The state of water resources in major Mediterranean islands

This work analyses the state of water resources in six Mediterranean islands: Corsica, Crete, Cyprus, Mallorca, Malta and Sicily. The analysis is focused on the prevailing social, economic and hydroclimatological characteristics of these islands in order to identify the main common features affecting water availability, demand and use. A detailed analysis of the state of water resources in all the considered islands has been carried out. A background of current conditions relating to freshwater availability, quality and use has been established. Different strategies to face water scarcity and enhance water quality in theislands have been assessed in a context of climate change which is a common threat. The identification of similar problems for all the islands highlights the importance of strengthening inter-islands co-operation in the field of sustainable water resources management.     

Bedload transport measurements at the Erlenbach stream with geophones and automated basket samplers

In the Erlenbach stream, a pre‐alpine steep channel in Switzerland, sediment transport has been monitored for more than 25 years. Near the confluence with the main valley river, stream flow is monitored and sediment is collected in a retention basin with a capacity of about 2000 m³. The basin is surveyed at regular intervals and after large flood events. In addition, sediment transport has been continuously monitored with piezoelectric bedload impact and geophone sensors since 1986. In 2008–2009, the measuring system in the Erlenbach stream was enhanced by installing an automatic system to obtain bedload samples. Movable metal baskets are mounted on a rail at the downstream wall of the large check dam above the retention basin, and they can be moved automatically into the flow to take bedload transport samples. The wire mesh of the baskets has a spacing of 10 mm to sample all sediment particles coarser than this size (which is about the limiting grain size detected by the geophones). The upgraded measuring system permits to obtain bedload samples over short sampling periods and to measure the grain size distribution of the transported material and its variation over time and with discharge. The analysis of calibration relationships for the geophone measuring system confirms findings from very similar measurements which were performed until 1999 with piezoelectric bedload impact sensors; there is a linear relationship between impulse counts and bedload mass passing over the sensors. Findings from flume experiments are used to discuss the most important factors which affect the calibration of the geophone signal. The bedload transport rates as measured by the moving baskets are among the highest measured in natural streams, with values of the order of several kilograms per meter per second. Copyright © 2012 John Wiley & Sons, Ltd.     

Influence of different mechanical column-foundation connection devices on the seismic behaviour of precast structures

Dry-assembled precast concrete frame structures are typically made with dowel beam-to-column connections, which allow relative rotation along the beam direction. In the orthogonal direction the rotation of the beam is prevented but again the connections of the superimposed floor elements allow for relative rotation. All the ductility and energy dissipation demand in case of seismic action is therefore concentrated at the base of cantilever columns. Hence, the column-to-foundation connection plays a key role on the seismic performance of such structures. Mechanical connection devices, even if correctly designed for what concerns resistance, may affect the behaviour of the whole joint modifying the ductility capacity of the columns and their energy dissipation properties. An experimental campaign on different mechanical connection devices has been performed at Politecnico di Milano within the Safecast project (European programme FP7-SME-2007-2, Grant agreement No. 218417, 2009). The results of cyclic tests on full scale structural sub-assembly specimens are presented. Design rules are suggested for each of the tested connections on the basis of the experimental observations, and numerical analyses have been performed with hysteretic parameters calibrated on the experimental loops. The seismic performance of structures provided with those connections is investigated through a case study on a multi-storey precast building prototype, which has also been subject to full-scale pseudo-dynamic testing within the same research project at the European Laboratory of Structural Assessment of the Joint Research Centre of the European Commission. The comparison of the results from the structure provided with the different studied connections clearly highlights how some solutions may lead to both reduction of ductility capacity and dissipation of energy, increasing the expected structural damage and the seismic risk.     

Tracing clinothem geometry and sediment pathways in the prograding Holocene Po Delta system through integrated core stratigraphy

Though clinothem geometry represents a key control on fluid flow in reservoir modelling, tracing clinothem boundaries accurately is commonly limited by the lack of sufficiently precise outcrop or subsurface data. This study shows that in basin systems with strongly heterogeneous compositional signatures, the combination of bulk-sediment geochemistry and benthic foraminiferal distribution can help identify clinothem architecture and generate realistic models of 3D deltaic upbuilding and evolution. Middle-late Holocene deposits in the Po Delta area form an aggradational to progradational parasequence set that reveals the complex interaction of W–E Po Delta progradation, S-directed longshore currents (from Alpine rivers) and Apennines rivers supply. Unique catchment lithologies (ophiolite rocks and dolostones) were used to delineate basin-wide geochemical markers of sediment provenance (Cr and Mg) and to assess distinctive detrital signatures. The geochemical characterization of cored intervals across different components of the sediment routing system enabled a direct linkage between clinothem growth, transport pathways and provenance mixing to be established. On the other hand, abrupt microfaunal variations at clinothem boundaries were observed to reflect the palaeoenvironmental response to sharp changes in sediment flux and fluvial influence. This study documents the ability of an integrated geochemical and palaeoecological approach to delineate three distinct sources (Po, Alps and Apennines) that contributed to coastal progradation and to outline the otherwise lithologically cryptic geometries of clinothems that using conventional sedimentological methods it would be virtually impossible to restore.     

TIMS measurements of Ra and Ra in the Gulf of Lion, an attempt to quantify submarine groundwater discharge

Submarine groundwater discharge (SGD) is now recognized as an important pathway for water and chemical species fluxes to the coastal ocean. In order to determinate SGD to the Gulf of Lion (France), we measured the activities of ²²⁶Ra and ²²⁸Ra by thermal ionization mass spectrometry (TIMS) in coastal waters and in the deep aquifer waters of the Rhone deltaic plain after pre-concentration of radium by MnO₂. Compared to conventional counting techniques, TIMS requires lower quantities of water for the analyses, and leads to higher analytical precision. Radium isotopes were thus measured on 0.25–2 L water samples containing as little as 20 fg of ²²⁶Ra and 0.2–0.4 fg of ²²⁸Ra with precision equal to 2%. We demonstrate that coastal surface waters samples are enriched in ²²⁶Ra and ²²⁸Ra compared to the samples further offshore. The high precision radium measurements display a small but significant ²²⁶Ra and ²²⁸Ra enrichment within a strip of circa 30 km from the coast. Radium activities decrease beyond this region, entrained in the northern current along the shelf break or controlled by eddy diffusion. The radium excess in the first 30 km cannot be accounted for by the river nor by the early diagenesis. The primary source of the radium enrichment must therefore be ascribed to the discharge of submarine groundwater. Using a mass-balance model, we estimated the advective fluxes of ²²⁶Ra and ²²⁸Ra through SGD to be 5.2 × 10¹⁰ and 21 × 10¹⁰ dpm/d respectively. The ²²⁶Ra activities measured in the groundwater from the Rhone deltaic plain aquifer are comparable to those from other coastal groundwater studies throughout the world. By contrast, ²²⁸Ra activities are higher by up to one order of magnitude. Taking those groundwater radium activities as typical of the submarine groundwater end-member, a minimum volume of 0.24–4.5 × 10¹⁰ l/d is required to support the excess radium isotopes on the inner shelf. This has to be compared with the average rivers water runoff of 15.4 × 10¹⁰ l/d during the study period (1.6 to 29% of the river flow).     

Reduction of Multiphase Atmospheric Chemistry

The aim of this article is to investigate the dynamical behaviour ofmultiphase atmospheric chemical mechanisms. Reducing procedures areapplied to a multiphase chemical box model including gas-phasereactions, aqueous-phase reactions and interfacial mass transfer. The lumping of species is computed in an automatic wayusing an efficient algorithm (apla). The computed lumped species arerelated to the fast behaviour of chemical and microphysical processessuch as Chapman cycle, ionic dissociations within the cloud drops andinterfacial Henry's equilibria. Depending on some parameters (liquidwater content, droplet radius) mixed lumped species (including both phases) may also becomputed. We show the existence of hierarchical reduced models due to the existence ofmultiple timescales. We use a special algorithm (dan2) in order tosolve the reduced models. Such models are accurate and the relative errorremains under the threshold of 1%. The speed-up is up to a factor 5comparedwith a fully implicit method (Gear) for the same accuracy. The key pointis that it provides a good qualitative understanding for the behaviourof the kinetic scheme.     

Magnetic fabric of Late Miocene clay-rich sediments from the southern Pannonian basin

The magnetic fabric of Late Miocene sediments from the southern Pannonian basin was studied on oriented samples collected from 19 geographically distributed localities. All of them are characterized by near-horizontal magnetic foliation plane after tilt correction, indicating weak deformation. Well-developed lineations were observed for 16 localities, which are interpreted as due to compressional/transpressional deformation, except from three localities, where the fabric must have been formed in an extensional setting. Comparison between the orientation of the map-scale folds and faults and magnetic lineation directions shows that magnetic lineation is either related to NNE-SSW directed compression, leading to the formation of folds or it can be connected to NW–SE or NNE-SSW trending dextral faults.     

Complete Trace Elemental Characterisation of Granitoid (USGS G-2, GSP-2) Reference Materials by High Resolution Inductively Coupled Plasma-Mass Spectrometry

The United States Geological Survey granitic and granodioritic reference materials G‐2 and GSP‐2 were decomposed in high‐pressure bombs using both HF‐HNO₃ and HF‐HNO₃‐HClO₄ in order to evaluate the feasibility of characterising the entire suite of geologically relevant trace elements through direct analysis with a high‐resolution inductively coupled plasma‐mass spectrometer (HR‐ICP‐MS). The digested samples were diluted to the appropriate levels and analysed at low, medium and high resolution depending on the required sensitivity and potential interferences for each element. Memory effects during analysis of the high field strength elements (HFSE) were negligible when analysed using an all‐Teflon, uncooled sample introduction system and combined with adequate wash times with 4% v/v aqua regia + 0.5% v/v HF between samples. The concentration of the remaining lithophile elements was determined with a conventional, cooled, Scott‐type spray chamber using a wash solution of 1% v/v HNO₃. Total procedural blanks contributed between 0.01 to 0.5% to final sample concentrations and blank subtractions were typically unnecessary. Abundances for Li, Hf, Ba, Zr, Ga, Rb, Sr, La, Ce, Th and U were systematically higher, while those for the heavy rare earth elements (HREEs), Cu and Y were systematically lower in this study compared to USGS values for G‐2 and GSP‐2. This is likely to be related to, respectively, higher recoveries from more efficient digestion of refractory phases (i.e., zircon, tourmaline), and better resolution of interferences when using a HR‐ICP‐MS. Sample digestion experiments also showed that perchloric acid digestion in high pressure bombs resulted in superior recoveries and better precision for the bulk of the trace elements analysed. The concentration of the remaining elements overlapped within uncertainty with recommended reference values and with values determined in other studies using isotope‐dilution TIMS, ICP‐MS and XRF. Concentrations for the elements Cd, Sn, Sb, Ta, Bi, Tb, Ni and Mo are also reported for G‐2 and GSP‐2 reference materials. Our study shows therefore that it is feasible to determine thirty‐nine geologically relevant trace elements accurately and directly in granitoid sample digests when using a HR‐ICP‐MS, thereby negating the need for ion exchange or isotopic spiking.