云南石林世界地质公园阿诗玛石柱碳酸盐岩 显微特征及沉积环境

云南石林世界地质公园阿诗玛石柱,其岩石地层是呈水平产状的中二叠统茅口组厚层块状灰岩,但其构成岩石的具体岩性却未见做过详细工作。笔者等经公园管理部门同意,自下而上分别在阿诗玛石柱背侧底部、下部、中部、上部和顶部共采集样品五块,对其岩石学特征及沉积微相作了详细研究,弄清了这一世界著名景点自下而上的岩石构成及沉积相。底部为高能浅滩相灰色厚层块状具平行层理生屑颗粒灰岩,构成阿诗玛脚部。下部为中能浅潮下灰色厚层块状虫筳生屑泥粒灰岩,构成阿诗玛腿部。中部为中能浅潮下灰色厚层块状砂屑泥粒灰岩,构成阿诗玛腰部。上部为中能浅潮下灰色厚层块状具生物扰动含砂屑生屑泥粒灰岩,构成阿诗玛胸部;顶部为高能浅滩相灰色厚层块状砂屑生屑颗粒灰岩,构成阿诗玛头部。其中含有大量生物化石碎屑:有孔虫、三叶虫、藻类、介形虫、腕足、苔藓虫、虫筳、海百合茎、双壳类,为高能浅滩相和中等能量浅潮下环境。希能为石林形成过程研究和科学普及提供参考。     

王家岗断阶带含烃流体的成藏效应分析

王家岗断阶带及其附近地区地层和地层流体所表现出的能量场和物质两方面的成藏效应,反映其局部地区的油气运移具有瞬态流体流动的特点.在以断层活动为主、以烃源岩超压为辅的双重控制作用下,来自牛庄洼陷内深部烃源岩的超压含烃热流体沿断阶带内的断层向王家岗地区方向快速充注.能量场上,快速的大规模流体流动既引起了地温场的局部扰动,也将深层的超压能量传递到浅层.物质上,溶解有大量矿物质的深部热流体以混相涌流的方式运移到浅层.流体活动强的断层附近区域水-岩相互作用强烈,地层岩石中的碳酸盐质量分数和黏土矿物组成变化较大.同时在深部流体进入浅层活动活跃的层段内,地层水矿化度高的地段聚集的油气也较多.     

非线性支持向量机在油气预测中的应用

油气预测的传统方法通常是基于经验风险最小化准则,但在有限样本情况下,预测效果并不理想.研究引入基于结构化风险最小化准则的非线性支持向量机方法,通过对推广误差界的最小化达到最大的泛化能力和全局最优,时于小样本数据,该方法具有可靠的预测能力.在对四川观音场构造面新统上部碳酸盐岩储层数据处理中.通过实例试算,结果表明该方法有效可靠,预测精度高,与已知结果吻合较好.     

Trace Elements in Fluid Inclusions in the Carlin—Type Gold Deposits,Southwestern Guizhou Province

Fluid inclusions in quartz from the Lannigou and Yata Carlin-type gold deposits in southwestern Guizhou were analyzed by inductively coupled plasma-mass spectrometry for their trace elements(Co,Ni,Cu,Pb,Zn,Pt,etc.).The results show that quartz fluid inclusions entrapped at different ore-forming stages contain higher Co,Ni,Cu,Pb and Zn.It has been found for the first time that the ore-forming fluids responsible for the Carlin-type gold deposits are rich in Pt.From this it can be concluded that basic volcanic rocks seem to be one of the important sources of ore-forming materials for the Carlin-type gold deposits.     

皖南南陵地区砷菱铅矾的发现及初步研究

皖南南陵地区首次发现砷菱铅矾, 砷菱铅矾主要产于交代石英岩的含金氧化带中, 多与石英连生。主要伴生矿物是自然金、辰砂。Ｘ 射线粉晶衍射、化学分析和光学测定手段对该矿物进行了初步的矿物学研究。     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

点苍山-哀牢山变质杂岩带变沉积岩的变质演化

点苍山-哀牢山变质杂岩带位于青藏高原东南缘大理-元江-元阳-河口一带,出露规模达数百千米,是扬子板块和印支陆块之间的一条重要构造带.该变质杂岩带主要由各类正片麻岩、副片麻岩、大理岩所组成,夹有斜长角闪岩、石榴辉石岩和超镁铁质岩石的透镜体或团块.其中,变沉积岩如含夕线石和蓝晶石的片麻岩类岩石保存了多阶段的矿物组合及异常复杂的矿物相转变关系.详细的岩相学、成因矿物学以及矿物相转变关系分析表明,变沉积岩系经历了早期进变质阶段(M1)、峰期角闪-麻粒岩相变质阶段(M2)、峰后近等温减压(脱水熔融)阶段(M3)以及晚期退变质阶段(M4)的变质演化.其中,M1阶段的稳定矿物组合为石榴石+斜长石+白云母+石英+十字石±蓝晶石±黑云母±钾长石,M2阶段的稳定矿物组合为石榴石+黑云母+蓝晶石/夕线石+斜长石+石英、石榴石+黑云母+斜长石+石英±钾长石±夕线石,M3阶段的共生矿物组合为石榴石+黑云母+夕线石+斜长石+石英,M4阶段的矿物组合为黑云母+白云母+斜长石+石英±钾长石±石榴石等.通过传统GB-GASP温压计和二云母温度计的估算结果,配合P-T视剖面定量计算,确定早期进变质阶段(M1)的温压条件为T=560 ～ 590℃,P=5.5 ～6.3kb,峰期角闪-麻粒岩相阶段(M2)的温压条件为T=720～ 760℃、P=8.0～9.3kb,峰后近等温减压阶段(M3)的温度压力条件为T=640～760℃,P=5.0～7.3kb,晚期退变阶段(M4)的温压条件为T=521～648℃,P=4.0～5.0kb.上述研究结果表明,点苍山-哀牢山变沉积岩记录了典型碰撞造山带型式的顺时针P-T演化轨迹,表明点苍山-哀牢山变质杂岩带的形成与印度板块和欧亚板块之间的俯冲-碰撞存在密切的成因关系.     

基于残余强度修正的岩石损伤软化统计本构模型研究

岩石随着围压的增大,残余强度的增加幅度比峰值强度大,残余强度逐渐成为影响岩石全应力-应变曲线峰后段的主要因素,因此,建立岩石损伤软化统计本构模型时,对残余强度进行修正是非常必要的。基于岩石应变强度理论以及岩石微元强度服从Weibull随机分布的假设,考虑岩石峰后残余强度对损伤变量进行修正,在微元破坏符合Hoek-Brown屈服准则条件下,建立了能够反映岩石峰后软化特征的三维损伤统计本构模型;依据岩石试验全应力-应变曲线的几何特征,推导出本构模型参数的数学表达式,并基于花岗岩室内试验数据对模型参数进行探讨,研究了Weibull分布参数与本构模型的关系,探讨了损伤修正系数的取值和岩石累积损伤的扩展过程;将建立的本构模型理论曲线与4种岩石（斑状二长花岗岩、细晶大理岩、砂岩和粉砂质泥岩）不同围压下的常规三轴压缩试验曲线进行对比分析,结果表明,该模型能很好地描述岩石破裂过程的全应力-应变关系和表征岩石残余强度特征。这对于岩石损伤软化问题以及岩石加固处理措施的研究均具有重要的意义。     

平南幔源包体中橄榄石的显微构造研究及其意义

平南玄武岩中的尖晶石二辉橄榄岩包体的平衡温度为930~980℃, 平衡深度为59~74km, 包体中橄榄石的扭折带滑移系多为(010) [100], 但也有(001) [100]的滑移系类型; 斜方辉石的滑移系为(100) [001], 它们均为高温低应变速率下的滑移系, 说明该区的上地幔主要是在高温低应变速率条件下经历了塑性变形作用.橄榄石位错组态多样, 有自由位错、位错壁、位错弓弯、缠结、{110}滑移带, 反映了上地幔的塑性变形特征.根据位错壁的大小估算, 上地幔差异流动应力为24.5~42.1MPa, 流动速率为2.93×10-17~8.36×10-16s-1, 有效粘度为1.72×1023~2.80×1024 Pa·s, 特征与中国东部新生代上地幔较为一致, 反映同处于拉张环境.