increases the shakedown limit until a maximum value is reached. The anisotropic shakedown limit varies with frictional coefficient, and the peak value may not occur for the case of normal loading only. Copyright © 2013 John Wiley & Sons, Ltd.     

Varying water utilization of Haloxylon ammodendron plantations in a desert‐oasis ecotone

Haloxylon ammodendron is a desert shrub used extensively in China for restoring degraded dry lands. An understanding of the water source used by H. ammodendron plantations is critical achieving sustainable vegetation restoration. We measured mortality, shoot size, and rooting depth in 5‐, 10‐, 20‐, and 40‐year‐old H. ammodendron plantations. We examined stable isotopic ratios of oxygen (δ¹⁸O) in precipitation, groundwater, and soil water in different soil layers and seasons, and in plant stem water to determine water sources at different shrub ages. We found that water acquisition patterns in H. ammodendron plantations differed with plantation age and season. Thus, the main water source for 5‐year‐old shrubs was shallow soil water. Water sources of 10‐year‐old shrubs shifted depending on the soil water conditions during the season. Although their tap roots could absorb deep soil water, the plantation main water sources were from soil water, and about 50% of water originated from shallow and mid soil. This pattern might occur because main water sources in these plantations were changeable over time. The 20‐ and 40‐year‐old shrubs acquired water mainly from permanent groundwater. We conclude that the main water source of a young H. ammodendron plantation was soil water recharged by precipitation. However, when roots reached sufficient depth, water originated mainly from the deep soil water, especially in the dry season. The deeply rooted 20‐ and 40‐year‐old shrubs have the ability to exploit a deep and reliable water source. To achieve sustainability in these plantations, we recommend a reduction in the initial density of H. ammodendron in the desert‐oasis ecotone to decelerate the consumption of shallow soil water during plantation establishment.     

δ18O and δ13C in fossil shells of Radix sp. from the sediment succession of a dammed palaeo‐lake in the Yarlung Tsangpo valley,Tibet, China

A series of confirmed and suspected dammed palaeo‐lake sedimentary successions is scattered within the middle Yarlung Tsangpo valley in Tibet. However, the chronology, the genesis of the dam and its location, the water level of the dammed lake, the process of dam failure and the spatiotemporal relationships between the sedimentary successions remain controversial. Here, we focus on one sedimentary succession of the suspected dammed palaeo‐lake at Xigazê. We measured the grain‐size distribution, magnetic susceptibility, organic and inorganic carbon content, and δ¹³C_org and δ¹⁵N_total ratios of the sediments. In addition, we measured the δ¹⁸O_shell and δ¹³C_shell values of modern and fossil Radix sp. shells, and the δ¹⁸O_water and δ¹³C_DIC values of the ambient water with different hydrological regimes. The results indicate that the δ¹⁸O_shell values of modern Radix sp. and the δ¹⁸O_water of the ambient water body significantly depend on its hydrological status. In addition, a strong positive relationship was observed between δ¹⁸O_shell values of modern Radix sp. shells and the δ¹⁸O_water of the ambient water on the Tibetan Plateau. According to this correlation, the δ¹⁸O_water values of the palaeo‐water body are reconstructed using the δ¹⁸O_shell values of Radix sp. fossil shells in the Xigazê section. Further, based on the δ¹⁸O_shell values of fossil Radix sp., the reconstructed δ¹⁸O_water of the palaeo‐water body and the specific habitats of Radix sp., we infer that the sedimentary succession in the Xigazê broad valley was mainly formed within the backwater terminal zone of a dammed palaeo‐lake and that the elevation of the water level of the lake was approximately 3811 m a.s.l. AMS ¹⁴C dating indicates that the deposits of the dammed palaeo‐lake were formed at about 33–22 cal. ka BP. Finally, the presence of Radix sp. fossil shells within the Xigazê section suggests that Radix sp. survived the late Last Glacial Period on the Tibetan Plateau.     

Modelling and experimental study of coupled exchange of p,p′‐DDE and colloids in a flume simulated stream–streambed system

Stream–subsurface exchange plays a significant role in the fate and transport of contaminants in streams. It has been modelled explicitly by considering fundamental processes such as hydraulic exchange, colloid filtration, and contaminant interactions with streambed sediments and colloids. The models have been successfully applied to simulate the transport of inorganic metals and nutrients. In this study, laboratory experiments were conducted in a recirculating flume to investigate the exchange of a hydrophobic organic contaminant, p,p′‐dichloro‐diphenyl‐dichloroethane (DDE), between a stream and a quartz sand bed. A previously developed process‐based multiphase exchange model was modified by accounting for the p,p′‐DDE kinetic adsorption to and desorption from the bed sediments/colloids and was applied to interpret the experimental results. Model input parameters were obtained by conducting independent small‐scale batch experiments. Results indicate that the immobilization of p,p′‐DDE in the quartz sand bed can occur under representative natural stream conditions. The observed p,p′‐DDE exchange was successfully simulated by the process‐based model. The model sensitivity analysis results show that the exchange of p,p′‐DDE can be sensitive to either the sediment sorption/desorption parameters or colloidal parameters depending on the experimental conditions tested. For the experimental conditions employed here, the effect of colloids on contaminant transport is expected to be minimal, and the stream–subsurface exchange of p,p′‐DDE is dominated by the interaction of p,p′‐DDE with bed sediment. The work presented here contributes to a better mechanistic understanding of the complex transport process that hydrophobic organic contaminants undergo in natural streams and to the development of reliable, predictive models for the assessment of impacted streams. Copyright © 2015 John Wiley & Sons, Ltd.     

A new standardized Palmer drought index for hydro‐meteorological use

Accepting the concept of standardization introduced by the standardized precipitation index, similar methodologies have been developed to construct some other standardized drought indices such as the standardized precipitation evapotranspiration index (SPEI). In this study, the authors provided deep insight into the SPEI and recognized potential deficiencies/limitations in relating to the climatic water balance it used. By coupling another well‐known Palmer drought severity index (PDSI), we proposed a new standardized Palmer drought index (SPDI) through a moisture departure probabilistic approach, which allows multi‐scalar calculation for accurate temporal and spatial comparison of the hydro‐meteorological conditions of different locations. Using datasets of monthly precipitation, temperature and soil available water capacity, the moisture deficit/surplus was calculated at multiple temporal scales, and a couple of techniques were adopted to adjust corresponding time series to a generalized extreme value distribution out of several candidates. Results of the historical records (1900–2012) for diverse climates by multiple indices showed that the SPDI was highly consistent and correlated with the SPEI and self‐calibrated PDSI at most analysed time scales. Furthermore, a simple experiment of hypothetical temperature and/or precipitation change scenarios also verified the effectiveness of this newly derived SPDI in response to climate change impacts. Being more robust and preferable in spatial consistency and comparability as well as combining the simplicity of calculation with sufficient accounting of the physical nature of water supply and demand relating to droughts, the SPDI is promising to serve as a competent reference and an alternative for drought assessment and monitoring. Copyright © 2013 John Wiley & Sons, Ltd.     

A two‐dimensional coupled hydromechanical discontinuum model for simulating rock hydraulic fracturing

Within the framework of our discontinuous deformation analysis for rock failure algorithm, this paper presents a two‐dimensional coupled hydromechanical discontinuum model for simulating the rock hydraulic fracturing process. In the proposed approach, based on the generated joint network, the calculation of fluid mechanics is performed first to obtain the seepage pressure near the tips of existing cracks, and then the fluid pressure is treated as linearly distributed loads on corresponding block boundaries. The contribution of the hydraulic pressure to the initiation/propagation of the cracks is considered by adding the components of these blocks into the force matrix of the global equilibrium equation. Finally, failure criteria are applied at the crack tips to determine the occurrence of cracking events. Several verification examples are simulated, and the results show that this newly proposed numerical model can simulate the hydraulic fracturing process correctly and effectively. Although the numerical and experimental verifications focus on one unique preexisting crack, because of the capability of discontinuous deformation analysis in simulating block‐like structures, the proposed approach is capable of modeling rock hydraulic fracturing processes. Copyright © 2014 John Wiley & Sons, Ltd.