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281.
Marie-Françoise André Bruno Phalip Olivier Voldoire Franck Vautier Yves Géraud Mhammed Benbakkar Christophe Constantin Fabienne Huber Gilles Morvan 《Environmental Earth Sciences》2011,63(7-8):1723-1739
This article is based on field investigations carried out at Ta Keo and Banteay Srei temples (Angkor, Cambodia), which have similar environmental histories and display the same recurrent decorative pattern (lotus petal) in three different sandstone lithotypes. Based on two original scales of mechanical and chemical weathering, the degree of deterioration of c.2000 sandstone petals was visually assessed, resulting in the proposal of a durability scale. An explanatory scheme was provided, based on laboratory analyses of stone materials (ICP-AES, XRD, SEM-EDS, polarizing microscopy and mercury injection). The key drivers of sandstone durability are both mineralogical and petrophysical. The remarkable preservation of the pink sandstone is due to the quartzose nature of its clasts, the non-swelling clay content of its abundant matrix (kaolinite) and its porosity structure (large connected pores and probable non-connected porosity). The overall good preservation of the green sandstone is due to its extremely low porosity and specific surface area, associated with its strong cementation. The severe deterioration of the grey sandstone is due to its laminated structure (oriented biotites), the susceptibility to hygric swelling and solution of its binding agents (chlorite/smectite and calcite) and its porosity structure, which evolves during a two-stage weathering sequence. The first stage is characterized by a bimodal porosity due to the partial clogging of macropores by swelling clays, and the second stage by a substantial increase in porosity and the penetration of salts (barite and anhydrite). Conversely, oxidation phenomena associated with weathering can lead to a drastic reduction of porosity. 相似文献
282.
Bruno Hamelin Gérard Manhes Francis Albarede Claude J. Allègre 《Geochimica et cosmochimica acta》1985,49(1):173-182
A reappraisal of the “Double Spike Method” for correction of the mass discrimination in lead isotope analysis is presented in view of the possible efficiency of this method, especially as related to the improved performance of the new multi-collector mass spectrometers.First, the effects of mass discrimination during lead isotope analysis, using the silica-gel phosphoric acid method, are discussed in order to verify the validity of the linear discrimination law. In this discussion, we give evidence of a slight bias of the isotopic composition of the SRM 981 NBS lead standard, commonly used for mass discrimination calibrations.A rigorous way to deal with the propagation of the within-run statistical errors on the precision of the double spike correction is then presented. This allows the optimization of the parameters of the method (spike isotopic composition and precision, spiking proportion) and the calculation of the respective error associated with each corrected isotopic ratio. The perturbation of the double spike correction due to analytical contamination, which has caused previous failure in the application of the method, is avoided by preparation of the mixture between the spike and the sample at the very end of the chemical separation procedure.Using a single collector mass spectrometer, examples of application on lead standards and on a set of samples suggest a possible improvement in the precision by a factor of 3 compared to the usual method of fractionation normalization and confirm the usefulness of the method with the new generation of mass spectrometers. 相似文献
283.
Aesthetic characteristics are important when rocks are used as construction materials. Among all the surface finishes available, the polished finish is the one which best enhances the rock attractiveness. Colour (C), roughness (R) and gloss (G) are surface properties usually used to assess the rock polishing. In this research, the CRG properties were assessed in polished samples of three ornamental granites with different textures and physical–mechanical properties, one weathered and two sound. C was evaluated in CIE-L * a * b * and CIE-L * C * ab h ab systems, R with R a and R z parameters and G using the 20°, 60° and 85° geometries. The weathered granite presents a noticeable colour variation, especially in the b * parameter, while the sound ones have a more homogeneous colour. Sound and more textural homogeneous granites have a low surface roughness and high gloss, which are uniformly distributed. The weathered granite shows a higher surface roughness and lower gloss, with scattered distribution. The mineral contacts are the main cause of the surface irregularities. The results show the interdependence between the CRG properties and stress the importance of the polishing process for enhancing the aesthetic characteristics of the granites. CRG properties could be used for quality control in granite processing plants, thus avoiding noticeable differences in the facades of buildings, particularly when weathered granites are used. 相似文献
284.
Bruno Goffé William M. Murphy Martine Lagache 《Contributions to Mineralogy and Petrology》1987,97(4):438-450
A study of hydrothermal vein mineralization in meta-argillites subjected to high-pressure, low-temperature metamorphism reveals that ferromagnesian (e.g., chlorite) and pure aluminosilicate (e.g., pyrophyllite) mineralization can be correlated with regimes of increasing and decreasing temperature, respectively. An experimental study of the transport of silica, aluminum and magnesium in hydrothermal solutions has been undertaken to simulate variations in the physical conditions during metamorphism and the accompanying mass transport in a closed system. Thermodynamic and kinetic analysis of the experimental results indicates that local equilibrium among aqueous and mineral phases controls the distribution and composition of hydrothermal vein mineralization and that vein mineralogy can be used to infer the sense of variation of pressure and temperature during metamorphism. 相似文献
285.
286.
Hubble Space Telescope (HST) images of Prometheus and Pandora show longitude discrepancies of about 20° with respect to the Voyager ephemerides, with an abrupt change in mean motion at the end of 2000 (French et al., 2003, Icarus 162, 143-170; French and McGhee, 2003, Bull. Am. Astron. Soc. 34, 06.07). These discrepancies are anti-correlated and arise from chaotic interactions between the two moons, occurring at interval of 6.2 yr, when their apses are anti-aligned (Goldreich and Rappaport, 2003a, Icarus 162, 391-399). This behavior is attributed to the overlap of four 121:118 apse-type mean motion resonances (Goldreich and Rappaport, 2003b, Icarus 166, 320-327). We study the Prometheus-Pandora system using a Radau-type integrator taking into account Saturn's oblateness up to and including terms in J6, plus the effects of the major satellites. We first confirm the chaotic behavior of Prometheus and Pandora. By fitting the numerical integrations to the HST data (French et al., 2003, Icarus 162, 143-170; French and McGhee, 2003, Bull. Am. Astron. Soc. 34, 06.07), we derive the satellite masses. The resulting GM values (with their standard 3-σ errors) for Prometheus and Pandora are respectively and . Using the nominal shape of the two moons (Thomas, 1989, Icarus 77, 248-274), we derive Prometheus and Pandora's densities, 0.40+0.03−0.07 and 0.49+0.05−0.09 g cm−3, respectively. Our numerical fits also enable us to constrain the time of the latest apse anti-alignment in 2000. Finally, using our fit, we predict the orbital positions of the two satellites during the Cassini tour, and provide a lower limit of the uncertainties due to chaos. These uncertainties amount to about 0.2° in mean longitude at the arrival of the Cassini spacecraft in July 2004, and to about 3° in 2008, at the end of the nominal tour. 相似文献
287.
Pier Paolo Bruno 《Bulletin of Volcanology》2004,66(4):342-355
Digital marine seismic reflection data acquired in 1973 in the Bay of Pozzuoli, and recently reprocessed, were used to study the volcanological evolution of the marine sector of Campi Flegrei Caldera during the last 37 ka. In order to gain more information, interpretation also involved estimation of the "pseudo-velocity" and the "pseudo-density" from the resistivity logs of two onshore deep exploration wells. The main results are: (1) discovery of ancient pre-18 ka and post-37 ka submarine and mainly effusive volcanic activity, along coeval emission centers located at the edges of Campi Flegrei Caldera; (2) confirmation that the caldera collapse in the marine sector of Campi Flegrei seems strongly controlled by regional NE–SW and NW–SE structural discontinuities; (3) the finding of at least two episodes of collapse in the bay; and (4) identification of a post-18 ka volcanic deflation phase that has caused about 150–200 m of subsidence in the central sector of the Bay of Pozzuoli in the last 18 ka.Editorial responsibilty: T. Druitt 相似文献
288.
Monitoring chemical contamination levels in the Mediterranean based on the use of mussel caging 总被引:3,自引:0,他引:3
Andral B Stanisiere JY Sauzade D Damier E Thebault H Galgani F Boissery P 《Marine pollution bulletin》2004,49(9-10):704-712
Within the framework of the biointegrator network (RINBIO), 92 man-made cages containing mussels (Mytilus galloprovincialis), distributed over 1800 km of the French Mediterranean coast, made it possible to assess chemical contamination by heavy metals (Cd, Hg, Zn, Pb, Cu, Ni, Cr, As) and organic compounds (DDT, PCBs, HAP). The caging technique was adopted to compensate for the scarcity of natural shellfish stocks in the Mediterranean and to enable comparison of the sites regardless of their physicochemical and trophic characteristics. Models linking a biometric parameter (the condition index) to pollutant levels make it possible to adjust raw data on contamination for a reference individual, by making a clear distinction between physiological factors (growth) and environmental ones. The results demonstrate significant levels of pollutants in sites heretofore unsampled; the pollution occurs at limited areas, and the sources have been identified. Moreover, average contamination levels are comparable to those measured in wild species and in other areas. Overall, the research demonstrates the reliability of this methodological approach for monitoring marine pollution, especially in the Mediterranean. 相似文献
289.
290.
This study aims at quantifying the effect of rheology on plan-view shapes of lava flows using fractal geometry. Plan-view shapes of lava flows are important because they reflect the processes governing flow emplacement and may provide insight into lava-flow rheology and dynamics. In our earlier investigation (Bruno et al. 1992), we reported that flow margins of basalts are fractal, having a characteristic shape regardless of scale. We also found we could use fractal dimension (D, a parameter which quantifies flow-margin convolution) to distinguish between the two endmember types of basalts: a a (D: 1.05–1.09) and pahoehoe (D: 1.13–1.23). In this work, we confirm those earlier results for basalts based on a larger database and over a wider range of scale (0.125 m–2.4 km). Additionally, we analyze ten silicic flows (SiO2: 52–74%) over a similar scale range (10 m–4.5 km). We note that silicic flows tend to exhibit scale-dependent, or non-fractal, behavior. We attribute this breakdown of fractal behavior at increased silica contents to the suppression of small-scale features in the flow margin, due to the higher viscosities and yield strengths of silicic flows. These results suggest we can use the fractal properties of flow margins as a remote-sensing tool to distinguish flow types. Our evaluation of the nonlinear aspects of flow dynamics indicates a tendency toward fractal behavior for basaltic lavas whose flow is controlled by internal fluid dynamic processes. For silicic flows, or basaltic flows whose flow is controlled by steep slopes, our evaluation indicates non-fractal behavior, consistent with our observations. 相似文献