Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

Biosorption of cadmium(II) from aqueous solution onto <Emphasis Type="Italic">Hydrilla verticillata</Emphasis>

Biosorption is an effective method to remove heavy metals from wastewater. In this work, the biosorption of Cd(II) onto Hydrilla verticillata was examined in aqueous solution with parameters of initial pH, adsorbent dosage, contact time, initial Cd(II) concentration, temperature, and co-existing ion. Linear Langmuir and Freundlich models were applied to describe the equilibrium isotherms, and both of the two models were fitted well. The monolayer adsorption capacity of Cd(II) was found to be 50 mg/g at pH 6 and 20°C. Dubinin–Radushkevich isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (11.18 kJ/mol) indicated that the adsorption of Cd(II) onto H. verticillata might be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, including free energy (∆G ⁰), enthalpy (∆H ⁰), and entropy (∆S ⁰) of adsorption, were also calculated. These results showed that the biosorption of Cd(II) onto H. verticillata was a feasible, spontaneous, and exothermic process in nature. Desorption experiments indicated that 0.01 mol/L EDTA and HNO₃ were efficient desorbents for the recovery of Cd(II) from biomass. IR spectrum analysis suggested that amido, hydroxyl, C=O and C–O could combine strongly with Cd(II). EDX spectrum analysis suggested that an ion exchange mechanism might be involved.     

Radium-traced nutrient outwelling from the Subei Shoal to the Yellow Sea: Fluxes and environmental implication

The Subei Shoal is the largest sandy ridge in the southern Yellow Sea and is important source for nutrient loading to the sea. Here, the nutrient fluxes in the Subei Shoal associated with eddy diffusion and submarine groundwater discharge（SGD） were assessed to understand their impacts on the nutrient budget in the Yellow Sea. Based on the analysis of 223 Ra and 224 Ra in the field observation, the offshore eddy diffusivity mixing coefficient and SGD were estimated to be 2.3×10⁸ cm     

半球形多向波聚合波道振荡水柱气室优化设计

为了解决振动水柱式波浪能转换装置收集多向波浪问题,本文设计了半球形多向聚合波道振荡水柱气室结构,以适合远海单点波浪能采集和发电。在规则波正向入射条件下,基于流体仿真分析软件(FLUENT)、流体动力学连续性假设和粘性不可压缩流体动量守恒的运动方程(Navier-Stokes方程)建立半球形振荡气室和三维数值波浪水槽模型。仿真结果表明:增设气室后壁,合理设计波道开口角度实现多向迎波捕获波浪能,优化前壁形状可降低波浪触底反射带来的能量耗散,同时提高了气室内空气压强和出气口速度,有效提升波浪能俘获效率,为后续发电的二次能量转换提供高效的空气动力。     

微塑料添加对小麦苗期生长及干物质分配的影响

土壤环境中微塑料污染已成为全球关注的环境问题。关于微塑料对于植物生长的直接影响和由于土壤理化性状改变的间接影响研究已逐步开展,但针对小麦的研究鲜见报道。试验选择两个旱地小麦品种(甘春27和禾尚头)作为研究对象,选取高密度聚乙烯作为微塑料添加,设置3种质量浓度(0、1、4 g·kg^-1)开展盆栽试验,对不同微塑料组合处理下小麦的出苗率、株高、全株生物量和地上/地下干物质分配进行了分析。结果表明：(1)微塑料添加对两个品种出苗率没有影响。(2)禾尚头在添加1 g·kg^-1微塑料时比添加0、4 g·kg^-1时全株生物量分别高46.7%、8.5%,甘春27在添加1 g·kg^-1微塑料时比添加0、4 g·kg^-1时全株生物量分别高28.7%、17.2%;甘春27整体比禾尚头在3种浓度处理下全株生物量分别高24.9%、9.6%、1.5%。(3)不同试验处理条件下,甘春27将更多的干物质分配在地上植株的构建,其在地下(根系)和地上(茎叶)部分的分配比例整体小于禾尚头。整体上,适度微塑料添加可...     

九江市蓼花剖面末次冰期中晚期沉积的粒度端元特征与气候变化

鄱阳湖湖滨地区广泛分布着晚第四纪风沙沉积序列。在星子县沙岭沙山进行野外调查后选择蓼花剖面开展工作,测试了地质时代和粒度,对粒度结果使用端元分析模型进行研究,探讨该区域末次冰期中晚期的气候变化规律。结果显示：该剖面由湖相-古土壤-沙丘砂等沉积相叠覆堆积组成,形成于末次冰期中晚期（48.8—17.1 ka）。端元分析模型将粒度数据分解出3个不同的粒度端元,不同端元组分在垂向上呈峰谷交替的旋回变化,EM1代表粉砂端元组分,峰值对应湖相和古土壤发育时期;EM2和EM3代表中砂—粗砂端元组分,峰值对应沙丘砂发育期,这些峰谷交替变化的规律指示了末次冰期的季风演变以及气候波动变化,万年尺度上表现为LH10 (48.8—39.9 ka)和LH3～LH5 (28.1—17.1 ka)的冬季风强盛期,分别对应深海氧同位素的MIS3b和MIS2阶段。LH6～LH9 (39.9—28.1 ka)为温暖的夏季风时期,对应深海氧同位素的MIS3a阶段。这些变化与YZ洞石笋氧同位素以及格陵兰冰心有良好的对应,与全球气候变化基本一致。     

Damming of large river by debris flow: Dynamic process and particle composition

The frequency and extent of debris flows have increased tremendously due to the extreme weather and the Wenchuan earthquake on May 12, 2008. Previous studies focused on the debris flow from gullies damming the mountain streams. In this paper, an equation for the run-out distance of debris flow in the main river is proposed based on the dynamic equation of debris flow at different slopes given by Takahashi. By undertaking field investigations and flume experiments, a new calculation method of the volume of debris flow damming large river is obtained. Using the percolation theory and the renormalization group theory it was deduced that the large particles should comprise more than 50% for forming a stable debris flow dam. Hence, the criteria of damming large river by debris flow is presented in terms of run-out distance and grain composition which was then validated through the event of damming river by debris flow at Gaojia gully, the upper reaches of the Minjiang River, Sichuan, China, on July 3, 2011.     

中国科技资源配置效率测度及其时空格局演变特征(英文)

According to the connotation and structure of science and technology resources and some relevant data of more than 286 cities at prefecture level and above during 2001–2010, using modified method—Data Envelopment Analysis(DEA), science and technology(ST) resource allocation efficiency of different cities in different periods has been figured out, which, uncovers the distributional difference and change law of ST resource allocation efficiency from the time-space dimension. Based on that, this paper has analyzed and discussed the spatial distribution pattern and evolution trend of ST resource allocation efficiency in different cities by virtue of the Exploratory Spatial Data Analysis(ESDA). It turned out that:(1) the average of ST resource allocation efficiency in cities at prefecture level and above has always stayed at low levels, moreover, with repeated fluctuations between high and low, which shows a decreasing trend year by year. Besides, the gap between the East and the West is widening.(2) The asymmetrical distribution of ST resource allocation efficiency presents a spatial pattern of successively decreasing from Eastern China, Central China to Western China. The cities whose ST resource allocation efficiency are at higher level and high level take on a cluster distribution, which fits well with the 23 forming urban agglomerations in China.(3) The coupling degree between ST resource allocation efficiency and economic environment assumes a certain positive correlation, but not completely the same. The differentiation of ST resource allocation efficiency is common in regional development, whose existence and evolution are directly or indirectly influenced by and regarded as the reflection of many elements, such as geographical location, the natural endowment and environment of ST resources and so on.(4) In the perspective of the evolution of spatial structure, ST resource allocation efficiency of the cities at prefecture level and above shows a notable spatial autocorrelation, which in every period presents a positive correlation. The spatial distribution of ST resource allocation efficiency in neighboring cities seems to be similar in group, which tends to escalate stepwise. Meanwhile, the whole differentiation of geographical space has a diminishing tendency.(5) Viewed from LISA agglomeration map ofST resource allocation efficiency in different periods, four agglomeration types have changed differently in spatial location and the range of spatial agglomeration. And the continuity of ST resource allocation efficiency in geographical space is gradually increasing.     

南极半岛周边海域表层沉积物粒度分布特征及其环境指示意义

基于南极半岛周边海域表层沉积物调查以及收集的资料,并通过分析表层沉积物粒度数据研究沉积物类型和分布特征,探讨沉积物的变化规律。南极半岛周边海域的沉积物类型比较丰富,主要分为四大类:砾质、砂质、粉砂质以及泥质沉积物;根据不同的水深和地貌单元可分为陆架(或岛架)碎屑沉积物、陆坡(或岛坡)沉积物和深海沉积物。研究区沉积物属于冰海沉积物,并可划分为残副冰碛物和混合副冰碛物。沉积物的搬运介质以冰川、冰筏为主,海流对沉积物的影响较为明显,沉积物类型随地形变化而呈有规律的分布。     

Measurement of trace nitrate concentrations in seawater by ion chromatography with valve switching

An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity （R〉0,99） in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability （RSD〈5%, n=6）. The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater.