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51.
Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C. 相似文献
52.
Kazem Kazemi Ali Kananian Yilin Xiao Fatemeh Sarjoughian 《Arabian Journal of Geosciences》2018,11(22):717
The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe3+?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H2O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent. 相似文献
53.
Nicola Nocilla Aldo Evangelista Anna Scotto di Santolo 《Rock Mechanics and Rock Engineering》2009,42(5):815-833
In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations
and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte
Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic
limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency
towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks
on the cliff faces (V
0) and fallen blocks on the slopes (V
f). It was assumed that the ratio V
f/V
0 decreases with the distance (x
f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated
by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering
perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation
measures. 相似文献
54.
松辽盆地东缘下白垩统营城组二段火山碎屑岩的发育特征 总被引:1,自引:0,他引:1
通过精细的野外剖面测量,发现松辽盆地东缘营城组二段中发育熔岩、凝灰岩和凝灰质砂岩。凝灰岩包括熔结凝灰岩、岩屑晶屑凝灰岩、灰球泥粒凝灰岩和角砾凝灰岩。这表明作为火山活动间歇期的营城组二段沉积期依然存在一定规模的火山活动,其沉积作用具有独特的火山和沉积双重控制的特点,区别于正常的沉积作用。营城组二段是一套介于火山岩和陆源碎屑岩之间的过渡岩性,物源既有来自同期火山喷发,也有来自营城组一段和营城组下段以及更老的地层的风化剥蚀。由于存在火山物质和陆源剥蚀物质的双重物源及存在火山物质堆积和沉积作用的双重机理,这套岩石在类型上具有特殊性。存在特殊的火山-沉积作用类型,主要为冲积平原上热碎屑流河道沉积、冲积平原泛滥盆地上热基浪沉积、冲积平原泛滥盆地上空落火山灰云沉积。 相似文献
55.
Lin-gun Liu C.-C. Lin Y. J. Yung T. P. Mernagh T. Irifune 《Physics and Chemistry of Minerals》2009,36(3):143-149
K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of
the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric
pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing
temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands
appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition
is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed
earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase,
microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure. 相似文献
56.
Shovan Lal Chattoraj Santanu Banerjee P. K. Saraswati 《Journal of the Geological Society of India》2009,73(4):567-574
Glauconitic minerals are considered as one of the valuable input parameters in sequence stratigraphic analysis of a basin.
In the present study glauconitic minerals are reported from subtidal green shale facies in the lower part of the Late Paleocene-Early
Eocene Naredi Formation of western Kutch. On the basis of the foraminiferal assemblage the glauconite bearing beds are interpreted
to have formed in a mid shelf depositional settings of an unstable marine conditions. XRD studies confirm the glauconite mineralogy
of the green pellets and provide an estimation of glauconite maturity. Textural attributes of the glauconites confirm their
derivation by different degrees of alteration of precursor feldspar grains. Because of the authigenic origin and autochthonous
nature, these glauconites hold promise for understanding sequence stratigraphy of the Palaeogene succession of the western
Kutch. 相似文献
57.
58.
59.
It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E4/E6 ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches. 相似文献
60.
橄榄石既是上地幔的主要矿物,又是俯冲板块的主要矿物。在正常地幔温度条件下,橄榄石中原子之间的振动是非谐振动,这已成为学界共识;然而,对于俯冲带的较低温情况,橄榄石中原子之间的振动的非谐性是否重要,目前还没有比较一致的结论。本研究利用透射红外光谱的方法,系统研究了室温下不同厚度橄榄石中硅氧四面体的红外光谱特征,并着重对其在2100~1500cm-1区域形成的二倍频峰/合频峰进行了指认。在此基础上,本研究通过采集不同温度下的透射红外光谱数据(最高温度达约450℃),确立了橄榄石中硅氧四面体的相应基频峰及二倍频峰峰位对温度的依赖性,进而得出其相应红外振动的非谐系数(χ)随温度(T)的变化关系,具体为:χ838=6.37(2)×10-7×T+0.0014(1)及χ993=7.86(3)×10-7×T+0.0015(1),其中温度的单位为℃。外推到600℃时,有χ838=0.0018(1)及χ993=0.0020(2)。这些结果表明,在俯冲带的较低温条件下,橄榄石中硅氧四面体的内部振动的非谐性可能不重要。 相似文献