GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.     

Update of Canadian Historical Snow Survey Data and Analysis of Snow Water Equivalent Trends, 1967–2016

ABSTRACT

In situ observations of snow water equivalent (SWE) from manual snow surveys and automated sensors are made at approximately 1000 sites across Canada in support of water resource planning for flood control and hydroelectricity production. These data represent an important source of information for research (e.g., validation of hydrological and climate models), for applied studies (e.g., ground snow loads), and for climate monitoring. This note describes the process to update a Canadian historical snow survey dataset to 2016 and the production of a 0.1° gridded version for research applications. Analysis of trends in SWE, snow depth (SD), and density over the 50-year period from 1967 to 2016 revealed large spatial variability in trend sign and strength, with a relatively small percentage of points showing statistically significant trends. Where SWE and SD trends were significant, they tended to be negative, which is consistent with previous investigations of snow cover changes in Canada. The results show evidence of a latitudinal dependence in SWE trends, with the largest negative trends occurring over lower latitudes, and a tendency for mainly positive trends in Arctic SWE, which is consistent with observations from Russia and climate model projections of the response of Arctic snow cover to climate warming. Arctic sites also showed evidence of an increasing trend in 1 April snowpack density of 6.6?kg m^?3 per decade but little corresponding change in SD. This has potentially important consequences for the soil thermal regime because it provides a cooling influence from an increase in the snowpack effective thermal conductivity. The snow survey dataset is available from the Government of Canada Open Data portal.     

Classes of Families of Generalized Periodic Solutions to the Beletsky Equation

For the equation describing plane oscillations and rotations of a satellite, we consider families of symmetric generalized periodic solutions with integral rotation number p. We give new confirmations of the hypothesis: there are only four classes of these families with topologically different structures, namely, the classes of families of periodic solutions with p≥ 1, p= 0, p=−1, and p≤−2. Besides, we demonstrate that the vertices of cusps of these families are placed on some analytical curves, and the same is true for the multiple intersections of these families with other families.     

On the detectability of H2S in Jupiter

The influence of hydrogen sulfide, a still-undetected key molecule for the Jovian atmospheric chemistry in the infrared spectrum, was investigated. Synthetic spectra including various vertical distribution profiles of H₂S have been computed and compared with observational data for Jupiter in the 2- to 15-cm^?1 and 1160- to 1200-cm^?1 spectral ranges. No firm conclusion about the presence of H₂S can be drawn from the latter spectral region because of large uncertainties in gaseous opacities. In the microwave range, H₂S is found to be a possible candidate to explain the measurements. Constraints to its vertical distribution which would imply a significant supersaturation in the troposphere are derived. Physical and chemical processes involving H₂S in the atmosphere are discussed in the light of this hypothesis.