硼酸盐化学(XXXV): MgO·3B2O3-18%MgSO4-H2O过饱和溶液0℃结晶动力学研究

首次研究了MgO·3B2 O3 1 8%MgSO4 H2 O过饱和溶液 0℃结晶动力学过程 ,得到三方硼镁石和章氏硼镁石两种固相及其结晶动力学方程。从多聚硼氧配阴离子多粒子共存的角度提出结晶反应机制 ,分析了制约硼酸镁盐析出的因素及不同电解质 (MgCl2 和MgSO4)对硼酸镁盐结晶过程的影响。     

新疆可持续协调发展动态分析与评价

作为“资源大区”的新疆,在中国经济发展中具有重要的资源战略地位、生态安全地位和沿边开放地位。实施可持续发展战略,走可持续发展之路,是新疆区域发展的必然要求。在构建区域可持续发展指标体系的基础上,依据1980-2003年的统计数据,采用组合评价法研究新疆可持续协调发展及其动态变化,并得出一些主要结论和启示。     

萃取法制取磷酸二氢钾工艺研究

本文研究改进了萃取法制取磷酸二氢钾的工艺路线,确定了较适宜的工艺条件,萃取在常温下进行,一次反应得到磷酸二氢钾。产品纯度高,能耗低,有望成为大规模工业生产该产品最经济的路线之一。     

Effect of hysteretic smoothness on inelastic response spectra with constant‐ductility

This paper presents an efficient methodology for computing constant‐ductility inelastic response spectra. The computation of constant‐ductility spectra involves numerical root‐finding algorithms to find the strongest structure providing a desired ductility response. Smooth inelastic structural behavior is modeled using a first‐order nonlinear differential equation and the transient structural response is solved using an implicit algorithm requiring Newton iterations at each time step. For structural models with smooth hysteretic behavior (not piece‐wise linear), a simple root‐finding method involving a combination of hyperbolic fits, linear interpolation, and Newton's method converges upon the highest strength (conservative) solution with a small number of iterations. The effect of the hysteretic smoothness on the occurrence of multiple roots is examined for two near‐fault and two far‐fault earthquake records, and for two measures of ductility and for normalized hysteretic energy. The results indicate how the smoothness of the hysteretic behavior affects ductility demand and constant‐ductility response spectra. Copyright © 2010 John Wiley & Sons, Ltd.     

Assessing the impacts of ecological-living-productive land changes on eco-environmental quality in Xining City on Qinghai-Tibet Plateau,China

The Ecological-living-productive land(ELPL) classification system was proposed in an effort to steer China's land pattern to an ecological-centered path, with the development model shifting from a single function into more integrated multifunction land use. The focus is coordinating the man-land contradictions and developing an intensive, efficient and sustainable land use policy in an increasingly tense relationship between humans and nature. Driven by socioeconomic change and rapid population growth, many cities are undergoing urban sprawl, which involves the consumption of cropland and ecological land and threatens the ecological balance. This paper aims to quantitatively analyze the critical effects of ELPL changes on eco-environmental quality according to land use classification based on leading function of ecology, living and production from 1990 to 2015 with a case study of Xining City. Also, four future land use scenarios were simulated for2030 using the Future Land Use Simulation(FLUS) model that couples human and natural effects. Our results show a decrease in productive land(PL) and an increase in ecological land(EL) and living land(LL) in Xining City. Forestry ecological land(FEL) covered the top largest proportion; agriculture productive land(APL) showed the greatest reduction and urban and rural living land(U-RLL) presented a dramatic increase. The eco-environmental quality improved in 1990-2010, mainly affected by the conversion of APL to FEL and GEL. However, the encroachment of U-RLL into APL, other ecological land(OEL) and FEL was the main contributor to the decline in eco-environmental quality in 2010-2015 as well as the primary reason for the increase area of lower-quality. The Harmonious Development(HD)-Scenario, characterized by a rational allocation of LL and PL and a better eco-environment, would have implications for planning and monitoring future management of ELPL, and may represent a valuable reference for local policy-makers.     

近2000年古里雅冰芯净积累量与南疆盆地南沿的干湿变化

利用1951-1991年古里雅冰芯净积累量、1951-2000年南疆盆地南沿的降水资料和1958-2000年NCEP/NCAR再分析的大气环流资料,讨论了它们之间的相互关系,并对其机理进行了初步分析,在此基础上建立了南疆盆地南沿近2000年高分辨率的干湿变化序列。     

塔克拉玛干沙漠腹地大气气溶胶散射特征研究

利用沙漠腹地塔中气象站积分浊度计的2004年观测资料,结合同期PM10质量浓度、能见度和常规气象资料,分析了塔克拉玛干沙漠腹地气溶胶散射系数的变化特征,以及气溶胶散射系数与PM10质量浓度、能见度的关系。研究表明,2004年塔中气溶胶散射系数、PM10质量浓度、能见度日平均值分别为124.74±187.30 Mm-1,538.9±841.7 μg·m-3,12 748±7 274 m。塔中气溶胶散射系数小时平均值出现频率最高的区间主要在100 Mm-1以下,中午气溶胶散射系数小,早晚气溶胶散射系数大;冬春两季的凌晨空气中含有较多的粒子,气溶胶散射系数较大;气溶胶散射系数小时平均值与PM10质量浓度变化规律基本一致,2004年1—6月的气溶胶质量散射系数平均值为0.37 m2·g-1;散射系数与能见度日平均值非线性相关较好,两者呈负幂函数关系。     

训练样本对遥感影像分类精度影响研究

以大理SPOT-5 HRG影像和Landsat TM影像作为数据源,在构建标准训练样本数据集的基础上,探索训练样本对遥感影像分类的影响。选取不同训练样本数量组合,分别对监督分类中的平行六面体、最小距离、马氏距离、最大似然法、神经网络和支持向量机6种分类方法进行多次实验,并采用Kappa系数和总体分类精度对实验分类结果的精度进行评价。结果表明:以多次分类结果的平均值作为最终的分类结果能减小随机误差;增加训练样本数量可以减小单次分类引起的随机误差;在不同的训练样本量下,支持向量机的分类精度最高。     

太平洋海温异常对大理雨季开始期的影响

采用大理州雨季开始期资料、1961年6月~2008年5月太平洋5°×5°共286个格点的逐月平均海温资料及NCEP/NCAR的SSTA资料,通过相关分析发现,太平洋海温与大理雨季开始期的关系密切,春季和上年秋季太平洋海温对大理雨季开始的影响较大。雨季开始前若发生厄尔尼诺事件,大理雨季开始期偏晚,反之,若发生拉尼娜事件,大理雨季开始期偏早。N ino3区的海温异常对大理雨季开始期的影响相当明显,当5月N ino3区的海温异常偏高时,大理雨季开始期偏晚;反之,当5月N ino3区的海温异常偏低时,大理雨季开始期偏早,N ino3区海温异常可以作为大理雨季开始期预测的一个强信号因子。     

古村落社区旅游参与度及影响因素——西递、宏村、南屏比较研究

以社区家庭为视角,建立基于利益导向的社区旅游参与水平测度指标,以皖南古村落西递、宏村、南屏为实证研究对象,揭示了古村落社区旅游参与度异同及其影响机理。研究结果表明:① 古村落内部、古村落之间的旅游参与度均有不同程度的差异,归因为家庭微观因子与社区中观因子交互作用所致。② 通过家庭微观因子对家庭人均旅游收入影响的通径系数分析,得出三个景区相应的直接通径系数和间接通径系数,发现古村落家庭微观因子的影响方向趋同而影响程度分异,与问卷调查结果分析的一致性也显示了该方法的较强解释力和潜在应用价值。③ 提高古村落社区旅游参与整体水平、缓解参与度空间差异的根本途径在于"让利于民",增强社区分利能力,政府在其中扮演着重要的引导角色。