柴达木盆地深层钾盐察ZK02孔施工工艺

柴达木盆地察汗斯拉图矿区蕴藏着极为丰富的钾盐类矿产资源。钾盐察ZK02孔设计1500 m,钻遇地层为新近系盐湖相沉积地层。在钻进过程中易产生缩径、造浆、掉块、坍塌等现象,钻遇盐岩层或含钙、镁离子盐水入侵时,钻井液性能易发生变化,给钻探施工带了困难。根据盐矿钻孔地质条件和技术要求,设计3级口径的钻孔结构。在施工中,针对巨厚层砂砾碎屑岩的特点,选择加重卤水钻井液护壁,起到了安全护壁效果,并采用研制的卤水钻井液混合搅拌器,提高了配浆速度,保证了钻井液性能和质量。卤水钻井液和卤水钻井液混合搅拌器的使用,为柴达木盆地深层卤水钾盐矿区的钻探施工探索出了快速配制钻井液提供了借鉴。     

王坡井田煤层气井部署方法研究

王坡煤矿是高瓦斯矿井,已有的井下瓦斯抽排不能满足矿井安全生产的要求,迫切需要通过地面抽采来缓解。在已有地质成果基础上,采用煤层气藏数值模拟方法,对王坡井田地面煤层气抽采工程部署方案进行优化。结果表明:A区块是井田煤层气开发试验首选区,以梅花形井网作为试验井网,井间距300m×250m,井网长轴方向60°。这种布井方式在工程实践中取得了较好效果,具有较大的推广价值。     

Investigating soil thermodynamic parameters of the active layer on the northern Qinghai-Tibetan Plateau

The soil thermodynamic parameters, including thermal conductivity, diffusivity and volumetric capacity within the active layer on the northern Tibetan Plateau, were calculated using the measured data of soil temperature gradient, heat flux, and moisture at four stations from October 2003 to September 2004. The results showed that the soil thermodynamic parameters exhibited clear seasonal fluctuation. The thermal conductivity and diffusivity in summer and autumn at Beiluhe, Kexinling, and Tongtianhe were larger than those in winter. The volumetric thermal capacity causes an opposite change; it was larger in autumn and winter than in summer. In spring, the soil thermal conductivity at the Kekexili station was larger than that in summer. Generally, fine-grained soils and lower saturation degrees in the topsoil might be a reason for the lower soil thermal conductivity in winter. For a given soil, soil moisture was the main factor influencing the thermodynamic parameters. The unfrozen water content that existed in frozen soils greatly affected the soil thermal conductivity, whose contribution rate was estimated to be 55 %. The thermodynamic parameters of frozen soils could be expressed as a function of soil temperature, volumetric ice content and soil salinity, while for the unfrozen ground the soil moisture content is the dominant factor for those thermal parameters. As for the soil thermal diffusivity, there exists a critical value of soil moisture content. When the soil moisture content becomes less than a critical value, the soil thermal diffusivity increases as the soil moisture content rises.     

Surface characterization of maize-straw-derived biochars and their sorption performance for MTBE and benzene

Biochars generated at various temperatures might show significant differences in sorption for organic contaminants. In this study, a series of biochars, generated from pyrolyzing maize straws at different temperatures, were systematically characterized. The characterization results showed that with increasing pyrolysis temperature, the surface areas, micropore areas and aromaticity of biochars were enhanced. Batch experiments were conducted to study methyl tert-butyl ether (MTBE) and benzene sorption to biochars. The results indicated that the sorption capacity of benzene to biochars was higher than that of MTBE. The higher pyrolyzed temperature of biochars resulted in a stronger sorption affinity for target compounds, and the dominant sorption mechanisms varied for biochars pyrolyzed at different temperatures. The sorption to biochars pyrolyzed at 700 and 800 °C performed a high adsorption capacity, which indicated that they might be a promising sorbent to remove MTBE and benzene from water. Biochar pyrolyzed at 400 °C showed transitional sorption mechanisms from partition to adsorption for MTBE and benzene. Pore-filling was a possible sorption mechanism to biochars pyrolyzed at high temperature.     

Regional frequency analysis of extreme precipitation and its spatio-temporal characteristics in the Huai River Basin, China

With the increasing exposure of populations and economy to natural hazards, the spatio-temporal characteristics of extreme rainfall remain a key subject of study. Based on annual maximum rainfall (AM) and peaks over threshold rainfall series at 30 meteorological stations during 1960–2011 in the Huai River Basin (HRB), spatio-temporal characteristics of extreme rainfall are analyzed through regional frequency analysis method using L-moments. The accuracy and uncertainty analysis of quantile estimations are also carried out, and the regional and at-site frequency analyses are compared. Results indicate the following: (1) During 1960–2011, AM precipitation at 20 stations in the HRB shows an increasing trend, while at the other 10 stations, it shows a decreasing trend. And both the increased and decreased trends are not significant. (2) The HRB can be categorized into three homogeneous regions via cluster analysis. For both at-site and regional frequency analyses, the root mean square error values increase with the increase in return periods. The estimations are reliable enough for the return periods of less than 100 years. The quantile estimates of large return period from regional frequency analysis are more accurate and have smaller uncertainty than those from at-site frequency analysis. (3) Extreme precipitation in the HRB concentrates in the upstream of the Huai River and YiShuSi water system in the east of the HRB. Generally, the area with extreme precipitation, especially the upper reaches of the Huai River and Yimeng Mountain areas, also has large standard variations of extreme precipitation, which will increase the risk of natural hazards.     

Hazardous geology zoning and influence factors in the near-shore shallow strata and seabed surface of the modern Yellow River Delta,China

In this study, on the basis of 3,200 km shallow stratigraphic section and side-scan sonar data of the coastal area of the Yellow River Delta, we delineated and interpreted a total of seven types of typical hazardous geologies, including the hazardous geology in the shallow strata (buried ancient channel and strata disturbance) and hazardous geology in the seabed surface strata (pit, erosive residual body, sand patch, sand wave and scour channel). We selected eight parameters representing the development scale of the hazardous geology as the zoning indexes, including the number of hazardous geology types, pit depth, height of erosive residual body, length of scour channel, area of sand patch, length of sand wave, width of the buried ancient channel and depth of strata disturbance, and implemented the grid processing of the research area to calculate the arithmetic sum of the zoning indexes of each unit grid one by one. We then adopted the clustering analysis method to divide the near-shore waters of the Yellow River Delta into five hazardous geology areas, namely the serious erosion disaster area controlled by Diaokou lobe waves, hazardous geology area of multi-disasters under the combined action of the Shenxiangou lobe river wave flow, accumulation type hazardous geology area controlled by the current estuary river, hazardous geology area of single disaster in the deep water area and potential hazardous geology area of the Chengdao Oilfield. All four of the main factors affecting the development of hazardous geology, namely the diffusion and movement of sediment flux of the Yellow River water entering the sea, seabed stability, bottom sediment type and distribution, as well as the marine hydrodynamic characteristics, show significant regional differentiation characteristics and laws. These characteristics and laws are consistent with the above-mentioned zoning results, in which the distribution, scale and genetic mechanism of hazardous geology are considered comprehensively. This indicates that the hazardous geology zoning based on the cluster analysis is a new attempt in research regarding the hazardous geology zoning of the near-shore waters of the modern Yellow River Delta and that this type of zoning has a high level of reasonability.     

基于Budyko假设和分形理论的水沙变化归因识别——以北洛河流域为例

全球气候变化及人类活动深刻影响了区域水文过程,进行水沙变化归因识别对流域生态保护和高质量发展尤为重要。基于Budyko假设和分形理论,采用弹性系数法,对北洛河流域上（丘陵沟壑区）、中（土石山林—高塬沟壑区）、下游（渭北旱塬农区）3种不同地貌和植被类型区1959—2019年的水、沙通量变化进行归因分析。结果表明,北洛河上、中、下游径流量均显著减少,由20世纪60年代的35 mm、32 mm、34 mm,减少到21世纪10年代的19 mm、24 mm、6 mm,60 a减少率分别为0.3 mm a^-1、0.2 mm a^-1、0.4 mm a^-1。上游输沙量极显著减少,中游降低趋势不显著,下游显著减少,由20世纪60年代的99×10⁶ t、8×10⁶ t、3×10⁶ t,减少到21世纪10年代的10×10⁶ t、3×10⁶ t、0.3×10⁶ t,60 a减少率分别为1.5×10⁶ t a^-1、0.04×10⁶ t a^-1、0.1×10⁶ t a^-1。20世纪70年代以来,上游径流变化逐渐受人类活动影响,且影响程度逐渐增强,21世纪10年代人类活动贡献率达66.3%;气候变化是中游径流变化的主控因子,21世纪10年代降雨和潜在蒸散发的贡献率分别为77.0%和20.2%;下游径流减少主要为人类活动影响,21世纪10年代其贡献率为64.3%。对比20世纪60年代流域输沙量变化始终受人类活动主导,21世纪10年代人类活动对上、中、下游输沙量减少的贡献率分别为80.7%、59.2%和92.7%。上游人类活动对输沙量减少的贡献中,退耕还林等沟坡措施和沟道工程措施分别为39.0%、42.7%,中、下游人类活动贡献的估算结果反映出高植被覆盖区和农区汲水灌溉对区域水、沙的影响特征。     

中国稀土对外贸易格局演化及影响因素

从中美贸易摩擦到“科技冷战”以来,被誉为“高科技命脉”的稀土,日益成为国际博弈的前沿领域。在此背景下,厘清中国稀土进出口贸易流动态势、把握中国在国际稀土市场中的地位变动,对中国资源安全格局的整体优化和科技自立自强的长久维持具有一定意义。本文基于2008—2018年中国稀土进出口贸易数据、相关国家社会经济政治指标及联合国投票数据,借助相互依存指数、地缘亲和度模型、GIS空间技术以及负二项面板回归等手段,探讨了中国稀土产品对外贸易格局的演化及影响因素。研究发现：① 中国稀土贸易存在较大波动,出口额远大于进口额,整体呈现“升—降—升”发展态势。② 中国稀土进口市场高度集中且路径依赖增强,出口市场逐步多元且路径依赖减弱。中国主要出口具有较高附加值的中、下游产品,进口具有较低附加值的上游矿物类产品。③ 中国在全球稀土贸易相互依存格局中的优势地位整体强化。中国与多数友好型国家间的相互依存关系呈现优化态势,但与美国、加拿大、澳大利亚等分歧型国家之间的相互依存关系呈现恶化态势。④ 国家主体属性、国家间邻近性以及中国的贸易政策、贸易环境等对中国稀土对外贸易产生重要影响。     

气候变化对冰冻圈国家领土博弈的地缘影响

冰冻圈变化的自然过程影响着国家领土博弈地缘关系的建构。基于人地关系思想,以变化-影响-适应为主线建立气候变化影响下冰冻圈国家领土博弈的研究框架,分析自然因素对冰冻圈地缘结构的塑造和对冰冻圈国家身份-利益的建构,以及极地海权、陆权和其他地区领土博弈所形成的双多边地缘关系。研究结果：① 冰冻圈领土博弈地缘结构初步形成。理念层面,自然要素成为气候政治的力量之一,冰冻圈领土博弈体现出传统地缘逻辑;空间层面,气候变化释放极地、高山等新运筹空间,北极、南极成为大国博弈焦点;物质层面,极地海权和陆权利益是大国博弈的主要目标。② 冰冻圈国家身份-利益影响其冰冻圈地缘政治行为,其身份认同的客观基础之一是在冰冻圈分布结构的相对位置。③ 冰冻圈国家领土博弈地缘关系有“趋利”“避害”两类。“利”指为赢得极地海权、陆权,气候变化下西方大国和地区大国开始争夺南北极200海里外大陆架权属,加强极地实质性“硬、软存在”战略布局,美国和丹麦强化格陵兰岛北极战略支点作用;“害”指冰冻圈灾害引起的跨境气候移民等国家利益受损问题。     

“软−硬”关系框架下城市型目的地出入境旅游响应路径——基于1997―2019年中国香港特区数据的组态分析

选取1997―2019年中国香港特区数据,使用定性比较分析（QCA）方法对出入境旅游流产生路径的前因条件以及结果条件进行分析,研究结果表明：① 在路径数量上,虽持续简化,但是仍然具有复杂性;② 在核心条件中,所有的单因素均不构成影响的核心条件,中国香港出入境旅游流路径受到多因素组合作用;③ 在前因条件中,“软?硬”关系影响存在差异,硬实力关系对高出入境旅游流起主导作用,软实力关系则对非高出入境旅游流作用较大;④ 在路径国家（地区）中,高和非高出入境旅游流存在显著地区差异;⑤ 在时间层面上,阶段1与阶段2、阶段3路径差异较大,表明时间节点的分割事件对中国香港出入境旅游的影响不同。