南梁煤矿多煤层开采地下水系统演化规律

煤层开采对所在矿区地下水系统有着重要影响.以往研究单煤层开采对地下水系统的影响较多,而对多煤层的影响研究甚少,特别对于我国西部缺水矿区.以南梁煤矿为例,运用地下水系统演化理论和岩石力学模拟等,对该矿井水文地质结构、矿井涌水变化规律、矿井地下水流场演变、矿井地下水化学成分变化等方面进行了综合分析研究,重构了多煤层开采条件...     

The thermal structure and the location of the snow line in the protosolar nebula: Axisymmetric models with full 3-D radiative transfer

The precise location of the water ice condensation front (‘snow line’) in the protosolar nebula has been a debate for a long time. Its importance stems from the expected substantial jump in the abundance of solids beyond the snow line, which is conducive to planet formation, and from the higher ‘stickiness’ in collisions of ice-coated dust grains, which may help the process of coagulation of dust and the formation of planetesimals. In an optically thin nebula, the location of the snow line is easily calculated to be around 3 AU, subject to brightness variations of the young Sun. However, in its first 5-10 myr, the solar nebula was optically thick, implying a smaller snowline radius due to shielding from direct sunlight, but also a larger radius because of viscous heating. Several models have attempted to treat these opposing effects. However, until recently treatments beyond an approximate 1 + 1D radiative transfer were unfeasible. We revisit the problem with a fully self-consistent 3D treatment in an axisymmetric disk model, including a density-dependent treatment of the dust and ice sublimation. We find that the location of the snow line is very sensitive to the opacities of the dust grains and the mass accretion rate of the disk. We show that previous approximate treatments are quite efficient at determining the location of the snow line if the energy budget is locally dominated by viscous accretion. Using this result we derive an analytic estimate of the location of the snow line that compares very well with results from this and previous studies. Using solar abundances of the elements we compute the abundance of dust and ice and find that the expected jump in solid surface density at the snow line is smaller than previously assumed. We further show that in the inner few AU the refractory species are also partly evaporated, leading to a significantly smaller solid state surface density in the regions where the rocky planets were formed.     

Determination of cosmogenic 32P and 33P in environmental samples

Understanding phosphorus dynamics in marine environment is of great importance, and appropriate tracers for phosphorus cycling in oceans are invaluable. In this study, two methods were developed for extraction, purification, and determination of naturally occurring 32P and 33P in rainwater, marine plankton and sediments using both a low-level beta counter (LBC) and an ultra-low-level liquid scintillation spectrometer (LSS). Blanks, chemical yields and counting efficiencies were quantified for both methods. The chemical purification of 32P and 33P separated by both procedures was validated by their decay curves. The absorber thickness of aluminum for LBC was assessed as 39.2 mg/cm 2 . 32P and 33P specific activities in some rain samples were determined by both methods and showed good consistent results. The advantage of the LSS over the LBC is apparent in its high counting efficiency and in determining samples with high concentration of stable phosphorus. However, when measuring environmental samples with low concentration of stable phosphorus, such as rainwater, both methods can be used and each has its distinct advantage.     

蓝隐藻藻蓝蛋白结构与功能稳定性研究

以蓝隐藻(Chroomonas placiodea)藻蓝蛋白 PC-645为材料,通过改变环境 pH 和尿素质量浓度,监测其变性和复性过程中特征荧光谱和吸收谱的动力学变化,以期了解隐藻藻蓝蛋白的色基和蛋白结构稳定性及其与功能的关系。结果表明, PC-645在很宽的 pH 范围和一定质量浓度的尿素中维持结构和功能的稳定,空间结构具有很强的柔性。pH诱导的 PC-645蛋白构象与功能变化可分为3个不同的区段。(1)稳定区(pH 3.5~7)：吸收和荧光光谱都比较稳定,显示蛋白质构象和功能在此区域都保持正常。(2)次稳定区(pH 7~10)：光吸收依然保持平稳,亚基内部的色基的状态和疏水微环境都没有改变,但荧光传递效率降低,可能是由亚基表面局部构象变化、解离(四级结构变化)或者色素基团间的空间距离变化引起。(3)不稳定区(pH<3.5和 pH>10),吸光度和荧光强度都呈快速下降,色基在近紫外和可见光区的吸收峰位变动,蛋白构象处于快速崩溃期。PC-645在酸性条件下的稳定性高于在碱性环境下,是与隐藻藻蓝蛋白所处的特殊环境及生理功能相适应的。     

海洋细菌脂肪酸的气相色谱分析

以副溶血性弧菌VP-X-3为试验对象,利用气相色谱技术分析了其细胞脂肪酸的组成和含量,以色谱峰的数量、色谱峰高及脂肪酸含量作为评价指标,探讨了不同的皂化和甲酯化条件对细菌细胞脂肪酸测定结果的影响。结果表明:皂化和甲酯化条件都对细胞脂肪酸的组成和含量产生一定的影响。较低温度皂化处理利于增加色谱峰数量和色谱峰高。甲酯化温度过高容易破坏脂肪酸,尤其是长链脂肪酸和不饱和脂肪酸的结构。高温甲酯化条件下,时间越长,甲酯化效果越差。试验得到较为理想的气相色谱前处理条件:2 mol/L NaOH-甲醇溶液2 mL,70℃水浴10 min;10%(V/V)H2SO4-甲醇溶液2 mL,70℃水浴15 min。此条件下的色谱峰的数量多达29种,色谱峰高明显高于其他处理条件下的峰高。     

南海表层沉积硅藻的分布及其与环境因子的关系

通过对取自南海62个站位的表层沉积物样品,进行了硅藻、沉积物粒度分析,查明了研究海区硅藻的种类组成及分布特点,共鉴定到硅藻56属的235个种和变种、变型.种类以热带外洋种为优势,如Azpeitia nodulifer、Roperia tesselata、Azpeitia africanus、Hemidiscus cuneiformis、Nitzschia marine 等,伴有一定量的热带—亚热带近岸种和广布种如Paralia sulcata、Thalassiosira excentrica、Cyclotella stylorum、Thalassionema nitzschioides、Thalassiothrix longissoma等.总体上,南海硅藻丰度变化呈现从陆架向陆坡至海盆递增的趋势.研究海区硅藻种类组成与临近的菲律宾海域相似程度最大,其次是东海、太平洋东北部海域.对影响南海表层沉积硅藻分布的主要因素进行了探讨,南海表层沉积硅藻主要受海底地质地貌、沉积速率、水动力条件和水文气候条件等的影响较大,硅藻的分布往往是这些因素综合作用的结果.     

潮湿环境中稻草的防腐效果及极限拉伸性能

滨海盐渍土存在盐胀、溶陷和吸湿软化等问题,需对其进行处理。设想使用高分子材料SH胶防腐处理稻草,以防腐后的稻草加筋滨海盐渍土。为评价浸胶稻草的防腐效果及其力学性能,测试了天然和浸泡SH胶稻草的吸水率,及天然、浸水、浸胶及浸胶后再浸海水稻草的极限拉力和极限延伸率。结果表明：（1）浸胶稻草与天然稻草相比,吸水率最多可降低50%,证实防腐效果较好;（2）浸胶后,稻草的极限延伸率和极限拉力最大提高了26%和23%;（3）同是浸泡在海水中,浸胶后稻草较天然稻草,其极限延伸率和极限拉力的最大增长率为12%和11%;（4）浸胶稻草的SEM照片观察及能谱分析表明,SH胶包裹了纤维并进入到稻草的孔隙中,增强了纤维间的联结,提高了稻草的极限抗拉性能。SH胶防腐后的稻草作为加筋材料是可行的。     

现代地质工作重要发展领域：“十一五”期间勘查地球化学评述

“十一五”期间(2006-2010年),国土资源部中国地质调查局继续推进区域化探与多目标区域地球化学调查计划。在区域化探方面,完成调查面积82.93万km2(累计完成756.62万km2),发现异常4 708处,经验证发现各类矿产411处,其中有色金属矿产273处,占66.4%,取得重大找矿突破。开展矿产资源地球化学评价,通过建立典型矿床地球化学异常模式,来圈定找矿靶区和进行资源潜力定量预测。在多目标区域地球化学调查方面,完成调查面积26.56万km2(累积完成165.66万km2),建立生态地球化学评价体系,主要针对重金属元素成因来源、迁移转化、生态效应与变化趋势进行较为全面和深入的研究。土地质量地球化学评价表明,中国土地达到优质级占53%,优良级占33%,较差等级主要分布在中东部经济社会发达地区。土壤有机碳研究表明,全国表层土壤(0~0.2 m)平均碳密度仅为3 186 t/km2,且各地区碳密度变化幅度较大,说明中国土壤有机碳处于低水平和不稳定状态。“十一五”期间勘查地球化学针对重大资源与环境问题,深化和延拓地质工作内涵,逐步形成矿产资源评价、生态地质科学研究、土地质量与生态评价、全球变化科学研究及基础地学研究等现代地质工作若干重要发展领域。     

改进氨水-碘量法测定高银铜精矿中铜的含量

在对广西河池地区高银铜精矿中铜含量的测定中,由于样品中银含量较高,极大地影响终点判定,常用国标碘量法无法准确对铜含量进行定量.用氨水-碘量法将样品利用盐酸-硝酸-溴体系处理,样品充分溶解后,用盐酸去除高含量银残留的影响,用氨水-乙酸法调节溶液pH值,用硫代硫酸钠标准溶液滴定测定样品中铜的含量,结果满意.     

城市综合与专业地下管线空间数据的差异性分析

从管线数据来源及数据精度、数据模型、信息分类、数据语义等几个方面,本文对城市综合与专业两类地下管线空间数据进行了深入的差异分析,提出了差异形成的原因及消除差异的初步对策,以期对城市管线空间数据资源的集成、融合、共享、交换等技术提供支撑,并推动地下管线信息化统一标准的制订。