Increasing critical sensitivity of the Load/Unload Response Ratio before large earthquakes with identified stress accumulation pattern

The Load/Unload Response Ratio (LURR) method is proposed for short-to-intermediate-term earthquake prediction [Yin, X.C., Chen, X.Z., Song, Z.P., Yin, C., 1995. A New Approach to Earthquake Prediction — The Load/Unload Response Ratio (LURR) Theory, Pure Appl. Geophys., 145, 701–715]. This method is based on measuring the ratio between Benioff strains released during the time periods of loading and unloading, corresponding to the Coulomb Failure Stress change induced by Earth tides on optimally oriented faults. According to the method, the LURR time series usually climb to an anomalously high peak prior to occurrence of a large earthquake. Previous studies have indicated that the size of critical seismogenic region selected for LURR measurements has great influence on the evaluation of LURR. In this study, we replace the circular region usually adopted in LURR practice with an area within which the tectonic stress change would mostly affect the Coulomb stress on a potential seismogenic fault of a future event. The Coulomb stress change before a hypothetical earthquake is calculated based on a simple back-slip dislocation model of the event. This new algorithm, by combining the LURR method with our choice of identified area with increased Coulomb stress, is devised to improve the sensitivity of LURR to measure criticality of stress accumulation before a large earthquake. Retrospective tests of this algorithm on four large earthquakes occurred in California over the last two decades show remarkable enhancement of the LURR precursory anomalies. For some strong events of lesser magnitudes occurred in the same neighborhoods and during the same time periods, significant anomalies are found if circular areas are used, and are not found if increased Coulomb stress areas are used for LURR data selection. The unique feature of this algorithm may provide stronger constraints on forecasts of the size and location of future large events.     

Study on the kinetics of iron oxide leaching by oxalic acid

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.     

Biostratigraphy of Jurassic-Cretaceous boundary sediments in the Eastern Crimea

The Dvuyakornaya Formation section in the eastern Crimea is described and subdivided into biostratigraphic units based on ammonites, foraminifers, and ostracodes. The lower part of the formation contains first discovered ammonites of the upper Kimmeridgian (Lingulaticears cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Olóriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian (?(Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel)). Based on the assemblage of characteristic ammonite species, the upper part of the formation is attributed to the Berriasian Jacobi Zone. Five biostratigraphic units (zones and beds with fauna) distinguished based on foraminifers are the Epistomina ventriosa-Melathrokerion eospirialis Beds and Anchispirocyclina lusitanica-Melathrokerion spirialis Zone in the upper Kimmeridgian-Tithonian, the Protopeneroplis ultragranulatus-Siphoninella antiqua, Frondicularia cuspidiata-Saracenaria inflanta zones, and Textularia crimica Beds in the Berriasian. The Cyrherelloidea tortuosa-Palaeocytheridea grossi Beds of the Upper Jurassic and Raymoorea peculiaris-Eucytherura ardescae-Protocythere revili Beds of the Berriasian are defined based on ostracodes. A new biostratigraphic scale is proposed for the upper Kimmeridgian-Berriasian of the eastern Crimea. The Dvyyakornaya Formation sediments are considered as deepwater facies accumulated on the continental slope.