九龙江河口区表层水铀同位素的粒级分布

利用微滤和超滤技术研究了九龙江河口区表层水中铀及其同位素组成的粒级分布和地球化学行为.结果表明,溶解态(<0.4μm)中低分子量组分(<10 000 u)占主要份额,胶体态(10 000 u~0.4μm)238U所占比例不足1%,且随盐度的增加其所占份额逐渐降低.溶解态、低分子量组分和胶体态238U的比活度与盐度之间存在良好的线性正相关关系,证实它们在九龙江河口区呈现保守行为.在颗粒态(>0.4μm)中,各粒级组分238U所占份额主要受控于相应颗粒物的浓度,在盐度小于20的区域,各粒级颗粒组分238U占颗粒态的份额有如下变化次序:10~53μm>2~10μm>0.4~2μm>大于53μm,而在盐度大于30的近外海站位,该次序发生一些变化:0.4~2μm>10~53μm>2~10μm>大于53μm,最小粒级颗粒组分238U的贡献有所增加,反映了自生铀贡献的加强.九龙江河口区表层水中溶解态(包括低分子量组分和胶体态)的234U/238U)_A.R.均大于1,显示出234U过剩的特征,而各粒级颗粒组分中的234U/238U)_A.R.则接近于平衡值(1.0).这一现象与陆地岩石风化过程中水体对铀的淋滤释出量及234U的优先浸出有关.对232Th/238U质量比的研究显示,溶解态及其所包括的低分子量组分和胶体态的232Th/238U质量比均小于1,而颗粒态及其所包括的4个粒级组分中的232Th/238U质量比均大于1,反映了向外海输送过程中铀、钍地球化学行为的差异.     

罗非鱼、南美白对虾对重金属富集的研究

对广东省养殖的罗非鱼Oreochromis niloticus及南美白对虾Litopeneaus vannamei体内Pb、Cd、Hg、As 4种重金属富集及分布状况进行研究。比较了不同规格罗非鱼及南美白对虾体内重金属差异。分析重金属在罗非鱼及南美白对虾不同部位的分布状况。结果表明,罗非鱼及南美白对虾体内Pb、Cd、Hg、As均有不同程度的检出,但含量均低于国家限定标准(NY5125-2002);其中Pb的含量最高,罗非鱼和南美白对虾体内Pb含量最高值分别为限量的39.32%和42.18%;重金属含量因其规格大小及部位而异,趋势为大规格样品重金属含量相对较高,重金属含量在罗非鱼及南美白对虾体内的增长情况与其体重具有正相关性;罗非鱼内脏重金属含量明显高于肌肉组织,虾头为虾重金属富集的主要部位。     

A comparison of several wave spectra for the random wave diffraction by a semi-infinite breakwater

A comparison of the diffraction of multidirectional random waves using several selected wave spectrum models is presented in this paper. Six wave spectrum models, Bretschneider, Pierson–Moskowitz, ISSC, ITTC, Mitsuyasu, and JONSWAP spectrum, are considered. A discrete form for each of the given spectrum models is used to specify the incident wave conditions. Analytical solutions based on both the Fresnel integrals and polynomial approximations of the Fresnel integrals and numerical solutions of a boundary integral approach have been used to obtain the two-dimensional wave diffraction by a semi-infinite breakwater at uniform water depth. The diffraction of random waves is based on the cumulative superposition of linear diffraction solution. The results of predicted random wave diffraction for each of the given spectrum models are compared with those of the published physical model presented by Briggs et al. [1995. Wave diffraction around breakwater. Journal of Waterway, Port, Coastal and Ocean Engineering—ASCE 121(1), 23–35]. Reasonable agreement is obtained in all cases. The effect of the directional spreading function is also examined from the results of the random wave diffraction. Based on these comparisons, the present model for the analysis of various wave spectra is found to be an accurate and efficient tool for predicting the random wave field around a semi-infinite breakwater or inside a harbor of arbitrary geometry in practical applications.     

不同温度的有机溶剂分提对鯷鱼鱼油得率及脂肪酸组成的影响

讨论了不同温度的有机溶剂分级提取对鳀鱼鱼油得率、脂肪酸组成及EPA、DHA含量变化的影响。经15℃干法分级提取的液态鳀鱼鱼油,在设定的4种温度下,液态鳀鱼鱼油得率均随溶剂量的增加而提高;在相同溶剂量的情况下,随着分级提取温度的降低,液态鳀鱼鱼油得率呈下降的趋势。有机溶剂分级提取对14碳短碳链的饱和与不饱和脂肪酸及16碳、18碳的饱和脂肪酸的脱除效果是明显的,但对脱除20碳、22碳的长碳链饱和脂肪酸的效果不明显。在4种试验温度下,EPA和DHA的总量分别为29.88%、31.74%、35.27%和41.80%,高出美国阿拉斯佳深海鱼油对应总量(28.76%)的1.12%～13.04%。     

Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H2S concentrations

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.     

Distribution characteristics of zooplankton biomass in the East China Sea

On the basis of the data of oceanographic survey in the East China Sea in four seasons during 1997-2000 (23°30'~33°00'N, 118°30'-128°E), the variation of total biomass and diet biomass of zooplankton and their spatial-temporal distribution and relationship with the fishing ground of Engraulis japonicus are approached and analyzed. The results show that the average biomass is 65.32 mg/m3 in four seasons, autumn (86.18 mg/m3) being greater than summer (69.18 mg/m3) greater than spring (55.67 mg/m3) greater than winter (50.33 mg/m3). The average value of diet zooplankton biomass is 40.9 mg/m3. The trends of horizontal distribution both in the total biomass and the diet biomass of zooplankton are similar. The high biomass region (250-500 mg/m3) is very limited, only accounting for 1% of the investigation area. Seasonal variation of the biomass is very remarkable in the west and north parts of East China Sea coastal waters ( 29°30'N,125°E). The horizontal distribution of diet zooplankton depends on the     

虾蟹海产品香味的前体物质的加热变化

本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明：对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降，糖原是Ｍａｉｌｌａｒｄ反应的基础物质．不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分ＡＭＰ在加热后减少，而肌肉提取物中的游离氨基酸和结合氨基酸，特别是疏水氨基酸含量均增加。     

可编程序控制器的多机联用

多台可编程序控制器通过输入、输出点的直接连接,传递命令、状态和数据,实现多机联用系统。     

环胶州湾公路海上段汽车尾气的环境影响

对类比路段进行连续模拟试验,进行现场调查,给出汽车尾气主要污染物的排污强度,预测了汽车尾气中CO、C_nH_m和NO_x的扩散范围。     

我国海域分等定级指标体系研究

长期以来,海域的无偿使用导致海洋开发活动秩序混乱、海洋环境污染加剧、海洋生物资源枯竭、海洋生态环境遭到破坏,严重阻碍和制约沿海地区的可持续发展.本文试图根据经济学的“地租级差”理论和运筹学中的“层次分析法”并结合我国沿海11个省、市和自治区的社会、经济、基础设施、自然资源等因素进行理论探讨,给出了我国管辖海域的等级.为今后我国制定海域有偿使用金的征收标准奠定基础.