Amplified exchange rate by tidal forcing of a piecewise-linear Helmholtz bay

Sea-level and current measurements have been performed in the Mok Bay, a tidal embayment in the Dutch Wadden Sea, situated on the island of Texel, the Netherlands. Characteristic for this estuary is its nonuniform hypsometry. Oscillations in both water level and inflow of the estuary were observed, with characteristic frequencies of 31 and 48 cycles per day. The significant change in basin shape between low and high water is the cause for the existence of these two frequencies of resonance. Due to its semi-enclosed nature, the basin could at both tidal phases be characterized as a Helmholtz resonator, albeit of different dimensions. Depth measurements were performed to find these characteristic dimensions of the estuary, allowing the determination of its theoretical Helmholtz frequencies. These estimates match to within 10% with the observed frequencies, and this deviation can partly be explained. Although sea level oscillations at these frequencies have small amplitude (of order 1 cm), the accompanying oscillatory flow at the entrance is of similar magnitude as the tidal flow. The water level measurements (spanning only 8 days of data) were therefore modeled using a piecewise-uniform hypsometry that approximates the real hypsometric curve well. The simplified semi-analytical piecewise-linear viscous Helmholtz model captures the observed combination of tidal and eigenoscillations well. However, despite its simplicity, this model is able to display nonlinear behavior for certain parameter values. This is because of the intrinsic nonlinearity that accompanies the matching of the low and high water phases. In the setting studied here, bifurcations up to period 13 were found. This nonlinear type of response may be of importance in facilitating an extra exchange of sediments and nutrients between the Bay and the sea.     

Refractor velocity analysis: a signal processing procedure

This paper presents a signal processing procedure to perform refractor velocity analysis. The procedure enables one to obtain the seismic velocity from the refracted wavefield without the picking of refracted arrival times. Two processing procedures are derived, one starting from a seismic interferometric approach and another, from the conventional reciprocal method and generalized reciprocal method approaches. The theoretical equivalence of the two approaches is also demonstrated. The proposed processing procedure is applied to synthetic data in order to test the influence of some procedural parameters and its capability to reconstruct a known velocity model starting from refracted signals, without and with perturbations, in arrival times and noise; finally, it is applied to a field data set.     

The origin of large varioles in flow-banded pillow lava from the Hooggenoeg Complex,Barberton Greenstone Belt,South Africa

Exceptionally well-preserved pillowed and massive phenocryst-free metabasaltic lava flows in the uppermost part of the Palaeoarchaean Hooggenoeg Complex of the Barberton Greenstone Belt exhibit both flow banding and large leucocratic varioles. The flow banding is defined by blebs and bands of pale and dark green metabasalt and was the result of mingling of two types of basalt (Robins et al. in Bull Volcanol 72:579–592, 2010a). Varioles occur exclusively in the dark chlorite-, MgO- and FeO-rich metabasalt. Varioles are absent in the outermost rinds of pillows and increase in both abundance and size towards the centres of pillows. In the central parts of some pillows, they impinge to form homogeneous pale patches, bands or almost homogenous cores. Individual varioles consist essentially of radially orientated or outwardly branching dendritic crystals of albite. Many varioles exhibit concentric zones and finer-grained rims. Some varioles seem to have grown around tiny vesicles and vesicles appear to have been trapped in others between a core and a finer-grained rim. The matrix surrounding the ocelli contains acicular pseudomorphs of actinolite and chlorite after chain-like, skeletal Ca-rich pyroxenes that are partly overgrown by the margins of varioles. Varioles are enriched in the chemical constituents of feldspar but contain concentrations of immobile TiO₂, Cr, Zr and REE that are similar to the host metabasalts. The shape, distribution, texture and composition of the varioles exclude liquid immiscibility and support an origin by spherulitic crystallisation of plagioclase from severely undercooled basalt melt and glass. Nucleation of plagioclase was strongly inhibited and took place on vesicles, on the bases of drainage cavities and along early fractures. Eruption in deep water and retention of relatively high concentrations of volatiles in the melt may be the principal cause of spherulitic crystallisation in the interiors of pillows rather than only in their margins as in younger submarine flows.     

Acigöl rhyolite field,central Anatolia (part II): geochemical and isotopic (Sr–Nd–Pb, δ<Superscript>18</Superscript>O) constraints on volcanism involving two high-silica rhyolite suites

The Acigöl rhyolite field erupted the most recent high-silica rhyolites within the Cappadocian Volcanic Province of central Anatolia, Turkey. It comprises two sequences of domes and pyroclastic rocks with eruption ages of ~150–200 ka (eastern group) and ~20–25 ka (western group). Compositionally, the eastern rhyolite group lavas are less evolved (SiO₂ = 74–76 wt%), whereas the western group has higher silica abundance (SiO₂ = ~77 wt%) with extremely depleted feldspar-compatible trace elements. Within each group, compositional variability is small and ¹⁴³Nd/¹⁴⁴Nd (0.51257–0.51265) and Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.87–18.88, ²⁰⁷Pb/²⁰⁴Pb = 15.65–15.67 and ²⁰⁸Pb/²⁰⁴Pb = 38.94–38.98) are homogeneous. The western group rhyolites have δ¹⁸O(zircon) overlapping mantle values (5.7 ± 0.2‰), whereas eastern group rhyolites are enriched in δ¹⁸O by ~0.5‰, consistent with a tendency to lower εNd values. By contrast, western group rhyolites have markedly more radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7065–0.7091) compared to those of the eastern group (0.7059–0.7065). The presence of angular granitic xenoliths and a correlation between hydration (based on loss on ignition data) and ⁸⁷Sr/⁸⁶Sr in the western lavas, however, indicates that Sr was added during the eruption or post-eruption alteration. Isotope constraints preclude the possibility that the rhyolite magmas formed by partial melting of any known regional crystalline basement rocks. Basalts and andesites erupted in the periphery of the Acigöl field are characterised by ⁸⁷Sr/⁸⁶Sr ratios between 0.7040 and 0.7053, ¹⁴³Nd/¹⁴⁴Nd = 0.51259–0.51300, ²⁰⁶Pb/²⁰⁴Pb = 18.85–18.87, ²⁰⁷Pb/²⁰⁴Pb = 15.646–15.655, ²⁰⁸Pb/²⁰⁴Pb = 38.90–38.97. The isotopic and trace element data favour an origin of the rhyolites by mixing of basaltic/andesitic magmas with minor amounts of crustal melts and followed by extensive fractional crystallization.     

Barium-rich fluids and melts in a subduction environment (La Corea and Sierra del Convento mélanges,eastern Cuba)

Whole-rock compositions of muscovite-bearing amphibolite, trondhjemite, pegmatite and quartz-muscovite rocks from Sierra del Convento and La Corea mélanges (eastern Cuba), as well as mineralogy, record complex circulation of Ba-rich fluids and melts in the subduction environment. Partial melting of fluid-fluxed, MORB-derived amphibolite produced trondhjemite magmas that crystallized at depth, in some cases evolving into pegmatites. Qtz-Ms rocks probably crystallized from primary fluids derived from subducted sediments. All these rocks have elevated concentrations of large-ion lithophile elements, especially Ba (up to 11,810 ppm), presumably released from slab sediments by fluids and/or melts. Fluid–rock interaction produced crystallization of phengite in parental amphibolites. The phengite crystallized in all types of rocks is rich in Ba, with concentric zoning, characterized by Ba-rich cores and Ba-poor rims, indicating a compatible behaviour of Ba in the studied systems. Zoning in phengite is governed primarily by the celadonite (tschermak) exchange vector ((Mg,Fe)Si-(Al)_-2), with more moderate contributions of the celsian (BaAl-(KSi)_-1) and paragonite (NaK_-1) exchange vectors. Late remobilization of Ba at relatively low temperature formed retrograde celsian. The compatible behaviour of Ba in the studied rocks strengthens the importance of the stability of phengite for the transfer of LIL elements from the subduction to the volcanic arc environments.     

A quantitative reconstruction of organic matter and nutrient diagenesis in Mediterranean Sea sediments over the Holocene

A multicomponent diagenetic model was developed and applied to reconstruct the conditions under which the most recent sapropel, S1, was deposited in the eastern Mediterranean Sea. Simulations demonstrate that bottom waters must have been anoxic and sulphidic during the formation of S1 and that organic matter deposition was approximately three times higher than at present. Nevertheless, most present day sediment and pore water profiles — with the exception of pyrite, iron oxyhydroxides, iron-bound phosphorus and phosphate — can be reproduced under a wide range of redox conditions during formation of S1 by varying the depositional flux of organic carbon. As a result, paleoredox indicators (e.g., C_org:S ratio, C_org:P_org ratio, trace metals) are needed when assessing the contribution of oxygen-depletion and enhanced primary production to the formation of organic-rich layers in the geological record. Furthermore, simulations show that the organic carbon concentration in sediments is a direct proxy for export production under anoxic bottom waters.The model is also used to examine the post-depositional alteration of the organic-rich layer focussing on nitrogen, phosphorus, and organic carbon dynamics. After sapropel formation, remineralisation is dominated by aerobic respiration at a rate that is inversely proportional to the time since bottom waters became oxic once again. A sensitivity analysis was undertaken to identify the most pertinent parameters in regulating the oxidation of sapropels, demonstrating that variations in sedimentation rate, depositional flux of organic carbon during sapropel formation, bottom water oxygen concentration, and porosity have the largest impact. Simulations reveal that sedimentary nutrient cycling was markedly different during the formation of S1, as well as after reoxygenation of bottom waters. Accumulation of organic nitrogen in sediments doubled during sapropel deposition, representing a significant nitrogen sink. Following reventilation of deep waters, N₂ production by denitrification was almost 12 times greater than present day values. Phosphorus cycling also exhibits a strong redox sensitivity. The benthic efflux of phosphate was up to 3.5 times higher during the formation of S1 than at present due to elevated depositional fluxes of organic matter coupled with enhanced remineralisation of organic phosphorus. Reoxygenation of bottom waters leads to a large phosphate pulse to the water column that declines rapidly with time due to rapid oxidation of organic material. The oxidation of pyrite at the redox front forms iron oxyhydroxides that bind phosphorus and, thus, attenuate the benthic phosphate efflux. These results underscore the contrasting effects of oxygen-depletion on sedimentary nitrogen and phosphorus cycling. The simulations also confirm that the current conceptual paradigm of sapropel formation and oxidation is valid and quantitatively coherent.     

Submarine hydrothermal activity and gold-rich mineralization at Brothers Volcano, Kermadec Arc, New Zealand

Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO₄ and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO₂ (e.g., 206?mM/kg at the Cone site); high CO₂/³He; negative ??D and ??¹⁸O_H2O for vent fluids; negative ??³⁴S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??¹⁵N₂ (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in ³He/⁴He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members.     

加拿大原型产地矿物种名称的中文译名

加拿大原型产地的矿物种数计208种,其中118个是具有人名或地名意义的矿物种名。这些矿物的现中文译名多数采用化学成分名称,未能体现原作者的意愿,与IMA-CNMNC关于新矿物的命名原则和译名规则不相符合。本文根据英文的人名与地名,采用音译方法,列举这些矿物的英文名称、原命名依据和现中文译名,并列出新的建议中文译名。