丹霞山世界地质公园蜂窝状洞穴特征及成因分析

蜂窝状洞穴以其精致的形貌和众说纷纭的成因吸引着科研人员和普通大众的兴趣。丹霞山世界地质公园蜂窝状洞穴主要产于晚白垩世丹霞组二段(锦石岩段)风成砂岩的崖壁上。本文以园区长老峰锦石岩寺和睡美人禄意堂两处蜂窝状洞穴为研究对象,通过野外实地调查,了解洞穴生长环境,定量统计分析其形态特征,并采集砂岩样品进行显微镜下观察,探讨洞穴形成与盐风化作用的关系。研究表明:蜂窝状洞穴所在的岩性主要为中—细粒长石岩屑砂岩,发育大型高角度交错层理,渗透性较好;洞穴开口均向下朝向锦江,有利于来自锦江河流的湿润水汽较长时间地保持在小洞内部;洞穴开口基本服从泰森多边形分布。因此,碎屑颗粒相对比较均匀的风成砂岩为丹霞山蜂窝状洞穴的发育提供了重要的岩石基础,锦江河流为盐风化提供了必要的湿润水汽和盐分。在初始发育阶段,从岩壁上最适合盐风化作用的若干个点开始形成细小的坑洼,逐步向同层位扩张。单个小洞穴由于盐风化作用,洞穴内部风化速率大于洞穴开口边缘,导致蜂窝状洞穴内部空间扩大较快。然后,蜂窝状洞穴的发育突破纹层的限制,逐步加大、变深而呈泰森多边形规则分布。最终,随着洞穴加深,在重力、风力的影响下,蜂窝状洞穴隔壁减薄失稳,洞穴消亡。     

煤矸石制作轻质莫来石砖研究

本文研究了利用煤矸石生产高档轻质莫来石砖的可行性，实验研究表明，在煅烧后的煤矸石中加入部分工业氧化铝粉，一起混磨至８００目筛余小于５％，再经加有机质成型和１５５０℃×５小时煅烧，可制成物相及各种性能指标达到从德国进口轻质莫来石砖的制品。     

基于事例推理技术的水库洪水调度研究与应用

将基于事例推理(CBR)技术应用到水库洪水调度中,提出了一种基于CBR的水库洪水调度模式和方法。利用关系数据库实现了洪水调度事例的表示、组织、索引和存储,并建立了水库洪水调度事例库。将遗传禁忌算法与最近相邻法结合起来,构建了基于遗传禁忌算法和最近相邻法相结合的混合检索算法,提高了事例检索的速度和质量。利用遗传算法对事例特征属性权重进行优化,采用多目标决策方法进行事例的优选,并给出了事例调整和学习的策略。最后,应用该方法开发了基于CBR的水库洪水调度系统,并给出了一个应用实例。基于CBR的水库洪水调度为水库洪水调度提供了一种简化知识获取、提高调度效率和质量、进行知识积累和重用的新的思路和方法。     

Research on protection of steel piles of Baoshan general steel factory wharf by using DZ and DZ-2 tapes

Steel piles at the tidal zone can be seriously corroded. Common protective methods such as painting or coating with rubber or other protective materials, etc. cannot provide full protection when used as supplementary protection because these traditional methods require strict pretreatment and sealing of the metallic surface from the corrosive mediums, and time for the protective coatings to solidify. This is very difficult under the severe action of waves and surges on the sea. With our oil-soluble DZ-2 tape, protection efficiency for hanging steel plates at the tidal and splash zones reaches to 82–99%. The protection efficiency of water soluble DZ tape at the tidal zone reaches to 92.9%. The DZ and DZ-2 tapes can rapidly reduce the original corrosion velocity to ten percent and one percent respectively as fully proved by the 500 hour rapid corrosion testing with indoor salt fog and by the relevant electrochemical parameters of instantaneous corrosion velocity, etc. DZ tape absorbs much OH⁻ to cause a pH rise. A synergistic protective effect is gained when DZ tape is used together with cathodic protection of steel piles at the tidal zone. The working principle of DZ tape is different from that of DZ-2 tape even though they are composed of the same chemical materials. The latter provides protection because of the close affinity between metal and its carboxyl group shields the active centre at the metal surface to reduce the activation energy of metal. The carbon chain forms a covering oil film of netted structure. Dai Tao, Dai Wei and Xia Caiyuan et al. participated in the research and made useful contribution. Contribution No. 1656 from the Institute of Oceanology, Academia Sinica.     

Environmental Geochemistry of Mining Activities in Panzhihua Region, Southwestern China

INTRODUCTIONMining activlties have significant envi ronmenta1 inll)ac'l ssuch as visual intrusions, dust, noise, blasting, trafflc and h}'drology (Kwolek, l999; Ripley et al., l996 ). The l)rot'csst'sof mineral extraction, processing, smelting and refinlng;1rt'never approximate to the environmental neutrality, but tht' affected areas can be ameliorated (KwoIek, l999; Klukanov;1;llltlRapant, 1999). The regions, where mining activities are I,r('sent or continuous for a long tlme, are pote…     

X射线衍射技术应用于宝石鉴定-合成及晶体结构研究进展

因宝石检测常附带无损要求、宝石评价具科学性和不确定性等特点,X射线衍射(XRD)在宝石学这门矿物学的分支学科中的应用具有特殊性,其应用领域主要集中在三个方面。①宝石鉴定领域:对单晶宝石和多晶宝石进行物相鉴定、宝石产地特征研究以及宝石矿物多型的种类划分等。例如根据XRD图谱,可将品种繁多的微晶石英隐晶质变种玉髓中不同的SiO₂质矿物相精确区分;通过黏土矿物成分及其含量可将鸡血石中"地"的种类进行划分。②宝石矿物的晶体结构研究:对成分复杂的单晶宝石进行晶体化学分析、获取矿物类质同象替代情况、利用结晶度划分宝石品质。例如晶格参数中的c/a比值可将绿柱石的Al八面体类质同象替代和Be四面体类质同象替代进行区分;软玉中通过XRD数据计算出的结晶度与软玉的品质关系密切。③宝石学研究技术的开发:对宝石的优化处理过程进行监测,在宝石合成过程中检验矿物晶形大小、结晶质量及内应力等,以有机宝石的晶体结构为基础的人工养殖技术研究。例如尖晶石在热处理过程中,Mg离子由四面体中的T位迁移至八面体中的M位,导致M-O和T-O键长随温度变化,并反映在尖晶石的色调中;在托帕石合成过程中,XRD数据显示770~800℃时形成含氟托帕石(与天然托帕石结构相同),而在950℃和1000℃出现含氟托帕石离解成刚玉和莫来石。目前,我国在宝石学的XRD应用方面起步较晚,国外在宝石鉴定、优化与合成方面的应用相对成熟。本文认为,该技术与扫描电镜、质子探针等分析技术的联用仍有很大发展空间。     

Recent catastrophic debris flows in Luding county, SW China: geological hazards, rainfall analysis and dynamic characteristics

About 127 debris flow gullies have been identified, and debris flows have been an important type of geological hazards in Luding County, affecting cities, towns, rural areas, scenic spots and human’s engineering projects, such as mining and waterpower utilizing equipments. In this summary paper, recent two catastrophic debris flow events occurred on June 30, 2005, in Chuni town, in the central of the county, and on August 11, 2005, in Hailuogou scenic spot, in the southwest of the county, respectively, are reviewed. The debris flow events are introduced on the basis of field investigation and RS interpretation and the triggering factors for flow occurrence are identified. Furthermore, the rainfall related to flow occurrence including antecedent rainfall and intraday rainfall is analyzed, and a power-law function which can be used as a basic warning line is established based on both antecedent effective rainfall and intraday rainfall. Then dynamic parameters such as flow velocity and flow discharge are calculated, respectively. Through comparison and discussion, some conclusions are made including (1) The antecedent rainfall played an important role for debris flows which generated predominately based on the slope-instability due to the saturated loose sediments; (2) Despite slower flow velocity and smaller magnitude, the slope-type debris flows just like 2005-6-30 debris flows usually lead to serious damages for the difficulty to forecast and to prevent; (3) The mistaken recognition on debris flow hazards and lack of prevention consciousness strengthen the hazard and damage degree. This research is of certain significance for the prevention and mitigation of debris flow hazards and for the planning of the town building and tourism development in the future.     

Evaluation of aluminum speciation in surface waters in China and its environmental risk assessment

As the ongoing global research on acid precipitation is developing in depth, more and more attention has been paid to the ecological effects of aluminum (Al) due to its toxicity to plants and animals, which is caused by acid precipitation. As a very serious problem of terrestrial and aquatic environmental acidification occurs in China, especially in southwestern China, a systematic investigation of Al speciation in these regions is very important. In this paper, the Al speciation results of surface waters in China are reported and its ecological impacts is evaluated. More than 100 water samples were collected from about twenty provinces of China. Driscoll's Al speciation scheme combined with the modified MINQEL computer model is used for speciation of Al. This study shows that the ecological impacts of acidification are quite different between China and Western countries, because of different geographical environments and geological settings. In Western countries, acidification is mainly caused by NO₂^-. Due to low concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺, the buffer capacities of soil and water are weak. Therefore, natural waters can be acidified to pH<5 very easily, resulting in a considerable mobilization of Al and worsening of the ecological environment. In China, acid precipitation is mainly in the form of sulfuric acid. In northwestern China, concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ are high in soil and surface waters. This leads to much higher capacity and a high resistance ability to acidification. The pH values of waters in this region are high (around 7) and no serious Al toxicity is found at present. However, in northeastern and southeastern China, the soil is rich in Al (unsaturated aluminosilicates in northeastern China, saturated aluminosilicates in north and central China, aluminum-rich soil in southeastern and southwestern China). The concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ in soil and waters are lower than those of northwestern China. Therefore the buffer capacity is limited. Numerous surface waters have already been acidified and pH values declined to 5. The impacts of Al toxicity on ecological systems in these regions are very serious, especially in Jiangxi, Hubei Provinces and Chongqing Municipality.     

北京平原区水源热泵应用适宜区划分

北京市水源热泵的应用,宏观上未充分考虑地下水水源地的分布,微观上未注重应用场地的水文地质条件,地下水回灌率低造成了水资源浪费。本文针对北京平原区的水文地质条件,以浅层含水层导水系数、有效导水系数、地下水中的铁和总硬度为评价因子,以水源地保护区及补给区、地面沉降中心区为约束因子,利用叠加分析技术,将平原区分为适宜发展区、较适宜发展区、限制发展区和禁止发展区,为水源热泵的理性推广提供了技术参考。