1954年～2006年介休市降水及干旱气候变化特征分析

根据山西省介休市气象局1954年-2006年的降水等资料,分析了介休市近53年来的降水及干旱气候变化．得出：a）近53a来,介休市降水量总体呈减少趋势,减少速度为22．1mm／10a,显著高于全国水平。20世纪90年代减少趋势尤为显著。在季节上,夏、秋降水减少明显,说明降水减少主要是由夏、秋季降水减少造成。b）53年间介休市有2个明显干燥期：20世纪60年代中后期至70年代中期和90年代中后期至本世纪初。干燥系数四季均有增大趋势,但春季增大最为明显。     

一次持续空气污染过程的气象条件分析

2004年12月24-30日,淄博地区出现一次持续一周的强空气污染过程.本文分析了这次过程的主要污染物浓度变化特征和造成强污染的天气形势特点以及主要的气象变量分布特征.结果表明:高空维持稳定纬向环流、逆温层结持续存在、混合层厚度增加、低空风速小,导致污染物不能及时随大气扩散,污染物浓度增大.     

黄河中下游夏季降水时空分布及演变特征

利用黄河中下游地区44个测站1978-2005#夏季(6-8月)降水资料,采用EOF和REOF方法分析了黄河中下游夏季降水时空分布及演变特征,结果表明,黄河中下游地区夏季降水可分为全地区一致、陕西省北中部和晋陕两省交界处为中心、晋陕豫三省交界处为中心、晋陕两省北部为中心、河南省西北部为中心等多种分布型.     

Correlation between local structure and molar ratio of Au (III) complexes in aqueous solution: An XAS investigation

The local and geometrical structure around gold (III) e.g., Au³⁺ ions in aqueous solution with different OH⁻/Cl⁻ molar ratios, has been investigated by X-ray absorption spectroscopy (XAS). X-ray absorption near-edge structure (XANES) spectra of [AuCl_n(OH)_4−n]⁻ solutions have been calculated and the multiple-scattering spectral features have been attributed to Cl d-states, axial water molecules and the replacement of Cl⁻ ligands by OH⁻ ligands. A square–planar geometry for [AuCl_n(OH)_4−n]⁻ with two axial water molecules has been identified. Moreover, a spectral correlation between XANES features and the type of planar atoms has been identified. By extended X-ray absorption fine structure spectra (EXAFS), the planar Au bond distances in the solutions have also been determined, e.g., 2.28 Å for Au–Cl and 1.98 Å for Au–O, respectively. The same EXAFS analysis provides evidence that the peak at about 4.0 Å in solutions with the lowest OH⁻/Cl⁻ molar ratio arises from collinear Cl–Au–Cl multiple-scattering contributions. For the first time, a complete detailed reconstruction of the hydration structure of an Au ion at different pH values has been achieved.     

Assessing probability of surface manifestation of liquefaction at a given site in a given exposure time using CPTU

This paper is a follow-up to a previous paper on the subject of liquefaction potential index (LPI), a parameter that is often used to characterize the potential for surface manifestation of liquefaction at a given site subjected to a given shaking level (represented by a pair of peak ground surface acceleration a_max and moment magnitude M_w). In the previous paper by Juang and his coworkers, the LPI was re-calibrated for a piezocone penetration test (CPTU) model, and a simplified model based on LPI was created for computing the conditional probability of surface manifestation of liquefaction (P_G). In this paper, the model for this conditional probability P_G is extended into a complete framework for assessing the probability of surface manifestation of liquefaction in a given exposure time at a given site subjected to all possible ground motions at all seismic hazard levels. This new framework is formulated and demonstrated with an example site in 10 different seismic regions in the United States.     

New insights into the origin of perylene in geological samples

The origin of the polycyclic aromatic hydrocarbon (PAH) perylene in sediments and petroleum has been a matter of continued debate. Reported to occur in Phanerozoic organic matter (OM), fossil crinoids and tropical termite mounds, its mechanism of formation remains unclear. While a combustion source can be excluded, structural similarities to perylene quinone-like components present in e.g. fungi, plants, crinoids and insects, potentially suggest a product-precursor relationship. Here, we report perylene concentrations, ¹³C/¹²C, and D/H ratios from a Holocene sediment profile from the Qingpu trench, Yangtze Delta region, China. Perylene concentrations differ from those of pyrogenic PAHs, and rise to prominence in a stratigraphic interval that was dominated by woody vegetation as determined by palynology including fungal spores. In this zone, perylene concentrations exhibit an inverse relationship to the lignin marker guaiacol, D/H ratios between −284‰ and −317‰, similar to the methoxy groups in lignin, as well as co-variation with spores from wood-degrading fungi. ¹³C/¹²C of perylene differs from that of land plant wax alkanes and falls in the fractionation range expected for saprophytic fungi that utilise lignin, which is isotopically lighter than cellulose and whole wood. During progressive lignin degradation, the relative carbon isotopic ratio of the perylene decreases. We therefore hypothesise a relationship of perylene to the activity of wood-degrading fungi. To support our hypothesis, we analysed a wide range of Phanerozoic sediments and oils, and found perylene to generally be present in subordinate amounts before the evolutionary rise of vascular plants, and to be generally absent from marine-sourced oils, few exceptions being attributed perhaps to a contribution of marine and/or terrestrial-derived fungi, anoxia (especially under marine conditions) and/or contamination of core material by fungi. A series of low-molecular-weight aromatic quinones bearing the perylene-backbone were detected in Devonian and Cretaceous sediments, potentially representing precursor components to perylene.     

Distribution and significance of novel low molecular weight sterenes in an immature evaporitic sediment from the Jinxian Sag,North China

An unusual series of C₂₂–C₂₇ monounsaturated sterenes and C₂₄–C₃₀ tetracyclic terpanes (17,21-secohopanes) were detected in relatively high concentrations in an immature evaporitic marl sediment of the Jinxian Sag, Bohai Bay Basin, North China. The site of unsaturation in these novel sterenes is assigned tentatively to the D ring on the basis of mass spectral interpretation, which also distinguishes them from reported unsaturated sterenes. Other hydrocarbon biomarker or stable isotope characteristics are indicative of microbial (e.g. methyl hopanes), phytoplankton or higher plant (depleted δ¹³C values of isoprenoids and hopanes) inputs and an anoxic carbonate depositional environment (hexacyclic hopanes; tetracyclic terpanes). The hydrocarbon composition showed no obvious biodegradation and the relatively high concentration of unsaturated terpenoids (e.g. gammacerene) and low values of other established maturity parameters (T_s/T_m = 0.23; R_o = 0.44%; T_max = 417 °C), are consistent with sediments of low maturity. The novel, low molecular weight sterenes and the tetracyclic terpanes may be early diagenetic products of microbial sources in a carbonate environment.     

黔西南白层超基性岩墙锆石SHRIMP U-Pb年龄和Hf同位素组成研究

文章对黔西南白层地区出露的燕山期超基性岩墙进行了单颗粒锆石SHRIMP U-Pb年龄和Hf同位素组成研究,获得A、B两组不同的锆石年龄.A组锆石呈不规则粒状,具不完整的宽大条带,12颗锆石的 SHRIMP U-Pb年龄加权平均值为(84±1)Ma,代表了超基性岩墙的侵位年龄;锆石Hf原位分析表明,176Hf/177Hf从0.282561到0282719,εHf(84 Ma)平均为-3.61,表明岩浆源区主要以富集地幔为主,并受到部分地壳物质的混染.B组锆石晶形完整,具典型的中酸性岩浆型振荡环带,3颗锆石的SHRIMP U-Pb模式年龄为409～450 Ma.176Hf/177Hf从0282379到0282440,εHf(t)平均为-3.77,均低于A组锆石,属于捕获锆石.据此认为84 Ma左右由于华南岩石圈伸展,软流圈地幔上涌,导致岩石圈富集地幔部分熔融,熔体上升过程中与409～450 Ma左右形成的少量地壳岩石发生混染,随后快速侵位冷凝而形成基性-超基性岩墙.白层地区84 Ma的超基性岩浆活动是整个华南西部燕山晚期(80～90 Ma)岩浆活动的一部分.右江褶皱带周缘的燕山晚期岩浆活动主要与大规模的Sn、W、Ag、Cu、Pb、Zn等矿床有关,但右江褶皱带内部的燕山晚期岩浆活动是否与以卡林型金矿为代表的低温热液矿床有成因上的联系,尚需更多矿床年代学资料的证实.