Chains of type I stormbursts

From radio spectra between 160 and 320 MHz of chains of type I bursts it appears that their duration distributions allow an exponential fit, and that those of samples containing long and short chains respectively, taken from the same storm, have virtually the same characteristic time (logarithmic slope). On the average this figure decreases - as a function of the frequency - at about 1 s per 10 MHz. The high frequency cut-off of chain activity (noise storms) is mainly a consequence of the frequency dependence of the probability for the first burst of a chain to appear. Given the density of type I bursts in a chain, it is concluded that the probability of a type I burst to be followed by another one is at least 90% below 250 MHz and 70–80% at 300 MHz, which makes it essential for type I theories to include a mechanism to this effect. The drift rate distribution for chains is symmetrical with a peak at-10 MHz/s. The statistics is indicative of a correlation between drift rate and duration. No evidence has been found for the occurrence of chain pairs or frequency splitting in chains, nor for an association between chains and type III bursts.     

Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe in seawater: I. Measurements in UV photooxidised seawater

Calibration of a chalcogenide glass membrane, Fe(III)ISE [Fe_2.5(Ge₂₈Sb₁₂Se₆₀)_97.5], in buffered saline media has been undertaken in order to assess the suitability of this ISE for seawater analyses. The electrode slopes in saline citrate and salicylate buffers were 26.3 and 28.2 mV/decade, respectively, for Fe³⁺ concentrations ranging from 10⁻¹⁰ M to less than 10⁻²⁵ M Fe³⁺. The calibration lines in the citrate and salicylate buffers were essentially collinear with the response in unbuffered chloride-free standards containing >10⁻⁵ M Fe³⁺, demonstrating that the response of the FeISE is unaffected by chloride ions. A mechanism involving a combination of charge transfer and ion-exchange of Fe(III), at the electrode diffusion layer, can be used to explain the ≈30 mV/decade slope of the FeISE. The response of the FeISE in UV photooxidised seawater containing 8 nM total Fe was measured as the pH was changed from 8.27 to 3.51. The slope of the response was 24.2 mV/decade [Fe³⁺] calculated as a function of pH using Fe(III) hydrolysis constants for seawater. Moreover, the response was essentially collinear with that in citrate buffers and in unbuffered solutions containing >10⁻⁵ M Fe³⁺ and the slope for the combined data was 26.2 mV/decade. This study was restricted to organic-free seawater because the certainty in Fe(III)–ligand stability constants is insufficient to warrant the selection of an ideal calibration buffer system, and there is evidence that powerful chelating ligands (e.g., EDTA along with humic and fulvic acids) may alter the response of the Fe(III)ISE. The Fe dissolution rate of the FeISE in UV photooxidised seawater was found to be 1.6×10⁻² nmol Fe/min, as measured by cathodic stripping voltammetry (CSV). This would contaminate a 100-ml sample by 0.8–1.6 nM Fe over a typical measurement period of 5–10 min obtained using a stability criterion of 0.5 mV/min. Various methods are proposed for reducing the level of contamination in open ocean samples that contain sub-nanomolar concentrations of iron. The FeISE has the potential to detect free Fe³⁺ at concentrations typically found in natural seawater.     

Distribution and Abundance of Arsenic in the Soils and Sediments of O‘ahu,Hawai‘i

Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values.     

JpGraph绘图类库在地震数据展示中的应用

天津市地震局在进行地震观测数据可视化发布工作中,采用PHP语言及JpGraph类库实现了前兆类观测数据在WEB页面中的图形化展示,扩展了PHP语言在行业数据发布与展示系统中的应用,本文主要阐述JpGraph类库的应用及在使用中遇到的问题.     

Climate change and global cycling of persistent organic pollutants: A critical review

Climate warming, one of the main features of global change, has exerted indelible impacts on the environment, among which the impact on the transport and fate of pollutants has aroused widespread concern. Persistent organic pollutants (POPs) are a class of pollutants that are transported worldwide. Determining the impact of climate warming on the global cycling of POPs is important for understanding POP cycling processes and formulating relevant environmental policies. In this review, the main research findings in this field over the past ten years are summarized and the effects of climate warming on emissions, transport, storage, degradation and toxicity of POPs are reviewed. This review also summarizes the primary POP fate models and their application. Additionally, research gaps and future research directions are identified and suggested. Under the influence of climate change, global cycling of POPs mainly shows the following responses. (1) Global warming directly promotes the secondary emission of POPs; for example, temperature rise will cause POPs to be re-released from soils and oceans, and melting glaciers and permafrost can re-release POPs into freshwater ecosystems. (2) Global extreme weather events, such as droughts and floods, result in the redistribution of POPs through intense soil erosion. (3) The changes in atmospheric circulation and ocean currents have significantly influenced the global transport of POPs. (4) Climate warming has altered marine biological productivity, which has changed the POP storage capacity of the ocean. (5) Aquatic and terrestrial food-chain structures have undergone significant changes, which could lead to amplification of POP toxicity in ecosystems. (6) Overall, warming accelerates the POP volatilization process and increases the amount of POPs in the environment, although global warming facilitates their degradation at the same time. (7) Various models have predicted the future environmental behaviors of POPs. These models are used to assist governments in comprehensively considering the impact of global warming on the environmental fate of POPs and therefore controlling POPs effectively. Future studies should focus on the synergistic effects of global changes on the cycling of POPs. Additionally, the interactions among global carbon cycling, water cycling and POP cycling will be a new research direction for better understanding the adaptation of ecosystems to climate change.     

老滑坡路段路堑开挖与超前支护效果

为防止老滑坡路段路堑开挖过程中出现路堑边坡失稳的问题,以在建某高速公路老滑坡段路堑失稳边坡为例,借助数值分析,进行了老滑坡路段路堑开挖与超前支护效果研究。结果表明：1）一般宽平台开挖模式能提高边坡的整体稳定性;然而,对于存在具有膨胀性质滑带土的牵引式老滑坡,坡脚采用宽平台刷坡减重不利于路堑边坡的稳定,必须要采取超前支护,如锚索、抗滑桩等,必要时要紧急采取清方卸载措施。2）锚索超前支护能够有效抑制边坡变形,需采用有效措施提高设置在坡脚处锚索的抗拉强度,如施加预应力等。3）抗滑桩超前支护应注意桩位、桩长、桩距的优化设计。建议抗滑桩采用锚拉,对桩前坡体中的滑带进行超前注浆,有必要沿老滑坡主滑方向布置多排抗滑桩,或采用h型桩体设计。     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Recent Changes Occurred in the Terminus of the Debris-covered Bilafond Glacier in the Karakoram Himalayas Using Remotely Sensed Images and Digital Elevation Models (1978-2011)

Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM＋ images were used for this study. Digital elevation models derived from ASTER GDEM and SRTM were also utilized. Visible, infrared and thermal infrared channels were utilized in order to get accurate glacier change maps. Three methods were tried to map this debris-covered glacier in this research. The glacier has been mapped successfully and the changes in the glacier terminus from 1978 to 2011 have been calculated. Manual, semi-automatic and thermal methods were found to give similar results. It was found that the glacier has undergone serious ablation during this period despite of the fact that many of the larger glaciers in the Hindu Kush and Karakoram mountain regions in the Upper Indus Basin were reported to be expanding. The terminus has been moved back about 600 meters during this period and there was an abrupt change in the glacier terminus during 1990-2002. We propose that debris thickness is not the only factor that influences the glacier ablation but the altitude of the debris-covered glacier as well. Many glaciers in the Karakoram region reported to be expanding were having higher altitudes compared to the study area.     

Climatic changes have led to significant expansion of endorheic lakes in Xizang (Tibet) since 1995

Robust climate warming has led to significant expansion of lakes in the central Tibetan Plateau. Using remote sensing data, our quantitative analysis indicates that Siling Co, a saline lake in a characteristic endorheic basin in the central region of the Plateau, has expanded more than 600 km² in area since 1976. Particularly since 1995, the lake has significantly expanded in response to increasing precipitation, decreasing water surface evaporation caused by weaker winds and less solar radiation, and increased glacier meltwater draining to the lake. Glacier–lake interactions are important in governing lake expansion and are also part of a feedback loop that influences the local climate. Worsening climatic conditions (decreased precipitation and increased temperatures) that could have caused the lake to shrink during 1976–1994 were offset by increasing glacier meltwater feeding the lake, which made the lake nearly stable. We demonstrate that this pattern changed during 1995–2009, when glacier meltwater actually decreased but participation runoff increased and evaporation decreased, leading to expansion of the lake. If climatic conditions became suitable for further lake development, which would be indicated by expansion in lake area, glacier meltwater could be saved in a stable reservoir.