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滇西北保山核桃坪铅锌矿床成矿流体来源的同位素地球化学证据 总被引:11,自引:2,他引:9
滇西北核桃坪铅锌矿是保山地块内沿澜沧江断裂带发育的一个大型铅锌多金属矿床,矿体严格受近SN向的断裂带及层间破碎带控制,赋存于上寒武统核桃坪组和沙河厂组大理岩化灰岩及矽卡岩中。文章在分析矿床地质特征的基础上,通过对V1矿体的氢、氧、碳、硫、硅和铅同位素地球化学的示踪研究,探讨了成矿溶液中水、碳、硅、硫和铅的来源以及成矿流体的演化问题。研究表明,V1矿体中矿石的石英δ18O水值变化范围为6·1‰~7·6‰,平均为6·7‰,其δDV-SMOW值变化范围为-100‰~-108‰,平均为-104‰,说明成矿流体主要来自深部岩浆分异水,并在后期成矿作用过程中有地层建造水和大气降水的加入;矿石中方解石的δ13CV-PDB和δ18O水值分别为-6·6‰~-5·9‰和5·0‰~5·2‰,反映成矿流体的碳、氧具有深部流体与围岩发生交代反应的特征。硅、硫和铅同位素具深部岩浆或地幔来源的特点,但遭受后期壳源物质的混染。据此提出该矿床是与深部岩浆热液或幔源流体贯入有关的构造热液脉型矿床,其成矿作用受控于深部过程的驱动和控制,可为指导地质找矿提供依据。 相似文献
14.
云南官房铜矿床矿石矿物特征及银的赋存状态 总被引:1,自引:0,他引:1
通过显微镜鉴定、电子探针(EPMA)及扫描电镜能谱分析(SEM/EDS)等方法,首次对官房铜矿的矿物组合和银的赋存状态进行了研究。初步查明,矿石矿物为中-低温热液成因,并受火山机构及断裂构造的控制;银矿物主要为碲银矿和辉银矿。矿石中银与铜呈明显正相关关系,而方铅矿中不含银。银主要以类质同象的形式赋存于含铜矿物或黄铁矿中;银的独立矿物含量低,且多呈包裹体的形式存在于黄铜矿、斑铜矿及黄铁矿中,或以微细粒状赋存于矿物颗粒间和斑铜矿的表面。 相似文献
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Zhou Haiyan Zhou Xun Chai Rui Yu Lan Liu Chunhui Li Liangping 《Environmental Geology》2008,53(7):1483-1489
Thermal groundwater occurs in bedrock aquifers consisting of the dolomite of the Wumishan Group of the Jixianin System and
the Cambrian carbonate in the Xiaotangshan geothermal field near the northern margin of the North China Plain, China. The
hot water in the geothermal field of basin-type discharges partly in the form of the Xiaotangshan hot spring under natural
conditions. The hot water has TDS of less than 600 mg/L and is of Na·Ca-HCO3 type. The geothermal water receives recharge from precipitation in the mountain area with elevation of about 500 m above
sea level to the north of the spring. Thermal groundwater flows slowly south and southeast through a deep circulation with
a residence time of 224 years estimated with the Ra–Rn method. The Xiaotangshan hot spring dried up in the middle of the 1980s
owing to the increasing withdrawal of the hot water in the geothermal field in the past decades. The water level of the geothermal
system still falls continually at an annual average rate of about 2 m, although water temperature changes very little, indicating
that the recharge of such a geothermal system of basin-type is limited. Over-exploitation has a dramatic impact on the geothermal
system, and reduction in exploitation and reinjection are required for the sustainable usage of the hot water. 相似文献
16.
Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined
aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai
area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths
through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results
indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the
unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths. 相似文献
17.
Jos M. Marques Paula M. Carreira Maria Rosrio Carvalho Maria J. Matias Fraser E. Goff Maria J. Basto Rui C. Graa Luís Aires-Barros Luís Rocha 《Applied Geochemistry》2008,23(12):3278-3289
This paper reviews the geochemical, isotopic (2H, 18O, 13C, 3H and 14C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO3 type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ2H and δ18O suggest a common meteoric origin and that the Mg–HCO3 type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO3 to Mg–HCO3 waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO2 (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of 14C and 13C values, which is in agreement with the 3H concentrations being below the detection limit. 相似文献
18.
Li Miao Ruisong Xu Yueliang Ma Jinhong Xu Jie Wang Rui Cai Yu Chen 《Journal of Geochemical Exploration》2008,96(1):43-52
In the Hetai goldfield, Guangdong Province, China, samples including rocks, soils and leaves of four plants (Pinus massoniana, Rhodomyrms tomenlosa, D. linearis var. dichotoma and Embelia laeta) collected from the gold mineralization zone and the background area were analyzed for Au, Ag, Cu, Pb, Zn, Hg, As and physiological parameters. The objective of this investigation is to study the geochemical and biogeochemical characteristics of studied plants, aiming at biogeochemical methods in Au exploration. The goldfield region shows geochemical and biogeochemical anomalies. Abundances of Au in rocks, soils, plants and the leaf pigments in the mineralized area are much higher than those in the surrounding region. The plants display unhealthy physiological and ecological characteristics in the Hetai goldfield area. The cell structures of the goldfield plants were anomalous and aberrant, and there were many nano-metal particles diffused in mitochondria and chloroplasts. Macro- and microscopic evidences of the vegetation in the goldfield areas are distinctly different from the background regions. The strongly anomalies in responses to Au are profound in further geochemical and botanic exploration studies. 相似文献
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20.
西藏搭格架热泉型铯矿床矿物学与矿石组构特征及地质意义 总被引:5,自引:1,他引:4
在查明搭格架铯矿床产出的地质背景、成矿阶段及其年龄、地球化学与同位素组成的基础上,本文较为系统地研究了硅华的矿物学与组构特征,加深了对硅华形成演化过程的认识.研究表明成矿早期,矿石中存在大量的石英,晚期全为蛋白石.粒状蛋白石自早到晚均有出现,胶状蛋白石主要出现于晚期.早期矿石出现脱水造成的菜花状、粗粒块状与粗大孔隙状构造及溶蚀结构.晚期出现细粒块状与细小孔隙状构造.在第3阶段存在硅藻Denticula属,体现出低温阶段的特征.由早到晚,矿石的SiO2呈降低趋势,而(Na2O Al2O3 K2O CaO)与Cs2O呈升高趋势,是随着矿石中SiO2有序度的降低而其它成分被保留在晶格中所致. 相似文献