Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

Impacts of systematic precipitation bias on simulations of water and energy balances in Northwest America

At high latitudes and in mountainous areas, evaluation and validation of water and energy flux simu-lations are greatly affected by systematic precipitation errors. These errors mainly come from topographic effects and undercatch of precipitation gauges. In this study, the Land Dynamics （LAD） land surface model is used to investigate impacts of systematic precipitation bias from topography and wind-blowing on water and energy flux simulation in Northwest America. The results show that topographic and wind adjustment reduced bias of streamflow simulations when compared with observed streamflow at 14 basins. These systematic biases resulted in a -50%-100% bias for runoff simulations, a -20%-20% bias for evapotranspiration, and a -40%-40% bias for sensible heat flux, subject to different locations and adjustments, when compared with the control run. Uncertain gauge adjustment leads to a 25% uncertainty for precipitation, a 20% 100% uncertainty for runoff simulation, a less-than-10% uncertainty for evapotranspiration, and a less-than-20% uncertainty for sensible heat flux.     

赣北主要内生金矿床的形成条件

赣北地区的金矿床,可分为含金韧性剪切带型、硅化破碎带型、隐爆角砾岩型和微细粒浸染型等4个类型,其原始成矿物质来源于上地幔,通过火山喷发—沉积作用,形成含金沉积建造和含金火山岩建造.钠、钾质两个系列的花岗质岩石都可以形成金矿床.矿化富集主要通过韧、脆性变形和岩浆隐蔽爆破,产生多次破碎,多期蚀变矿化.在中—低温热液阶段,含矿热液体系的HS~-、Cl~-离子减少,还原介质增加的条件下沉淀富集,形成不同类型的金矿床.     

赣南地区石雷石英闪长岩的成因:岩石化学、副矿物微量元素、锆石U-Pb年代学与Sr-Nd-Hf同位素制约

石雷石英闪长岩是赣南崇-余-犹地区比较特殊的闪长质侵入体。锆石的原位U-Pb定年表明,该岩体侵位于433.5±3.4Ma。全岩主量元素特征上显示出中偏酸性(SiO2=56.92%～64.70%),富Al(Al2O3=14.10%～14.83%),富碱(Alk=6.41%～7.40%)特别是富钾(K2O=3.86%～4.85%),镁、铁含量较高,MgO:3.47%～5.95%,FeOT:5.23%～8.14%以及低磷(P2O5=0.27%～0.4%)的特点;微量元素上主要富集K、Rb、Cs等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti、P等高场强元素。磷灰石微量元素特征上显示高度富集稀土元素特别是轻稀土元素的特征;具有Eu的负异常(δEu=0.37～0.45)。ISr位于0.7073～0.7132之间,εNd(t)变化于-8.41～-4.97之间,两阶段钕模式年龄介于1.58～1.86Ga之间,Hf同位素组成相对均一,εHf(t)主要集中变化于-8～-2之间,两阶段Hf模式年龄加权平均为1.77±0.09Ga,这些特征都暗示了该石英闪长质岩体的形成是强烈壳幔相互作用的产物,区内加里东晚期可能发生了局部的岩石圈的减薄。     

黄河三角洲地下水动态变化及其与地面沉降的关系

为了分析黄河三角洲地下水动态及其与地面沉降的关系, 利用多年地下水和地面沉降监测数据, 发现黄河三角洲广饶县和东营区的地下水动态变化剧烈且地面沉降严重, 含水层多处于超采状态, 浅、深层地下水降落漏斗先后出现.深层地下水降落漏斗中心水位下降速度达2~3m/a.近年来, 东营和广饶地面沉降漏斗中心沉降量和速率分别为155.1mm、28.2mm/a和356.0mm、64.7mm/a.借助GIS技术及数理统计法, 发现深层地下水降落漏斗与沉降漏斗空间耦合良好, 深层地下水位与地面高程呈线性正相关, 相关系数为0.92, 深层地下水过度开采已成为影响沉降的最根本因素.井灌区第三粘性压缩层成为地面沉降主要贡献层, 且深层地下水降落漏斗中心的地下水位已低于第三承压含水层临界水位, 沉降趋于严重.      

20世纪南极菲尔德斯半岛毛皮海豹食谱比例变化的同位素混合模型比较分析

稳定同位素比值分析已成功用于示踪动物的食物来源研究,近年来已发展了多个同位素混合模型用于计算混合物中多来源物质的组成比例。本文以过去百年来南极菲尔德斯半岛南极毛皮海豹(Arctocephalus gazella)毛发的C、N同位素数据为基础,运用同位素混合模型中的欧几里得距离法、线性模型和贝叶斯模型进行计算、分析和比较,得到毛皮海豹食谱中南极磷虾(Euphausia superb)、南极电灯鱼(Electrona antarctica)和尼氏裸灯鱼(Gymnoscopelus nicholsi)所占比例随时间的变化趋势。各模型计算得出的结果可分为两组,分别是欧几里得距离法公式(1)和(2)的结果,表现为近百年来毛皮海豹食谱中Euphausia superb比例与其毛发稳定N同位素比值呈同步上升的趋势;第二组为欧几里得距离法公式(3)、线性模型和贝叶斯模型的结果,Euphausia superb比例与毛皮海豹毛稳定N同位素比值呈反相关关系。综合对比研究区域气候、海冰环境变化背景和已有的南极磷虾种群密度调查资料分析,第二组模型结果与实际情况较为相符,可用于讨论食物比例的时间变化趋势。近百年来,菲尔德斯半岛毛皮海豹食谱中Euphausia superb的比例显著下降,很可能是由于区域气候快速变暖和海冰的消退造成的。本文的计算结果指示西南极半岛气候变暖已显著影响到区域海洋食物链变化。     

北极海冰的年代际转型与中国冻雨年代际变化的关系

基于1961-2013年HadISST海冰密集度资料,定义了北极海冰的季节性融冰指数,结果显示近几十年来北极季节性融冰范围呈显著的上升趋势,并分别在20世纪70年代末和90年代中期存在显著的年代际转型,相应地,中国冻雨发生频数总体上呈现出显著的减少趋势,但也存在显著的年代际转型。在20世纪70年代末之前,北极季节性融冰范围较小但显著增长,中国冻雨频数年际变化振幅较大,且主要受巴伦支海、喀拉海海冰的影响;20世纪70年代末至90年代中期北极季节性融冰范围维持振荡特征,没有显著的线性趋势,中国冻雨频数变化振幅减小,与北极海冰相关较弱,主要相关因子为北大西洋及北太平洋海表温度变化;而90年代中期以后,北极海冰融化加快,特别是2007年以后,季节性融冰范围大大增加,而中国冻雨频数处于低发时段,其变化与太平洋扇区海冰及堪察加半岛附近海温呈显著负相关,季节性融冰的显著区域也从东西伯利亚海逆时针旋转向波弗特海-加拿大群岛北部扩张,同时向北极中央区扩张。不同年代影响冻雨的海温或海冰关键海区不同,产生特定的大气环流异常响应,进而影响到我国冻雨。     

High resolution seismic investigations for the determination of water flow directions during sulphur deposits exploitation

This paper shows the results of seismic research on some problems of sulphur in-situ mining. The difficulties during exploitation were mainly connected with the lack of detailed information on the structure and tectonics of deposit and overburden strata. This kind of information could be obtained using the High Resolution Seismic method. The use of seismic method allows to determine the range of subsidence provoked by well mining of sulphur. It is very important to undertake the measurements before exploitation, because the comparison of seismic sections before and during exploitation creates a possibility of determining the process of changes in the structure of the deposit and overburden strata.     

洪泽湖风生流数值模拟

湖流是湖泊中污染物质扩散，悬浮物沉降及输移等的主要水动力学要素，造成湖水运动的成因机制很复杂，其中风生流是重要形式，本文通过构造一个二维闭边界数值模拟，对不同风情下的洪泽湖湖流流态进行模拟研究，探讨其入流较小，沿岩各闸关闭的枯季情况下的风生流特征。