资源开发-环境灾害-地球化学——以贵州阿哈湖铁、锰污染为例

资源利用与环境改变、资源再生与环境净化互为因果。因资源开发所触发的环境灾害已成为环境地质学与地球化学的研究热点。贵州阿哈湖汇水区煤炭资源的不合理开采导致铁、锰在沉积物中蓄积并产生湖水季节性二次污染。文中以此为例 ,并依据地球化学过程是认识污染机理的关键、地球化学原理是污染控制技术的科学基础 ,讨论环境物质释放、运移、转化和界面作用与环境质量变异的关系。     

Paratacamite from Gypsum Veins in Sandstones of the Kuqa Basin,Xinjiang, China: Implications for a New Epigenetic Cu Enrichment Mechanism

The Kuqa Basin filled with Paleogene evaporite series is located in the northeast of the Tarim Basin, Xinjiang, China. It is famous for sandstone‐hosted Cu deposits formed by synsedimentary processes. However, our recent studies reveal that there has been another Cu mineralization mechanism in this basin. Field investigations show that there is a close relationship among faults, salt domes, and brine. Cu deposits are mainly located in two east–west‐trending anticlinal belts in the basin, adjacent to salt domes in the belts. Cu minerals in gypsum veins of the Jidike and Kangcun formations have been investigated by SEM, EDS, and X‐ray diffraction methods. The occurrence of paratacamite in gypsum veins has been reported to coexist with glauberite and halite in the joint planes of sandstones. In addition, it occurs accompanying residual crystal salt encrustation in limestone fractures, or in sandstones in dendritic form. These features indicate that the surface‐Cu enrichment in the Kuqa Basin might have originated from Cu‐bearing brine in the underlying evaporite units, which migrated upward along fractures. In addition, the presence of H₂S in the east–west fault belt in the Kuqa Basin, and the discovery of surface sulfur, calcium carbonate, and covellite, suggest thermochemical sulfate reduction near salt domes in the deeper parts of the rock units. This process resulted in the generation of reduced brine and provided a favorable environment for Cu enrichment. Therefore, the surface‐Cu mineralization near salt domes is interpreted to be the result of Cu‐bearing brine migrating upward to the surface along faults (or joints) following the intrusion of deep salt domes. The geological evidence indicates the presence of reducing brine and Cu‐bearing brine near the salt dome in the deeper rocks of the Kuqa Basin, thus making the intrusive contact zone of the salt dome a favorable site for the epigenetic enrichment of Cu. Our study demonstrates that Cu enrichment in the Kuqa Basin resulted not only from synsedimentary deposition but also through epigenetic enrichment associated with salt dome intrusion and brine‐rich fluids.     

Evolution mechanism of the western Pacific subtropical high

Ever since Charney et al.[1] studied the multiple equilibrium states in atmosphere with highly truncated spectral method in 1979, many Chinese researchers, such as Li Maicun et al. (1983)[2], Liu Chongjian et al. (1983)[3], Miu Jinhai et al. (1985)[4] and…     

Evaluating relationships between soil chemical properties and vegetation cover at different slope aspects in a reclaimed dump

Conducting research about the relationships between soil chemical properties and vegetation coverage at different slope aspects is especially important in reconstructed ecosystems of vulnerable ecological regions. This study was conducted in the first reclaimed dump within the Pingshuo mining area of Shanxi Province, China, to analyze patterns of soil chemical properties (soil organic matter (SOM), soil total nitrogen (STN), soil available phosphorus (SAP) and soil available potassium (SAp) and vegetation coverage (NDVI) and their correlations at different slope aspects. In the reclaimed dump, 26 quadrats were established along four slope aspects (i.e., shady, semi-shady, sunny and semi-sunny slopes). There was no significant difference in SOM or STN among different slope aspects, while SAP differed between shady slopes compared to semi-shady, sunny and semi-sunny slopes; SAP differed significantly between semi-shady and semi-sunny slopes. The NDVI of semi-sunny slopes differed significantly from that of the other three aspects. There was variation in the relationships between NDVI and soil chemical properties, depending on the slope aspects. The logarithm of SOM and NDVI was related linearly on shady and semi-shady slopes, while NDVI was inversely related to the natural logarithm of the logarithm of SOM on sunny and semi-sunny slopes. STN and NDVI had a first-order function relationship on shady and semi-shady slopes, yet a quadratic function relationship on sunny and semi-sunny slopes. The relationships between SAP and NDVI were inverse on all types of slopes. On shady and semi-shady slopes, NDVI had a quadratic relationship with the logarithm of SAp, but it was well fitted by using a cubic function on sunny and semi-sunny slopes. The sensitivity coefficients of soil chemical properties and NDVI were different, and soil chemical properties changed differently depending on changes in NDVI at different slope aspects.     

土壤对氟离子的吸附和释放实验研究

实验研究了土壤中的粘土矿物对氟离子有良好的交换吸附作用,用饱水动态土柱法对氟离子进行交换吸附处理可使含氟1.6mg/l的饮用水降到0.2mg/l,并且水的各项指标均达到国家饮用水标准,是降氟的很好材料,在水环境治理中发挥了很大作用.     

洱海四种沉水植物对弱光环境的适应性比较

水下弱光环境是水生态系统沉水植被恢复面临的常见问题,因此研究沉水植物在弱光胁迫下的适应性是必要的.本研究以云南大理州洱海南部重度退化的湖区(惯称湖心平台,曾分布有大面积沉水植物)作为实验地点,选取4种沉水植物——苦草(Vallisneria natans)、轮叶黑藻(Hydrilla verticillata)、穗花狐...     

Human settlement evaluation in mountain areas based on remote sensing, GIS and ecological niche modeling

The Qinghai-Tibet Plateau is the world’s highest and largest plateau. Due to increasing demands for environment exploration and tourism, a large transitional area is required for altitude adaptation. Hehuang valley, which locates in the transition zone between the Loess Plateau and the Qinghai-Tibet Plateau, has convenient transportation and relatively low elevation. Our question is whether the geographic conditions here are appropriate for adapted stay before going into the Qinghai-Tibet Plateau. Therefore, in this study, we examined the potential use of ecological niche modeling (ENM) for mapping current and potential distribution patterns of human settlements. We chose the Maximum Entropy Method (Maxent), an ENM which integrates climate, remote sensing and geographical data, to model distributions and assess land suitability for transition areas. After preprocessing and selection, the correlation between variables and spatial autocorrelation input data were removed and 106 occurrence points and 9 environmental layers were determined as the model inputs. The threshold-independent model performance was reasonable according to 10 times model running, with the area under the curve (AUC) values being 0.917 ± 0.01, and 0.923 ± 0.002 for test data. Cohen’s kappa coefficient of model performance was 0.848. Results showed that 82.22% of the study extent was not suitable for human settlement. Of the remaining areas, highly suitable areas accounted for 1.19%, moderately for 5.3% and marginally for 11.28%. These suitable areas totaled 418.79 km², and 86.25% of the sample data was identified in the different gradient of suitable area. The decisive environmental factors were slope and two climate variables: mean diurnal temperature range and temperature seasonality. Our model showed a good performance in mapping and assessing human settlements. This study provides the first predicted potential habitat distribution map for human settlement in Ledu County, which could also help in land use management.     

Dynamic Response Analysis of Interaction System of R.C. Gravity Single-Leg Platform

In this paper, the responses of the interaction system of R.C. gravity single-leg platform to seismic excitation are mainly analysed. A set of nonlinear equations for the interaction system are established by using the wave, one is the soil-structure interaction and the other is the fluid-structure interaction. The seismic response of the interaction system is analysed for the influence of the asymmetric structure, fluid action, etc. with the input of seismic SH waves in any direction. The numerical results are given for a simple example.     

某些硫化物矿物中Fe的价态电子探针分析

对湖南上堡、郴县及胶东地区5个黄铁矿样品和5个黄铜矿样品进行的穆斯堡尔谱及电子探针(波谱仪)的分析得出:含Fe~(2+)的黄铁矿中Fe的纯离子浓度I_(La)/I_(Ka)值为0.65±0.05,含Fe~(3+)的黄铜矿中Fe的纯离子浓度,I_(La)/I_(ka)值为0.40士0.05.可见,随Fe价态的升高,比值I_(La)/I_(ka)反而降低.     

构造煤与原生结构煤的显微傅立叶红外光谱特征对比研究

通过对平顶山、郑州和南票三大矿区石炭二叠纪含煤岩系中高煤级烟煤和无烟煤的显微傅立叶红外光谱分析，探讨了原生结构煤与构造煤的有机大分子结构演化特征及其影响因素。结果表明，构造应力有利于煤中氢发生化学环境转移，使脂肪烃含量相对减少、稳定的芳香烃含量相对增加，促进煤大分子结构缩合度和有序度增加。