Spatial and temporal distribution of cadmium and copper in water and zooplankton in the Bahía Blanca estuary,Argentina

Cadmium and copper in the dissolved and particulate phase and in zooplankton were determined in the Bahía Blanca estuary during six surveys from March to December 2005. Temperature, pH, salinity, dissolved oxygen, suspended particulate matter, particulate organic matter and chlorophyll-a were also considered. Dissolved Cd was below the detection limit (0.2 μg L⁻¹) for almost the entire study period whereas Cu concentrations (0.5–2.4 μg L⁻¹) indicated a continuous dissolved Cu input. Particulate Cd concentrations ranged from below the detection limit (<0.01) to 28.6 μg g⁻¹ d.w. while particulate Cu ranged from below the detection limit (<0.04) to 53.5 μg g⁻¹ d.w. Cd in mesozooplankton ranged from below the detection limit (<0.01) to 37.4 μg g⁻¹ d.w. Some of the Cd levels were higher than those reported for other aquatic ecosystems. Cu in the mesozooplankton ranged from 1.3 to 89.3 μg g⁻¹ d.w., values which were within the reported values or higher than other studies. The log of the partition coefficients (log (K_d)) of Cd was 0.04, while log (K_d) for Cu ranged from −0.39 to 2.79. These values were lower than both those calculated for other estuaries and the typical coefficients for marine environments. The log of the bioconcentration factor (log BCF) of Cd was 1.78, indicating that Cd concentration was higher in the zooplankton than in the dissolved phase. Log BCF of Cu ranged from 1.15 to 3. The logs of the biomagnification factors (log BMF) of Cd were low, with a range between −3.45 and 2.21 and those for Cu ranged from −0.1 to 3.35. Positive values indicate biomagnification while negative values indicate biodiminution. In general, no significant dissolved Cd concentration appeared to be present in the Bahía Blanca estuary and Cu values did not indicate a critical environmental status. The particulate phase seemed to be the major carrier for Cd and Cu and TPCu values were within the normal values for an anthropogenically stressed estuary but not for a strongly polluted system. This fraction was the most important metal source for the mesozooplankton. Moreover, the highest metal concentrations were in the mesozooplankton since most of the bioconcentration and biomagnification factors were positive, especially for Cu.     

Efficient multivariable submarine depth-control system design

An efficient solution for the multivariable submarine control design at low-depth conditions under the influence of wave disturbances is presented. The analysis and control design process is carried out under the framework of individual channel analysis and design (ICAD), which is based on the multivariable structure function (MSF). Classical frequency-domain control techniques based on Bode and Nyquist plots are used. Robustness is stated in terms of gain and phase margins. The closed-loop system includes low-order diagonal controllers facilitating its implementation, assessment, and tuning. ICAD discloses new physical insights of the submarine dynamical behaviour. Previous designs based on diagonal controllers consider the input–output channels defined by pairing the bow hydroplane angle with the depth and the stern hydroplane angle with the pitch angle. The alternative input–output pairing leads to unstable closed-loop systems. This phenomenon is associated with hydroplane reverse control. Here it is shown that MSF-based diagonal controllers can be applied effectively for both sets of channel configurations. Emphasis is placed on satisfying design specifications aiming at maintaining the depth low. The solution presented is more feasible and clearer to apply in practice than those so far reported in the literature.     

Nature and origin of the BIF-hosted São Bento gold deposit, Quadrilátero Ferrífero, Brazil, with special emphasis on structural controls

The orogenic banded iron formation (BIF)-hosted Au mineralization at São Bento is a structurally-controlled, hydrothermal deposit hosted by Archean rocks of the Rio das Velhas greenstone belt, Quadrilátero Ferrífero region, Brazil. The deposit has reserves of 14.3 t Au and historical (underground) production of 44.6 t Au between 1987 and 2001. The oxide-facies São Bento BIF is mineralized at its lower portion, where in contact with carbonaceous, pelitic schists, particularly in the proximity of sulfide-bearing quartz veins. Shear-related Au deposition is associated with the pervasive, hydrothermal sulfidation (mainly arsenopyrite) of the Fe-rich bands of the São Bento BIF. Auriferous, sulfide- and quartz-rich zones represent proximal alteration zones. They are enveloped by ankerite-dominated haloes, which reflect progressive substitution of siderite and magnetite within the BIF by ankerite and pyrrhotite, respectively. The São Bento BIF was intensely and extensively deformed, first into open, upright folds that evolved into tight, asymmetric, isoclinal folds. The inverse limb of these folds attenuated and gave way to sheath folds and the establishment of ductile thrusts. Mineralized horizons at São Bento result from early structural modifications imposed by major transcurrent and thrusts faults, comprising the Conceição, Barão de Cocais and São Bento shear zones. Dextral movement on the SW–NE-directed Conceição shear zone may have generated splays at a compressional side-stepping zone, such as the São Bento shear zone, which is the structural locus for the São Bento gold mineralization. Relaxation of the Conceição shear zone under more brittle conditions resulted in the development of dilatational zones where gold–sulfide–quartz veins formed. These structures are considered to have been generated in the Archean. Geochronological data are scarce, with Pb–Pb analyses of refractory arsenopyrite and pyrite from bedded and remobilized ore plotting on a single-stage growth curve at 2.65 Ga. A later compressional, ductile deformation of unknown age overprinted, rotated and flattened the original, N60E-directed structure of the whole rock succession, with development of planar and linear fabrics that appear similar to Proterozoic-aged structures. Fluid inclusion studies indicate low salinity, aqueous fluids, with or without CO₂ and/or CH₄, with extremely variable CO₂/CH₄ ratios, of probable metamorphic origin. Fluid evolution shows a paragenetic decrease in the carbonic phase from 10–15% to 5%, and increase in the H₂O/(CO₂ + CH₄) and CO₂/CH₄ ratios, suggesting important interaction with carbonaceous sediment. Trapping conditions indicate a temperature of 300 °C at 3.2 kbar.     

Ages and metallicities of five intermediate-age star clusters projected towards the Small Magellanic Cloud

Colour–magnitude diagrams are presented for the first time for L32, L38, K28 (L43), K44 (L68) and L116, which are clusters projected on to the outer parts of the Small Magellanic Cloud (SMC). The photometry was carried out in the Washington system C and T ₁ filters, allowing the determination of ages by means of the magnitude difference between the red giant clump and the main-sequence turn-off, and metallicities from the red giant branch locus. The clusters have ages in the range 2–6 Gyr , and metallicities in the range −1.65<[Fe/H]<−1.10, increasing the sample of intermediate-age clusters in the SMC. L116, the outermost cluster projected on to the SMC, is a foreground cluster, and somewhat closer to us than the Large Magellanic Cloud. Our results, combined with those for other clusters in the literature, show epochs of sudden chemical enrichment in the age–metallicity plane, which favour a bursting star formation history as opposed to a continuous one for the SMC.     

Behavior of the fresh- and saline-water phases in an urban area in Western Buenos Aires Province, Argentina

Given the particular hydrogeological setting at Salliqueló County, Western Buenos Aires Province, Argentina, this paper places attention on the lens that supplies fresh water to its capital, Salliqueló. This lens constitutes the most important fresh-water reservoir in the county. It overlies saline waters, and is recharged through high-permeability sandy sediments at a rate that exceeds by far the actual water demand. Restrictions in exploitation are not limited by the total requirement but rather by the flows extracted from individual wells that may generate up-coning of saline waters, with a resulting overall deterioration in quality of the pumped water. The variations in the position of the interface between saline and fresh waters, as related to the change in extraction rates, were obtained by means of a simulation of the flow of two fluids of different densities. Finally, based on the general hydrogeological characterization and on the simulation results, various methods for the management of these fresh-water resources are proposed, such as the deactivation of urban supply wells, the monitoring of the saline interface position, and the establishment of a protection perimeter for the water-supply wells.

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Resumen Enmarcado dentro de las características hidrogeológicas generales del partido de Salliqueló, oeste de la provincia de Buenos Aires, Argentina, este trabajo se centra en la lente que abastece de agua dulce a Salliqueló, la capital del partido. Esta lente constituye la reserva de agua dulce más importante del partido, se ubica sobre aguas salinas y es recargada a través de sedimentos arenosos de alta permeabilidad a una tasa que excede grandemente los requerimientos de la población. Sin embargo, las restricciones en la explotación no están dadas por las demandas totales sino por las extracciones en perforaciones individuales, que pueden generar ascensos de agua salina con el consiguiente deterioro en la calidad del agua extraída. Las variaciones de la posición de la interfase respecto de los cambios en la explotación fueron obtenidas por medio de la simulación del flujo de dos fluidos de diferente densidad. Finalmente, con base en la caracterización hidrogeológica general y en los resultados de la simulación, se proponen varias medidas para la protección del recurso hídrico, tales como: la desactivación de los pozos de abastecimiento en el ámbito urbano, el control de la posición de la interfase salina y la definición de perímetros de protección de los pozos de abastecimiento, entre otras.

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Résumé Etant donné les particularités hydrogéologiques de la région de Salliqueló, ouest de la province de Buenos Aires, Argentine, cet article traite de la lentille deau douce alimentant en eau potable la capitale, Salliqueló. Cette lentille constitue la réserve la plus importante deau douce de la région. Elle se superpose aux eaux salées et est rechargée via les sédiments sableux et perméables, à un taux dépassant largement la demande actuelle en eau. Les restrictions dans lexploitation ne sont pas limitées par la demande totale mais par les débits extraits des forages privés, qui pourraient générer des rabattements induisant des arrivées deaux salées, arrivées qui peuvent dégrader la ressource pompée. Les variations de la position de linterface eau douce–eau salée, en relation avec les taux dexploitation, ont été obtenues en simulant lécoulement de deux fluides de différentes densités. Finalement, sur base dune caractérisation hydrogéologique et des résultats de la simulation, des méthodes variées pour la gestion de la ressource en eau douce sont proposées, entre autre, la désactivation de pompages urbains, suivi de linterface eau douce–eau salée, et la mise en place de zones de protections des captages deau souterraine.

     

Hydrothermal alteration and fluid inclusion study of the Lower Cretaceous porphyry Cu–Au deposit of Tiámaro, Michoacán, Mexico

The Tiámaro deposit in Michoacán state has been dated as Lower Cretaceous (Valanginian), though most of the porphyry deposits in central Mexico were dated or have an attributed Eocene–Oligocene age. The host rocks belong to a volcanoplutonic complex overlain by red conglomerates. These rocks were intruded by pre-Valanginian plutonic and hypabissal rocks. Propylitic, phyllic, and argillic alteration assemblages developed, and their superimposition draws the evolution of the deposit. Stage I is represented by propylitic assemblages, stage II contains the main ore forming stockworks and both phyllic and argillic assemblages, and stage III contains late carbonatization assemblages. The obtained temperatures and salinities from inclusion fluids are low for a porphyry-type deposit, but we interpret that the known part of the deposit represents the shallow portion of a bigger deposit. The evolution of mineralizing fluids draws a dilution trend of brines from “porphyry-like” to “epithermal-like” stages. The richest ore zone is roughly located between the 300 and 350 °C isotherms, though unnoticed resources may occur at depth.     

LOST CITY METEORITE: DETERMINATION OF THE TEMPERATURE GRADIENT INDUCED BY ATMOSPHERIC FRICTION USING THERMOLUMINESCENCE

The temperature gradient induced in the Lost City meteorite during its nine-second flight through the atmosphere has been determined from measurements of the variations in the natural TL output of the meteorite with depth below the surface of the specimen. The rate of temperature change decreases about 5 °C per mm in the range of 4 mm to 15 mm below its surface. Although temperatures above 205 °C penetrated only the outer 4 mm of the meteorite, temperatures higher than 120 °C penetrated as far as 20 mm below its surface.     

Measurement of air temperature in the presence of a large radiant flux: an assessment of passively ventilated thermometer screens

The energy balance of small temperature sensors was modelled to illustrate the effects of sensor characteristics, particularly size, on the accuracy of readings in the presence of strong shortwave or longwave radiant loads. For all but extremely small sensors, radiant exchange may lead to unacceptable errors. The common practice of using passively ventilated instrument screens was evaluated in a series of comparative measurements. The differences resulting from the use of different models of shields may be an order of magnitude greater than the error resulting from sensor calibration. In the absence of technological innovation capable of reducing the error due to radiant exchange to negligible proportions, it is suggested that a standard methodology for calibrating and labelling the error resulting from the characteristics of the screens be adopted, to allow comparison of new data with long-established records.     

Late-Glacial History of Lago Argentino, Argentina, and Age of the Puerto Bandera Moraines

In the west-central part of Lago Argentino, the Puerto Bandera moraines are clearly detached from longer, more prominent moraines of the last glaciation and from shorter and smaller Neoglacial moraines. Scientists have long speculated about the age of the Puerto Bandera moraines. Detailed geomorphologic studies in the western area of Lago Argentino, including stratigraphic profiles at Bahía del Quemado in the northern branch (Brazo Norte), indicate that the Puerto Bandera moraines were deposited by three pulses of ice. Each of the three pulses is represented by single moraine ridges and belts of tightly arranged ridges. The timing of the three glacier advances was established by radiocarbon dating, including data published by John Mercer. The oldest moraine system, formed during the Puerto Bandera I substade, was deposited ca. 13,000 ¹⁴C yr B.P. Moraines of the Puerto Bandera II substade were deposited ca. 11,000 ¹⁴C yr B.P. The youngest moraine system was deposited during a minor readvance, shortly before 10,390 C¹⁴ yr B.P., and thus appears to have occurred some time during the European Younger Dryas interval. After this third substade, the ice tongues retreated into the interior branches of Lago Argentino and have remained there since. Evidence found at Bahía del Quemado, together with data provided by other authors, attests to a significant climatic change by the middle Holocene, which we believe occurred during the Herminita advance, the first Holocene glacial readvance recognized within the area.     

Abundance,Tidal Movement,Population Structure and Burrowing Rate of Emerita analoga (Anomura,Hippidae) at a Dissipative and a Reflective Sandy Beach in South Central Chile

Abstract. To evaluate the effects of beach morphodynamics upon the abundance, tidal movement, population structure and burrowing rate of the crab Emerita analoga (Stimpson) (Anomura, Hippidae) we sampled two beaches in south central Chile (ca. 42° S), Mar Brava and Ahui with dissipative and reflective characteristics, res­pectively. The swash zone at the dissipative beach was 5 – 6 times wider than that of the reflective beach. A at the dissipative beach, upwash speeds were higher and the number of effluent line crossings were lower by more than an order of magnitude. To examine the tidal movement of E. analoga, we collected crabs from 5 to 6 tidal levels of each beach every 2 h across 12 h of the tidal cycle. The intertidal distribution of crabs differed between beaches; i. e., at the dissipative beach they were primarily located at the swash zone, while at the reflective beach they were mostly located at the low tide level and shallow subtidal. The change in position of crabs was pronounced across the tidal cycle at the dissipative beach (Mar Brava), with most of the animals remaining in the active swash zone. Body size data were used to construct size frequency distributions for each population. Crabs from the dissipative beach reached larger sizes than those at the reflective beach. Sediments were coarser at the latter versus the former beach. Crabs burrowed at similar rates in the sand from both beaches, a result which supports the idea that E. analoga is a “sediment generalist” capable of burrowing successfully in a wide range of sediment types. This characteristic is likely a key to the broad success of this species on the full range of beach morphodynamic types along the coasts of South and North America.