Occurrence,distribution and partitioning of nonionic surfactants and pharmaceuticals in the urbanized Long Island Sound Estuary (NY)

This work deals with the environmental distribution of nonionic surfactants (nonylphenol and alcohol ethoxylates), their metabolites (NP, nonylphenol; NPEC, nonylphenol ethoxycarboxylates; and PEG, polyethylene glycols) and a selection of 64 pharmaceuticals in the Long Island Sound (LIS) Estuary which receives important sewage discharges from New York City (NYC). Most target compounds were efficiently removed (>95%) in one wastewater treatment plant monitored, with the exception of NPEC and some specific drugs (e.g., hydrochlorothiazide). Concentrations of surfactants (1.4–4.5 μg L⁻¹) and pharmaceuticals (0.1–0.3 μg L⁻¹) in seawater were influenced by tides and sampling depth, consistent with salinity differences. Surfactants levels in suspended solids samples were higher than 1 μg g⁻¹, whereas only most hydrophobic or positively charged pharmaceuticals could be found (e.g., tamoxifen, clarithromycin). Maximum levels of target compounds in LIS sediments (PEG at highest concentrations, 2.8 μg g⁻¹) were measured nearest NYC, sharply decreasing with distance from major sewage inputs.     

Occurrence and spatial distribution of metals in intertidal sediments of a temperate estuarine system (Bahía Blanca,Argentina)

Intertidal sediments of the inner and middle zone from the Bahía Blanca estuary were sampled for geochemical and environmental assessment of metals (Cd, Cu, Pb, Zn, Mn, Ni, Cr and Fe). Results indicate that both the organic matter content and the sediment grain size plays an important role in controlling the differential concentrations of the metals found in sediments from both zones. For most of the elements (except Mn), sediment metal concentrations were greater in the middle zone, although the concentrations did not exceed the maximums for quality of marine sediments. In this sense, anthropogenic impact (i.e., sewage drain) appears to be a key factor in the distribution of metals within the estuarine system. Comparing the levels obtained with quality levels (LEL and SEL), except Cu that showed levels slightly above the LEL, the rest of the concentrations of metals were lower to those levels. The low metal concentrations obtained within this highly impacted estuarine system suggest that the great volume of water that flooding the extensive flats in each tidal cycle has much importance. Although the potential risks of metals to the estuarine environment were low, taking into account the toxicity of some of these metals, continuity of monitoring is highly recommended.     

Hydrogeological characterization of carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias,N Spain) by means of geochemical and isotopic techniques

Chemical and isotopic analyses of groundwater from the carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias, northern Spain) were carried out. Nine springs were sampled to determine major cations and anions, as well as the stable isotopes of the water molecule (δ²H and δ¹⁸O) and sulphate (δ³⁴S) values. Also, δ³⁴S values from gypsum coming both from Triassic rocks and bottom of Jurassic sequence were also determined. The results obtained were used to classify the waters with a genetic criteria in three groups: (1) waters with a high gypsum influence, with sulphate coming from Jurassic gypsum, (2) waters without gypsum influence, where sulphate source could be atmospheric deposition from industrial processes and marine aerosol, and (3) waters with some gypsum influence, in which sulphate origin could be a combination of different sources. In relation to recharge, δ²H and δ¹⁸O values were close to those of Global Meteoric Water Line and fit a local line that suggests a meteoric origin. The estimated elevations for spring recharge are in agreement with those obtained from hydrogeological maps.     

Determination of heterogeneities in the hydraulic properties of a phreatic aquifer from tidal level fluctuations: a case in Argentina

A well-known analytical solution of Jacob (1950) for groundwater flow due to tidal-wave propagation, together with field measurements along a complete tidal cycle and geological data, were used to evaluate the heterogeneities in the hydraulic properties of a phreatic aquifer located next to the River Ajo in the coastal plain environment of the southern sector of the Samborombon Bay wetland, Argentina. From the analysis of water-table fluctuations in a set of monitoring wells located along a riverbank-normal transect, it was possible to quantify the piecewise spatial variations of the hydraulic diffusivity of the phreatic aquifer. The results show the strong lateral variations of the sedimentary environment due to the influence of the different transport and deposition agents that characterize the coastal plain. The known thickness of the phreatic aquifer and the estimated range of the specific yield allowed the hydraulic conductivity to be identified as the most influential factor. [Jacob CE (1950) Flow of ground water. In: Rouse H (ed) Engineering Hydraulics. Wiley, New York]     

Efficient multivariable submarine depth-control system design

An efficient solution for the multivariable submarine control design at low-depth conditions under the influence of wave disturbances is presented. The analysis and control design process is carried out under the framework of individual channel analysis and design (ICAD), which is based on the multivariable structure function (MSF). Classical frequency-domain control techniques based on Bode and Nyquist plots are used. Robustness is stated in terms of gain and phase margins. The closed-loop system includes low-order diagonal controllers facilitating its implementation, assessment, and tuning. ICAD discloses new physical insights of the submarine dynamical behaviour. Previous designs based on diagonal controllers consider the input–output channels defined by pairing the bow hydroplane angle with the depth and the stern hydroplane angle with the pitch angle. The alternative input–output pairing leads to unstable closed-loop systems. This phenomenon is associated with hydroplane reverse control. Here it is shown that MSF-based diagonal controllers can be applied effectively for both sets of channel configurations. Emphasis is placed on satisfying design specifications aiming at maintaining the depth low. The solution presented is more feasible and clearer to apply in practice than those so far reported in the literature.     

Construction and assessment of a logistic regression model applied to short-term forecasting of thunderstorms in León (Spain)

Forecasting thunderstorms is one of the most difficult tasks in weather prediction due to the scarce knowledge on how to characterise the mechanisms taking part in the formation of thunderstorms. New tools based upon the objective recognition of appropriate conceptual models have been developed in the last years. A good example of this are the statistical models, based on variables that characterise the preconvective atmospheric conditions.This paper presents the results obtained by applying a short-term forecast model to thunderstorms during the summer periods in León (Spain). This model makes use of the logistic function as a binary forecasting technique determining storm/no storm. The logistic function used was a combination of 15 previously selected meteorological variables. The model has been constructed with the data collected on 152 occasions, and it has been verified on 77 other occasions.The skill scores obtained show that the use of statistical models combining the data, provided by variables characterizing the preconvective conditions and the triggering mechanisms, represent an important step in the difficult task of short-term thunderstorm forecasting.     

A short-term forecast model for hail

Predicting the occurrence of hailstorms is one of the most complicated tasks in weather forecasting because of the small area of land that is usually affected, and because of the short time hail events last. Today there are a number of parameters available that may be used to characterize preconvective conditions and predict the beginning of convection. However, forecast models based on stability indices should be developed separately for each geographic area.The databases available were used in this study with two aims in mind: determining which meteorological variables or indices obtained from a radiosonde in the study zone are more relevant in characterizing preconvective conditions; and, secondly, setting up an objective short-term forecast model for storms on the basis of one or more meteorological parameters.The logistic regression was used to establish the dichotomy risk/no risk of storms. A function was developed combining seven meteorological variables. The results show that the forecast model has a Probability of Detection of 0.87 and a False Alarm Ratio of 0.18.     

Determination of Te,As, Bi,Sb and Se (TABS) in Geological Reference Materials and GeoPT Proficiency Test Materials by Hydride Generation‐Atomic Fluorescence Spectrometry (HG‐AFS)

The study of Te, As, Bi, Sb and Se (TABS) has increased over the past years due to their use in the development of low‐carbon energy technologies. However, there is a scarcity of mass fraction values of TABS in geological reference materials. This underlines the difficulty in undertaking routine determinations of these elements. The mass fractions of TABS were determined in geological reference materials using hydride generation‐atomic fluorescence spectrometry (HG‐AFS), calibrated with standard solutions. Comparisons with literature values were used to validate the method. Samples from the GeoPT proficiency test were also analysed. For most elements, there are no assigned or even provisional values for many of the GeoPT and reference materials because of the wide range of results reported. For mass fractions above the quantification limit of the method, our results are in good agreement with the median of GeoPT results. Thus, we propose GeoPT median values as informational values for these elements. In contrast, at mass fractions < 0.5 µg g^?1 median values of Se from GeoPT are systematically higher than our results. Our Se results are in agreement with the reference materials down to 0.02 µg g^?1, which suggest that many of the results for Se reported in GeoPT testing are too high.