Development of Polymeric and Polymer‐Based Hybrid Adsorbents for Chromium Removal from Aqueous Solution

Ferric oxide‐loaded hybrid sorbents are environmentally benign and exhibit sorption behaviors for chromium removal from waters. In the current study, glycidyl methacrylate‐based polymer (GMD) and nanosized ferric oxide loaded glycidyl methacrylate‐based polymer (GMDFe) were prepared and assayed to examine the effect of ferric oxide loading on chromium sorption from aqueous solution for the first time from the equilibrium and kinetic points of view. The experimental equilibrium data, suitably fitted by the Langmuir and Freundlich isotherms, have shown that ferric oxide loaded hybrid sorbent exhibits higher adsorption capacity than glycidyl methacrylate‐based polymer (GMD). The Langmuir isotherm model was found to be the most suitable one for the Cr(VI) adsorption. The maximum adsorption capacities of GMD and GMDFe sorbents were determined at pH 4 as 109.54 and 157.52 mg/g, respectively. A series of column experiments was carried out to determine the breakthrough curves. The column was regenerated by eluting Cr(VI) using NaOH (10% w/v) solution after adsorption studies.     

Black carbon and chemical characteristics of PM<Subscript>10</Subscript> and PM<Subscript>2.5</Subscript> at an urban site of North India

The concentrations of PM₁₀, PM_2.5 and their water-soluble ionic species were determined for the samples collected during January to December, 2007 at New Delhi (28.63° N, 77.18° E), India. The annual mean PM₁₀ and PM_2.5 concentrations (± standard deviation) were about 219 (± 84) and 97 (±56) μgm⁻³ respectively, about twice the prescribed Indian National Ambient Air Quality Standards values. The monthly average ratio of PM_2.5/PM₁₀ varied between 0.18 (June) and 0.86 (February) with an annual mean of ∼0.48 (±0.2), suggesting the dominance of coarser in summer and fine size particles in winter. The difference between the concentrations of PM₁₀ and PM_2.5, is deemed as the contribution of the coarse fraction (PM_10−2.5). The analyzed coarse fractions mainly composed of secondary inorganic aerosols species (16.0 μgm⁻³, 13.07%), mineral matter (12.32 μgm⁻³, 10.06%) and salt particles (4.92 μgm⁻³, 4.02%). PM_2.5 are mainly made up of undetermined fractions (39.46 μgm⁻³, 40.9%), secondary inorganic aerosols (26.15 μgm⁻³, 27.1%), salt aerosols (22.48 μgm⁻³, 23.3%) and mineral matter (8.41 μgm⁻³, 8.7%). The black carbon aerosols concentrations measured at a nearby (∼300 m) location to aerosol sampling site, registered an annual mean of ∼14 (±12) μgm⁻³, which is significantly large compared to those observed at other locations in India. The source identifications are made for the ionic species in PM₁₀ and PM_2.5. The results are discussed by way of correlations and factor analyses. The significant correlations of Cl⁻, SO₄²⁻, K⁺, Na⁺, Ca²⁺, NO₃⁻ and Mg²⁺ with PM_2.5 on one hand and Mg²⁺ with PM₁₀ on the other suggest the dominance of anthropogenic and soil origin aerosols in Delhi.     

The significance and timing of sheetflood vs braided channel deposition on lacustrine fan deltas,Junggar Basin,NW China

The fan-delta reservoir play has become an important exploration target within the Junggar Basin, especially in the Mabei area within the Mahu Sag, where a fan-delta oil and gas pool has been recently discovered. The sedimentary characteristics, distribution patterns and formation mechanisms of the fan-delta clastic bodies in Lower Triassic Baikouquan Formation (T1b) were studied using seismic, well log and core data accompanied by a flume tank experiment and a modern analogue depositional study. The T1b in the Mabei area is composed of a fan delta consisting of fan-delta plain (including debris flow deposits, sheetflood deposits, braided channel deposits, and floodplain deposits), fan-delta front (including subaqueous reworked sheetflood deposits and distal sheetflood deposits) and muddy lake deposits. The sheetflood deposits, characterised by moderately sorted conglomerates with brown matrix, form during the peak flooding. They are widespread and sheet-like, occupying the major portion of the fan-delta plain. The braided channel deposits are characterised by well-sorted and clast-supported conglomerates and pebbly sandstones, formed later during the falling flow stage. Owing to the decline in volume and velocity, and the formation of continuously braided fluid flow, the sediments of the flood period are reworked, generating the braided channels. Laterally, the braided channels occur as belts of clastic bodies surrounded by continuous sheetflood deposits. Vertically, the braided channels are interbedded between the sheetflood deposits. The subaqueous reworked sheetflood deposits are characterised by greyish-green, well-sorted and clast-supported conglomerates, whereas the distal sheetflood deposits are characterised by well-sorted sandstones, intercalated with mudstone. The subaqueous reworked sheetflood and distal sheetflood deposits are a distal partly subaqueous extension of the main sheetflood deposits, albeit reworked by basinal currents and waves. The distal sheetflood deposits form on distal fringes of the sheetfloods and are more thoroughly reworked by longshore and wave currents. The braided channel, subaqueous reworked sheetflood and distal sheetflood deposits can form high-porosity reservoirs. These findings challenge the common view and suggest that the channelised facies on the fans are not the main flood events; rather, the more extensive sheetfloods are the major flood events.     

The Interrelationship of Micro-Meso and Macroscopic Structures on the Western Limb of the Hazara Kashmir Syntaxis, Pakistan

Detailed micro-meso to macroscopic structural analyses reveal two deformation phases in the western limb of the Hazara-Kashmir Syntaxis(HKS). Bulk top to NW shearing transformed initially symmetrical NNE-SSW trending meso to macroscopic folds from asymmetric to overturned ones without changing their trend. Sigmoidal en-echelon tension gashes developed during this deformation,that were oblique to bedding parallel worm burrows and bedding planes themselves. Strain analyses of deformed elliptical ooids using the R_f/φ method constrain the internal strain patterns of the NNE-SSW structures. The principal stretching axis(S_3) defined by deformed elliptical ooids is oriented N27°E at right angles to WNW-ESE shortening. The deformed elliptical ooids in sub-vertical bedding vertical planes contain ooids that plunge ~70° SE due to NW-directed tectonic transport. Finite strain ratios are1.45(R_(xy)) parallel to bedding plane and 1.46(R_(yz)) for the vertical plane. From these 2D strain values, we derive an oblate strain ellipsoidal in 3D using the Flinn and Hsu/Nadai techniques. Strains calculated from deformed elliptical ooids average-18.10% parallel to bedding and-18.47% in the vertical plane.However, a balanced cross-section through the study area indicates a minimum of~-28% shortening.Consequently, regional shortening was only partially accommodated by internal deformation.     

Impact of grazing on soil,vegetation and ewe production performances in a semi-arid rangeland

Controlled grazing is considered a good management strategy to maintain or increase the live weight of livestock and to reduce vegetation degradation of rangelands. The present study investigated soil characteristics, aboveground vegetation biomass dynamics and controlled grazinginduced changes in the live weight of local ewes in the semi-arid rangeland of Ahmadun, Ziarat, Balochistan province of Pakistan. An area of 115 ha was protected from livestock grazing in April 2014. In June 2015, soil characteristics within 0-30 cm depth i.e. soil organic matter (SOM), mineral nitrogen, pH and texture in controlled and uncontrolled grazing sites were assessed. Aboveground vegetation biomass measured in early (June) and late summer (August) in 2015 and 2016. The nutritional value i.e. crude protein, phosphorus (P), neutral detergent fiber (NDF), acid detergent fiber (ADF), calcium (Ca), magnesium (Mg) and potassium (K) of dominant plant species were assessed at the beginning of experiment in 2015. Vegetation cover of controlled and uncontrolled grazing sites was also measured during the two years of the study period using the VegMeasure software. From June to November in 2015 and 2016, controlled and uncontrolled livestock grazing sites were grazed on a daily basis by local ewes with a stocking rate of 2 and 1 head ha-1 respectively. Results reveal that the organic matter contents of coarse-textured, slightly alkaline soil of the study site were in the range of 9.4 - 17.6 g kg-1 soil and showed a strong positive correlation with aboveground vegetation biomass. The biomass of plants was 56.5% and 33% greater at controlled than uncontrolled grazing site in 2015 and 2016 respectively and plant cover was also higher at controlled than uncontrolled grazing site in both years. The nutrient contents were significantly (P<0.05) lower in grasses than shrubs. In both years, the controlled grazing increased the weight gain of ewes about two folds compared to the uncontrolled grazing. The results indicate that controlled grazing improved the vegetation biomass production and small ruminant productivity.     

Timing of collision of the Kohistan–Ladakh Arc with India and Asia: Debate

The Kohistan–Ladakh Arc in the Himalaya–Karakoram region represents a complete section of an oceanic arc where the rocks from mantle to upper crustal levels are exposed. Generally this arc was regarded as of Jurassic–Cretaceous age and was welded to Asia and India by Northern and Southern Sutures respectively. Formation of this arc, timings of its collisions with Asia and India, and position of collision boundaries have always been controversial. Most authors consider that the arc collided with Asia first during 102–75 Ma and then with India during 55–50 Ma, whereas others suggest that the arc collided with India first at or before 61 Ma, and then the India–arc block collided with Asia ca 50 Ma. Recently published models of the later group leave several geological difficulties such as an extremely rapid drifting rate of the Indian Plate (30 ± 5 cm/year) northwards between 61–50 Ma, absence of a large ophiolite sequence and accretionary wedge along the Northern Suture, obduction of ophiolites and blueschists along the Southern Suture, and the occurrence of a marine depositional environment older than 52 Ma in the Indian Plate rocks south of the Southern Suture. We present a review based on geochemical, stratigraphic, structural, and paleomagnetic data to show that collision of the arc with Asia happened first and with India later.     

Reinterpretation of an archaeological pebble culture from the Middle Mekong River valley,Cambodia

In 1963, E. Saurin and J.‐P. Carbonnel discovered the Sre Sbov site on an alluvial terrace of the Mekong River in central Cambodia. Saurin described a lithic typology dating to the Lower/Middle Pleistocene from this site. Although the original lithic assemblage has been lost, this typology has been used continuously as a reference by Southeast Asian prehistorians. In 2007, a Khmer–French team conducted excavations at Sre Sbov that yielded numerous pebbles and cobbles showing apparently convincing handmade removals, as Saurin had previously described. However, an in‐depth study of this assemblage, combined with a geological survey of the area, led to the conclusion that the stones were, in fact, of natural origin, and that for this reason their typology should be disregarded. Using satellite imagery and geological surveys, we explain how such a misinterpretation may have occurred and define a “buffer zone,” corresponding to the maximal extent of the proto‐Mekong River, where fluvially reworked pebbles and cobbles resembling artifacts may be recovered. © 2009 Wiley Periodicals, Inc.