An advanced numerical model of elastomeric seismic isolation bearings

The nuclear accident at Fukushima Daiichi in March 2011 has led the nuclear community to consider seismic isolation for new large light water and small modular reactors to withstand the effects of beyond design basis loadings, including extreme earthquakes. The United States Nuclear Regulatory Commission is sponsoring a research project that will quantify the response of low damping rubber (LDR) and lead rubber (LR) bearings under loadings associated with extreme earthquakes. Under design basis loadings, the response of an elastomeric bearing is not expected to deviate from well‐established numerical models, and bearings are not expected to experience net tension. However, under extended or beyond design basis shaking, elastomer shear strains may exceed 300% in regions of high seismic hazard, bearings may experience net tension, the compression and tension stiffness will be affected by isolator lateral displacement, and the properties of the lead core in LR bearings will degrade in the short‐term because of substantial energy dissipation. New mathematical models of LDR and LR bearings are presented for the analysis of base isolated structures under design and beyond design basis shaking, explicitly considering both the effects of lateral displacement and cyclic vertical and horizontal loading. These mathematical models extend the available formulations in shear and compression. Phenomenological models are presented to describe the behavior of elastomeric isolation bearings in tension, including the cavitation and post‐cavitation behavior. The elastic mechanical properties make use of the two‐spring model. Strength degradation of LR bearing under cyclic shear loading due to heating of lead core is incorporated. The bilinear area reduction method is used to include variation of critical buckling load capacity with lateral displacement. The numerical models are coded in OpenSees, and the results of numerical analysis are compared with test data. The effect of different parameters on the response is investigated through a series of analyses. Copyright © 2014 John Wiley & Sons, Ltd.     

Objective assessment of instability indices for operational hail forecasting in Greece

Summary This paper examines the performance of several atmospheric instability indices for operational hail forecasting in the Greek National Hail Suppression Program (GNHSP). These indices are part of the adopted forecasting procedure in the GNHSP, which also involves a synoptic index of convection and a synoptic scale typing scheme. The assessment of the indices is accomplished objectively through a multivariate statistical technique, namely factor analysis. The analysis resulted in grouping of the indices into three factors. The indices with high loading and scores are considered to best detect convection for hail forecasting in the GNHSP.With 4 Figures     

The use of plastic debris as nesting material by a colonial seabird and associated entanglement mortality

Entanglement with plastic debris is a major cause of mortality in marine taxa, but the population-level consequences are unknown. Some seabirds collect marine debris for nesting material, which may lead to entanglement. Here we investigate the use of plastics as nesting material by northern gannets Morus bassanus and assess the associated levels of mortality. On average gannet nests contained 469.91 g (range 0-1293 g) of plastic, equating to an estimated colony total of 18.46 tonnes (range 4.47-42.34 tonnes). The majority of nesting material was synthetic rope, which appears to be used preferentially. On average 62.85 ± 26.84 (range minima 33-109) birds were entangled each year, totalling 525 individuals over eight years, the majority of which were nestlings. Although mortality rates are high, they are unlikely to have population-level effects. The use of synthetic fibres as nesting material is a common strategy among seabirds, but the impacts of entanglement warrants further investigation.     

Toxicity of antifouling biocides to the intertidal harpacticoid copepod Tigriopus japonicus (Crustacea, Copepoda): effects of temperature and salinity

Intertidal harpacticoid copepods are commonly used in eco-toxicity tests worldwide. They predominately live in mid-high shore rock pools and often experience a wide range of temperature and salinity fluctuation. Most eco-toxicity tests are conducted at fixed temperature and salinity and thus the influence of these environmental factors on chemical toxicity is largely unknown. This study investigated the combined effect of temperature and salinity on the acute toxicity of the copepod Tigriopus japonicus against two common biocides, copper (Cu) and tributyltin (TBT) using a 2 × 3 × 4 factorial design (i.e. two temperatures: 25 and 35 °C; three salinities: 15.0‰, 34.5‰ and 45.0‰; three levels of the biocide plus a control). Copper sulphate and tributyltin chloride were used as the test chemicals while distilled water and acetone were utilised as solvents for Cu and TBT respectively. 96h-LC50s of Cu and TBT were 1024 and 0.149 μg l⁻¹ respectively (at 25 °C; 34.5‰) and, based on these results, nominal biocide concentrations of LC0 (i.e. control), LC30, LC50 and LC70 were employed. Analysis of Covariance using ‘concentration’ as the covariate and both ‘temperature’ and ‘salinity’ as fixed factors, showed a significant interaction between temperature and salinity effects for Cu, mortality increasing with temperature but decreasing with elevated salinity. A similar result was revealed for TBT. Both temperature and salinity are, therefore, important factors affecting the results of acute eco-toxicity tests using these marine copepods. We recommend that such eco-toxicity tests should be conducted at a range of environmentally realistic temperature/salinity regimes, as this will enhance the sensitivity of the test and improve the safety margin in line with the precautionary principle.     

Estimating the elastic parameters of anisotropic media using a joint inversion of P-wave and SV-wave traveltime error

A method is presented to estimate the elastic parameters and thickness of media that are locally laterally homogeneous using P‐wave and vertically polarized shear‐wave (SV‐wave) data. This method is a ‘layer‐stripping’ technique, and it uses many aspects of common focal point (CFP) technology. For each layer, a focusing operator is computed using a model of the elastic parameters with which a CFP gather can be constructed using the seismic data. Assuming local homogeneity, the resulting differential time shifts (DTSs) represent error in the model due to anisotropy and error in thickness. In the (τ?p) domain, DTSs are traveltimes Δτ that connect error in layer thickness z, vertical slowness q, and ray parameter p. Series expansion is used to linearize Δτ with respect to error in the elastic parameters and thickness, and least‐squares inversion is used to update the model. For stability, joint inversion of P and SV data is employed and, as pure SV data are relatively rare, the use of mode‐converted (PSV) data to represent SV in the joint inversion is proposed. Analytic and synthetic examples are used to demonstrate the utility and practicality of this inversion.     

Vermiculite bio-barriers for Cu and Zn remediation: an eco-friendly approach for freshwater and sediments protection

The increase in heavy metal contamination in freshwater systems causes serious environmental problems in most industrialized countries, and the effort to find eco-friendly techniques for reducing water and sediment contamination is fundamental for environmental protection. Permeable barriers made of natural clays can be used as low-cost and eco-friendly materials for adsorbing heavy metals from water solution and thus reducing the sediment contamination. This study discusses the application of permeable barriers made of vermiculite clay for heavy metals remediation at the interface between water and sediments and investigates the possibility to increase their efficiency by loading the vermiculite surface with a microbial biofilm of Pseudomonas putida, which is well known to be a heavy metal accumulator. Some batch assays were performed to verify the uptake capacity of two systems and their adsorption kinetics, and the results indicated that the vermiculite bio-barrier system had a higher removal capacity than the vermiculite barrier (+34.4 and 22.8 % for Cu and Zn, respectively). Moreover, the presence of P. putida biofilm strongly contributed to fasten the kinetics of metals adsorption onto vermiculite sheets. In open-system conditions, the presence of a vermiculite barrier at the interface between water and sediment could reduce the sediment contamination up to 20 and 23 % for Cu and Zn, respectively, highlighting the efficiency of these eco-friendly materials for environmental applications. Nevertheless, the contribution of microbial biofilm in open-system setup should be optimized, and some important considerations about biofilm attachment in a continuous-flow system have been discussed.     

Results of chemical dating of monazite from the Talnakh economic intrusion (Russia)

Economic copper, nickel, and platinum-group element (PGE) deposits are associated with the Talnakh ultramafic–mafic intrusion of the Noril’sk Province in the northwestern part of the Siberian Platform. The results of the chemical Th–U–Pb dating of monazite from the ore-bearing melanotroctolites of the Talnakh intrusion are presented. The isotope-geochemical features of monazite are compared with zircon, sulfides, and baddeleyite.     

Metal and metalloid leaching from tailings into streamwater and sediments in the old Ag–Pb–Zn Terramonte mine,northern Portugal

Tailings deposited over the Castanheira, a stream which flows through the old Ag–Pb–Zn Terramonte mine area, showed a great potential environmental risk due to sulphide weathering, facilitated by the tailings–water interaction. The high concentrations of Al, Fe, Pb and Zn in the tailings are associated with the exchangeable, reducible and sulphide fractions and suggest sphalerite and pyrite occurrences. Oxidation of pyrite is responsible for the low pH values (3.38–4.89) of the tailings. The water from the Castanheira stream is not suitable for human consumption due to high concentrations of SO₄ ^2?, Mn, Al, Cd, Ni, and Pb. The lowest concentrations of metals and metalloids were detected in downstream stretches of the Castanheira. However, As, Fe and Zn in deeper sediments tend to increase downstream. Significant concentrations of trivalent forms of arsenic were detected in water samples. In downstream stretches of the Castanheira, some free ions (Fe²⁺, Mn²⁺ and Zn²⁺) also predominate and the water is saturated with ferrihydrite, goethite, hematite, lepidocrosite and magnetite.     

Trace metal dynamics in a seasonally anoxic lake

Selected results are presented from a detailed 12-month study of trace metals in a seasonally anoxic lake. Dissolved concentrations of Fe, Mn, organic carbon, Cd, Cu, Pb, Zn, and pH were determined in the water column and the interstitial waters on 39 occasions. Trace metal concentrations remained low throughout the year in both water column and pore waters. There was evidence for some remobilization at the sediment-water interface but sediments deeper than 3 cm acted as a sink throughout the year. Variations in the water concentrations were largely associated with increased loading during periods of heavy rainfall. During the summer, concentrations of Cu and Zn in the waters overlying the sediments were enhanced by release from decomposing algal material. Similarly, enhanced concentrations of Cd, Cu, Pb, and Zn were observed during periods of much reduced mixing during ice-cover. Although there were large seasonal variations in the concentrations of dissolved and particulate Fe and Mn, there were no comparable changes in the concentrations of trace metals.