Application of low-pressure gas adsorption to nanopore structure characterisation of organic-rich lower Cambrian shale in the Upper Yangtze Platform,South China

The pores in shales are mainly on a nanometer scale, and the pore-size distribution is vital with regard to the preservation and exploitation of shale gas. This study focuses on the organic-rich lower Cambrian black shale in the Upper Yangtze Platform, South China and investigates their TOC, mineralogical composition and nanopore structure. Low-pressure N₂ and CO₂ adsorption experiments were conducted at 77.35 K and 273.15 K, respectively, and the nanopore structures were characterised by the modified Brunauer–Emmett–Teller, Dubinin–Radushkevich, t-plot, Barrett–Joyner–Halenda and density functional theory (DFT) methods. The results indicate the following. (1) The lower Cambrian shale has a high TOC content (1.77–7.23 wt%) and a high quartz content (27.7–51.6 vol%). The total specific surface area varies from 12.02 to 28.87 m²/g. Both the total specific surface area and quartz content are positively associated with the TOC content. (2) Shale samples with a higher TOC content have a greater number of micropores, resulting in more complicated nanopore structures. Micropore volumes/surface areas and non-micropore surface areas all increase with increasing TOC content, indicating that TOC is the key factor determining the nanopore structure of the lower Cambrian shale. (3) A combination of N₂ and CO₂ adsorption provides the most suitable detection range (～0.3–60 nm) and is both highly reliable and accurate with regard to nanopore structure characterisation.     

LA-ICP-MS Analysis of Magnetite and Application in Genesis of Mineral Deposit

Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) is well characterized by the in-situ, real time, lower limit of detection and high space resolution, etc. Therefore, it is more excellent in the analysis of trace element for varied minerals in comparison to other micro-zone analysis technologies. Magnetite as a common mineral from different deposits and rocks has been focused on chemical compositions by researchers worldwide. In fact, as the insignificant matrix effect for most elements in magnetite, analysis results could be calculated effectively against Fe-rich silicate glass as the reference material. Therefore, researches on trace element distribution of magnetite have been developed rapidly in recent years, and it has a wide application prospect in reflecting the condition of ore-forming, discriminating different deposit types and indicating prospecting exploration. Comparing varied previous discrimination diagrams about magnetite via collecting trace element data from available literatures based on 25 deposits, we found that there was an urgent need for further detailing and reexamining the boundary of fields representing different genetic types, and it was vital for interpreting the data through carefully petrographical observation before analysis. In addition, we discussed several complex physicochemical factors, which would influence the element concentration of magmatite in igneous and hydrothermal processes, such as melt/fluid composition, temperature, cooling rate, pressure, oxygen fugacity, sulfur fugacity and silica activity. In magma stage, Magnetite’s components are closely related to melts composition and differentiation, while fluid features would also significantly change magnetie's components. Furthermore, there is serious interference for discriminating the genesis of magnetite because of late stage fluids and equilibrium again in subsolidus condition. This paper reviewed the developments of trace elements analysis by LA-ICP-MS and important applications about magnetite in mineral deposit so that unique thoughts for the research on mineralization and ore-forming processes could be obtained.     

A new record of ponyfish <Emphasis Type="Italic">Deveximentum megalolepis</Emphasis> (Perciformes: Leiognathidae) in Beibu Gulf of China

A new record ponyfish, Deveximentum megalolepis Mochizuki and Hayashi, 1989, was documented based on its morphological characteristics and DNA barcode. Fifty specimens were collected from Beibu Gulf of China and identified as D. megalolepis by morphological characterization. The coloration, meristic traits, and morphometric measurements were consistent with previously published records. In general, it is a silver-white, laterally compressed and deep bodied ponyfish with 6–9 rows of scales on cheek; scale rows above lateral line 6–8; scale rows below lateral line 14–17. Mitochondrial cytochrome oxidase I subunit (COI) gene fragment was sequenced for phylogenetic analysis. There is no sequence variation of COI gene between the specimens collected in this study. The genetic distances between D. megalolepis and other congeneric species range from 3.6% to 14.0%, which were greater than the threshold for fish species delimitation. The COI sequence analysis also supported the validity of D. megalolepis at genetic level. However, the genetic distance between Chinese and Philippine individuals was about 1.2% and they formed two lineages in gene tree, which may be caused by the geographical distance.     

汶川8.0级地震地表变形局部化样式与建筑物破坏特征关系初步研究

本文以汶川地震地表形变带的实地测量数据为基础,结合沿实测地震地表变形剖面建筑物破坏情况的调查与测量,分析了不同地震地表变形类型及其建筑物破坏特征,定量化地讨论了地表变形梯度与建筑物破坏程度间的关系。提出无论地震地表变形表现为何种类型的断层陡坎,地表破裂、强变形局部化在宽10~30m的地表破裂带内;建筑物受损情况最直接的影响是建筑物所处地点的地表变形梯度,地表变形梯度大于0.1的地段,建筑物均完全被摧毁;地表变形梯度在0.07~0.1间的地段,建筑物遭受严重损坏,产生倾斜及强烈变形等;地表变形梯度在0.03~0.07之间的地段,建筑物可能受到中度损坏,产生倾斜及变形等,具有抗震设防能力的构建筑物一般不会倒塌;地表变形梯度小于0.03的地段具有抗震设防能力的构建筑物一般只会受到轻的损坏或基本完好。     

1951—2009年丹东地区暴雨变化

利用丹东地区1951—2009年4个测站逐日降水资料,对丹东地区暴雨变化进行了分析。结果表明：丹东地区年暴雨日数和暴雨量呈减少趋势,汛期洪涝贡献率趋势变化不明显;2001—2009年6月份暴雨日数明显增多,7月份暴雨日数偏少,暴雨初期和终期提前。     

Statistical study on great geomagnetic storms during solar cycle 23

Characteristics of great geomagnetic storms during solar cycle 23 were statistically investigated. Firstly, we focused on the uniqueness of solar cycle 23 by analyzing both the great storm number and sunspot number from 1957 to 2008. It was found that the relationship between the sunspot number and great storm number weakened as the activity of the storms strengthened. There was no obvious relationship between the annual sunspot number and great storm number with Dstxi≤-300 nT. Secondly, we studied the relationship between the peak Dst and peak Bz in detail. It was found that the condition Bz≤-10 nT is not necessary for storms with Dst≤-100 nT, but seems necessary for storms with Dst≤-150 nT. The duration for Bz≤-10 nT has no direct relationship with the giant storm. The correlation coefficient between the Dst peak and Bz peak for the 89 storms studied is 0.81. After removing the effect of solar wind dynamic pressure on the Dst peak, we obtained a better correlation coefficient of 0.86. We also found the difference between the Dst peak and the corrected Dst peak was proportional to the Dst peak.     

基于点云曲线辨识的卫星激光数据预处理算法

针对卫星激光数据处理算法这一难题,分析了COMPASS系统GEO卫星激光观测数据的质量,讨论了反求工程和计算机视觉中的曲线识别与激光观测数据预处理的异同,提出了基于点云曲线辨识的卫星激光数据预处理算法。该算法将卫星激光观测数据预处理视为有序带噪声的空间曲线重建问题,利用COMPASS系统多圈GEO卫星实测数据进行验证。结果表明：该方法与常用算法一致率在85％以上,能够实现激光观测数据的自动处理与满足导航系统的需要。     

天津市地震前兆台网的运行监控与维护管理

介绍天津市地震前兆台网的基本概况以及前兆台网部的职责任务;阐述仪器设备运行监控、观测数据质量监控的方式与方法;总结在仪器设备、技术系统维护过程中解决的一些关键技术问题;最后提出了关于仪器和软件系统的一些问题与建议。     

临汾台摆式倾斜仪平行观测的差异性特征及其观测布局建议

根据临汾地震台石英摆、垂直摆、宽带垂直摆3套摆式倾斜仪器的观测资料,对山西中南部几次中等地震进行分析,发现在地震前各仪器同测向曲线有一定的异常反映,但异常并非呈相关一致性变化,有的还表现出明显的差异性特征;在同一台址条件下,异常的差异性与仪器的工作周期、动态响应范围、记录频段等有关;河津地震前后宽带垂直摆倾斜仪记录到的连续阶跃扰动(错位掉格)可能是慢地震现象,由此说明了宽频段仪器的优越性及发展性;建议在形变台网观测中,同一台站应建立宽频或多种同类型的形变观测仪器,组成尽量具有低、中、高频段的全面观测系统,这可能对于扑捉近震的短临前兆异常有实效意义.     

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