Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

Progress in the Research on the Impact of Wind Farms on Climate and Environment

Wind power has become one of the fastest growing renewable energy. With the large-scale deployment of wind farms in the world, people have started to pay attention to the impact of wind farms on the ecological environment and climate. This paper summarized the impact of wind farms on climate and ecological environment by investigating relevant literature: In the areas of wind farms, on the one hand, the set-up of wind turbines changes original aerodynamic roughness height and strengthens the dragging of the land surface against turbulence, directly affecting the turbulent motion of the boundary layer, resulting in the changes of intensity and pattern of material energy and water vapor exchange between land surface and near-surface atmosphere, further affecting the atmospheric circulation and climate. On the other hand, wind turbines convert the majority of the wind kinetic energy into electric energy, which produces the wake effect of the wind turbine. The budget patterns and spatial and temporal distribution of large-scale kinetic energy in the boundary layer are changed correspondingly, generating changes in various fluxes (heat flux, water vapor flux, etc.) in the atmosphere, which affect temperature, precipitation, and wind speed. Generally, the warming or cooling effect of wind farms on the near-surface is related to the stability of atmosphere. However, simulations in the global climate model showed that the average impact of wind farms on global climate is small, much smaller than the expected changes in greenhouse gas emissions and the interannual changes in natural climate.Wind power emits almost no carbon dioxide and pollutants. Compared with other traditional energy sources, it reduces water consumption but may generate some negative ecological impacts such as animal habitats, bird collisions, and noise, vision impact. However, some measures can be taken to mitigate these adverse effects.     

大别山超高压变质岩的变形特征及其地质意义

大别山超高压变质岩至少经过５期变形。第１期产生于榴辉岩相变质前；第２期大致与榴辉岩相变质作用同步．岩石产生紧密同斜褶皱及榴辉岩相糜棱岩；第３期产生于超高压变质岩向中地壳折返的过程中，以榴辉岩的布丁化及基质的透入性剪切为特征；第４期主要形成剪切条带及伸展沿劈理．是大别山碰撞后差异隆升，岩层向南滑脱的结果；最后一期为脆性变形，岩层沿北东向断层产生左行平移。通过超高压变质岩的变形分析，可以了解超高压变质岩形成和折返的构造运动过程。     

渤海湾盆地A油田新近系明下段沉积特征及演化模式

渤海湾盆地A油田新近系明下段Ⅱ—Ⅴ油组是其主力含油层位。通过观察分析岩心资料的沉积构造特征、岩矿特征和粒度特征、测井形态、地球物理属性等特征,综合判定其主要发育曲流河和浅水三角洲两种沉积相类型,油田范围内曲流河主要发育河道、决口扇、天然堤和泛滥平原4种沉积微相,浅水三角洲主要发育水下分支河道、水下天然堤、河口坝和分流间湾4种沉积微相。通过分析沉积相特征,结合高分辨率层序地层学观点,对A油田明下Ⅱ—Ⅴ油组的垂向演化特征进行了探讨,结果表明:处于长周期上升半旋回的Ⅴ油组曲流河呈条带状分布;处于长周期下降半旋回初期的Ⅳ油组浅水三角洲平面呈坨状,内部砂体连通性差;处于长周期下降半旋回中期的Ⅲ油组浅水三角洲平面呈朵叶状,砂体以侧向叠置为主;处于长周期下降半旋回晚期的Ⅱ油组浅水三角洲平面呈鸟足状,砂体以垂向叠置为主。最终提出该油田沉积演化模式。     

山东济宁高硫煤与低硫煤煤层剖面地球化学特征研究

运用电感耦合等离子质谱（ICP-MS）、X射线荧光光谱（XRF）、离子选择电极（ISE）、显微镜光度计和煤化学等方法,对山东济宁矿区的高硫煤（太原组16号煤层）与低硫煤（山西组3上煤层）剖面的煤岩、煤质和煤地球化学特征进行研究。高硫煤中微量元素在垂向上呈现显著的变化规律：（1）Sr含量从煤层底板到顶板呈增高趋势,而Ba含量则相反;因而Sr/Ba比值从下向上呈逐渐变大趋势（0.04～47.7）;（2）Th/U比值从下向上也呈逐渐变大趋势（0.2～37.1）;（3）As含量在煤层顶板石灰岩（26.1μg/g）、透镜状黄铁矿夹层（14.7～19.3μg/g）中较高;（4）V、Cr、Co、Ni、Cu、Pb、Zn等元素在煤层底部和顶部分层中含量较高,而在煤层中部分层中含量较低;（5）Nb、Ta、Zr、Hf、Ga等元素从煤层的底部到顶部呈逐渐降低趋势;（6）煤中稀土元素总量（REE）,除透镜状黄铁矿夹层（第2、4、11分层）外,其它分层（第1、3、5、6、7、8、9、10分层）显示从上往下逐渐增高之规律性。低硫煤中微量元素的分布和垂向变化与高硫煤明显不同：As含量在14个煤分层中都较低（1.03～3.37μg/g）,Sr/Ba比值从下向上变化不大（0.4～2.2）,各个煤分层中稀土元素总量（REE）呈现随灰份含量增高而增高的变化趋势,低硫煤与高硫煤的稀土元素分布模式差别很大。上述研究结果表明济宁矿区高硫煤与低硫煤在地球化学特征上的差别,反映了上石炭统太原组与下二叠统山西组沉积环境和聚煤条件的差别,具有指相意义;太原组16号煤层中富集的硫及有害微量元素,对环境具有潜在危害。     

离子色谱法测定水样中S~(2-)、SO_3~(2-)、SO_4~(2-)、S_2O_3~(2-)

该种方法利用离子色谱仪的电导检测器与电化学检测器串联 ,十几分钟即可连续完成水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3 的测定 ,方法具有快速、高效、方便、灵敏、选择性好等特点。方法的检出限分别为 :S2 - 12 5 μg/L ;SO2 - 3 2 2 4 μg/L ;SO2 - 45 0 μg/L ;S2 O2 - 35 0 μg/L。相对标准偏差在 1 5 %～ 6 9%之间 ,能够满足水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3四种阴离子分析测试的需要。     

应用光率体论述宝石折射率仪测试原理及其应用

】应用晶体光学中的光率体原理对宝石折射仪测试应用问题作较为详尽的论述,特别对一轴晶、二轴晶宝石测试所遇到的各种现象作进一步全面探讨,并给予确切的解释。     

Fractal Analysis of the Complexity of United States Coastlines

Coastlines have long been used as a principal example of a natural feature that exhibits fractal structure. With the advent of large digitized databases, it has become possible to examine in detail large regions of coast and to examine differences in complexity, as measured by the fractal dimension, among regions. In this study, we have determined the fractal dimension of the Atlantic and Pacific coastlines of the conterminous United States. The traditional divider method was used in obtaining the fractal dimension of each coastline arc from the NOAA Medium-Resolution Shoreline Data Set. On average, the Atlantic coast has much higher fractal dimension than the Pacific coast. The results also indicate that the complexity of the Atlantic coast increases toward low latitudes. These results have implications for the interpretation of species distributions and diversity patterns along the coast and for the understanding of the dynamics of biotic recovery from mass extinctions.     

Paleoclimate Modelling at the Institute of Atmospheric Physics, Chinese Academy of Sciences

Paleoclimate modelling is one of the core topics in the Past Global Changes project under the International Geosphere-Biosphere Programme and has received much attention worldwide in recent decades. Here we summarize the research on the Paleoclimate modeling, including the Holocene, Last Glacial Maximum, and pre-Quaternary climate intervals or events performed at the Institute of Atmospheric Physics under the Chinese Academy of Sciences (IAP/CAS) for over one decade. As an attempt to review these academic activities, we emphasize that vegetation and ocean feedbacks can amplify East Asian climate response to the Earth’s orbital parameters and atmospheric CO2 concentration at the mid-Holocene. At the Last Glacial Maximum, additional cooling in interior China is caused by the feedback effects of East Asian vegetation and the ice sheet over the Tibetan Plateau, and the regional climate model RegCM2 generally reduces data-model discrepancies in East Asia. The simulated mid-Pliocene climate is characterized by warmer and drier conditions as well as significantly weakened summer and winter monsoon systems in interior China. On a tectonic timescale, both the Tibetan Plateau uplift and the Paratethys Sea retreat play important roles in the formation of East Asian monsoon-dominant environmental pattern during the Cenozoic.