钛胶海水提铀动力学研究Ⅱ——吸附机理的推断

海水提铀机理的研究,已逐渐受到重视,然而,至今研究还不是很深入,观点也各有差别.例如,Keen等[1]认为钛胶从海水中吸附铀是阳离子交换过程,即海水中的铀是UO₂2+离子的形式与钛胶进行交换;尾方升等[2]则倾向于阴离子吸着,即铀是以UO₂(CO₃)₃4-的形式被吸附.我们曾于1973年在海洋局系统的一次会议上提出阳离子给合交换的看法,并在后来的两次专业会议上予以补充发展.张正斌[3]认为是阳离子交换或一价阳离子失水络合.最近崔清晨[4]提出可能是UO₂(OH)₃-的络合吸附.根据几年来的工作,我们仍认为,钛胶从海水中的吸铀机理可能是一种阳离子形式的络合交换过程.     

Optimum design of filament-wound multilayer-sandwich submersible pressure hulls

Submersible pressure hulls with fiber-reinforced multilayer-sandwich constructions have been developed in recent years as substitutes for classical metallic ring-stiffened pressure hulls. This study aims to optimize the design of filament-wound multilayer-sandwich submersible pressure hulls, taking into consideration the shell buckling strength constraint, the angle-ply laminated facing failure strength constraint and the low-density isotropic core yielding strength constraint under hydrostatic pressure using the hybrid genetic algorithm (HGA). The thickness of the facing, the thickness of the core layer, the orientation angle of the fibers in the facings and the shear modulus of the core material are taken as design variables. A sensitivity analysis is performed to study the effects of the operational depths and the hull shell geometry parameter, the length-to-diameter ratio (L/D), on the optimal design of filament-wound multilayer-sandwich submersible pressure hulls with graphite/epoxy, glass/epoxy and boron/epoxy composite facings. The results reveal that the optimal weight of various sandwich pressure hulls increases linearly with the operational depth, but it is almost unchanged as the geometry paramter. Furthermore, Graphite/Epoxy is the best choice for the material of the facings in a light-weight design. With reference to wall design, Boron/Epoxy is the best choice for the material of the facing at shallow depths, but Graphite/Epoxy is the best choice at extreme depths. Results of this study provide a valuable reference for designers of underwater vehicles.     

Objective prism survey of qsos in the field centered at 10h40m + 00°00′

QSO objective prism survey was done for the field centered at 10^h40^m + 00°00. For the 348 objects selected, we present in this paper their positions,B _J magnitudes, spectra, and finding charts. Based on the sample containing 163 QSO candidates with higher reliabilities (F 3), the surface density of QSO candidates withB _J 20 is estimated to be about 4.5 per square degree.Work based on UKST plates.     

钾霞石制备体系碱性滤液的利用技术

为处理钾长石水热制备钾霞石所产生的碱性滤液,本文采用水热法,考察了氢氧化铝溶解时间、晶化时间、晶化温度、水碱比对钾霞石产率和白度的影响,并对合成钾霞石物相进行了表征。结果表明,合成钾霞石的最佳条件为,氢氧化铝溶解时间为1.5 h,晶化时间为4 h,晶化温度280℃,水碱比为1.8。XRD结果表明,产物为钾霞石粉体。傅里叶变换红外光谱表明,Al(OH)₃中的Al在水热条件下进入到Si—O骨架中形成了Si—O—Al官能团,从而印证了钾霞石的合成。差热分析结果表明,合成钾霞石具有良好的热稳定性。氮气吸附结果表明,合成钾霞石比表面积为5.18 m²/g,平均孔径为32.98 nm。实现了钾长石水热制备钾霞石所剩碱性滤液的资源化利用,并为钾长石水热制备钾霞石提供了一种母液循环的思路,使水热制备钾霞石工业化成为一种可能。     

Soil degradation: a global problem endangering sustainable development

1 Introduction Soil is not only the major natural resource on which human being depends for the production of food, feed, fiber, renewable energy and raw materials, but also plays a key role in maintaining the complex terrestrial ecosystems and climate systems of this planet. Recent rapid increase in the human population is placing a great strain on the worlds soil resources. Only about 11% of the global land surface covered by the soils are being used to raise crops and livestock, in other …     

甲醛还原Pt/TiO2催化剂用于温和条件下高效催化氧化甲醛（英文）

通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差.     

试论中国缩微旅游资源

９０年代以来，我国缩微旅游景点出现巨大的投资热潮，随之而来的是巨大的浪费。作者通过对缩微旅游资源的特征与功能、市场容量及其在旅游资源中的地位分析，认为目前中国缩微旅游资源开发区域可分为３个等级，不同等级的区域所采取的缩微旅游资源开发措施及应开发的主题和规模也应有所不同。     

Application of discovery process models in estimating petroleum resources at the play level in China

Discovery process modeling has gained wide acceptance in the Chinese exploration community. In recent years, a variety of discovery process models have been applied to the prediction of undiscovered petroleum resources at the play level in sedimentary basins in China. However, challenging problems have been encountered, particularly when one method alone has been applied to small plays in nonmarine sedimentary basins or in plays with an unusual order of discovery wells. This paper presents results gotten by using the lognormal discovery process model of the Geological Survey of Canada and the geoanchored method for three petroleum plays in basins with different geologic settings. Although the predicted shapes of the parentsize distributions which use these two models, were not always similar, the expected values of the total resources and the number of fields (pools) to be discovered are comparable. The combined use of two discovery process models in the same play compensates for the weaknesses in one method compared with the other and vice versa. Thus, more reliable estimates are the result.     

重庆市云阳县开发荒山资源,发展经济林木

根据县内荒山资源特点,通过因地制宜,树立生态经济学观点,把开发荒山资源与保护生态环境密切结合,加以发展经济林木,促进了当地经济发展。