From aqueous solution to solid solutions: A process oriented review of the work performed within the FUNMIG project

The Fundamentals of Radionuclide Migration (FUNMIG) project was organised in some Research and Technological Development Components (RTDCs) integrated by a number of Work Packages (WP’s) attempting to cover the key migration processes at different scales (laboratory to repository) and in different geological media, mainly clay and granite, but also some salt rock related work was performed. The main RTDCs of interest for this review paper are numbers 1 and 2, which concerned laboratory studies of well-established and less-established migration processes. Some additional interesting outcomes arise also from RTDCs 3, 4 and 5 devoted to the upscaling and applicability of migration processes to clay, granite and salt rock environments, respectively. This review discusses the contribution of the various parts of the FUNMIG project in the process oriented context of understanding the mechanistic approximation to what can be seen as the final and thermodynamically stable stage of the long chain of processes which are covered under the general term of sorption and that culminate in the formation of solid solutions.     

Large wood load fluctuations in an Andean basin

The importance of monitoring and analysing wood fluxes in mountain environments is widely recognized. However, there is a lack of information related to the long-term fluctuations in wood load and associated to the changes in large wood (LW) characteristics. The main aims of the research were to analyse (i) changes in wood characteristics, (ii) fluctuations in wood load, and (iii) the relationship between wood load and sub-reach settings, proposing an ad hoc roughness index (RI). Repeated field surveys to measure wood load and LW characteristics during a 13-year period were conducted within a 2.2 km-long reach of the Rio Toro (Chile), which flows through the Malleco Forest National Reserve that was affected by wildfires in 2002 and 2015. Two spatial scales (i.e. study reach and sub-reach) were considered. Irrespective of the adopted scale wood load fluctuated considerably, in both number and volume, with significant changes in LW characteristics (i.e. mean diameter and length). Moreover, a clear tendency to the aggregation in wood jams (WJs) was observed within the entire study reach. Based on our results, we conclude that 17 years after the first wildfire wood recruitment has started in the upper parts of the basin. Moreover, Generalized Linear Mixed Models (GLMM) analyses were carried out to investigate the relationship between RI and both number and volume of LW. Both models are characterized by high adjusted R² of 74.9% and 72.8% for volume and number, respectively. This demonstrated that the RI can characterize the reaches in terms of tendency to deposition and trapping of wood. These results are promising, particularly in improving the knowledge related to potential deposition areas that can control wood load fluctuations, also permitting its management to be improved. © 2020 John Wiley & Sons, Ltd.     

Pluri-annual recharge assessment using vertical soil temperature profiles: Example of the Seine river basin (1984–2001)

Among the various methods used to determine vertical water seepage in unsaturated soils, thermal convection presents significant advantages: temperature measurements are simple to perform and record, and a wide range of time scales can be considered. The authors analysed the data recorded by the meteorological stations of the Seine river basin, at three different depths: 20, 50 and 100 cm. As the measurement sensitivity was limited to 0.1 K, long series of data needed to be stacked in order to obtain sufficient precision to quantify the convective component of heat transfer, in a predominantly conductive context. For the period from 1984 to 2001, it was possible to determine the average recharge at each station, and the recharge variation between groups of three-year periods. By interpolating these data over the whole basin, a global assessment has been made and compared to the exported flow rate at the river mouth: the resulting value of 94 mm yr^?1 lies between the lowest annual rate, 52 mm yr^?1, and the mean total exported value of 252 mm yr^?1.     

Regional modeling of carbonaceous aerosols over Europe—focus on secondary organic aerosols

In this study, an improved and complete secondary organic aerosols (SOA) chemistry scheme was implemented in the CHIMERE model. The implementation of isoprene chemistry for SOA significantly improves agreement between long series of simulated and observed particulate matter concentrations. While simulated organic carbon concentrations are clearly improved at elevated sites by adding the SOA scheme, time correlation are impaired at low level sites in Portugal, Italy and Slovakia. At several sites a clear underestimation by the CHIMERE model is noticed in wintertime possibly due to missing wood burning emissions as shown in previous modeling studies. In Europe, the CHIMERE model gives yearly average SOA concentrations ranging from 0.5 μg m ^− 3 in the Northern Europe to 4 μg m ^− 3 over forested regions in Spain, France, Germany and Italy. In addition, our work suggests that during the highest fire emission periods, fires can be the dominant source of primary organic carbon over the Mediterranean Basin, but the SOA contribution from fire emissions is low. Isoprene chemistry has a strong impact on SOA formation when using current available kinetic schemes.     

Structural reworking and heat transfer related to the late-Panafrican Angavo shear zone of Madagascar

The basement of central Madagascar displays two contrasted structural patterns. The first one (D1) is characterized by north-striking foliations that are gently dipping to the west and carry W- to WSW-plunging lineations, whereas the second one (D2) is characterized by steeper foliations that are striking to the NNE and lineations that are either subhorizontal or gently plunging to the SSW. The younger pattern is related to late-Panafrican tectonics along the major Angavo shear zone that is about 1000 km in length and 40 km in width with apparently little offset. Deformation in the Angavo zone induced interference folding on both sides. The D2 event is characterized by low pressures (ca 400 MPa) and high temperatures (up to 790 °C) responsible for prograde granulite facies conditions, that resulted from heat transfer due to magma and fluid advection in the Angavo shear zone. The D2 event is pinned at 550 ± 11 Ma by a new monazite age from a reoriented Andringitrean granite near Ankaramena. A new suite of amphibole and biotite Ar–Ar geochronological data enables to retrace the thermochronogical evolution inside and outside the Angavo shear zone. Combined with new structural results from the western interference zone, these ages yield a better understanding of the late-Panafrican history of central Madagascar. No diachronism is observed along the strike of the Angavo shear zone. Conversely, amphibole and especially biotite ages decrease from West to East, i.e. towards the shear zone. These new ages range from 511 to 469 Ma. A 1-D conductive model constrains the thermal effect in relation with the Angavo shear zone to be restricted to a lateral distance of ca 60 km (in map view) for a maximum heating duration of 20 Myr. This is in agreement with the Ar–Ar data and with the width of the observed interference zone. Following this episode of deformation and heat transfer, the estimated cooling rates of the Angavo shear zone range from to 15 to 6 °C/Myr, respectively before and after 515 Ma. A post-collision intracontinental setting is suggested for the Angavo shear zone, which is regarded as a remote effect of the Kuunga Orogeny between India and Antarctica.     

Effects of non-stoichiometry on the spinel structure at high pressure: Implications for Earth’s mantle mineralogy

A non-stoichiometric sample of spinel with composition ^T(Mg_0.4Al_0.6)^M(Al_1.8□_0.2)O₄ was investigated by single-crystal X-ray diffraction in situ up to about 8.7 GPa using a diamond anvil cell. The P(V) data were fitted using a third-order Birch-Murnaghan equation of state and the unit-cell volume V₀, the bulk modulus K_T0 and its first pressure derivative K′ were refined simultaneously providing the following coefficients: V₀ = 510.34(6) Å³, K_T0 = 171(2) GPa, K′ = 7.3(6). This K_T0 value represents the lowest ever found for spinel crystal structures. Comparing our data with a stoichiometric and natural MgAl₂O₄ (pure composition) we observe a decrease in K_T0 by about 11.5% and a strong increase in K′ by about 33%. These results demonstrate how an excess of Al accompanied by the formation of significant cation vacancies at octahedral site strongly affects the thermodynamic properties of spinel structure. If we consider that the estimated mantle composition is characterized by 3-5% of Al₂O₃ this could imply an Mg/Al substitution with possible formation of cation vacancies. The results of our study indicate that geodynamic models should take into account the potential effect of Mg/Al substitution on the incompressibility of the main mantle-forming minerals (olivine, wadsleyite, ringwoodite, Mg-perovskite).     

Family <Emphasis Type="Italic">h</Emphasis> of periodic solutions of the restricted problem for big μ

The results of the computation of the family h of symmetric periodic solutions of the circular planar restricted three-body problem for μ = 0.3, 0.4, and 0.5 are presented. This family begins with retrograde circular orbits around a massive body. Associated with each value of μ are the table of critical orbits, the orbit pictures, the graphs of characteristics of the family in four coordinate systems, and the graphs of the period and traces (planar and vertical). Regularities on the family and its evolution as μ increased were observed.     

Extension of fast periodic transfer orbits from the Earth–Moon RTBP to the Sun–Earth–Moon Quasi-Bicircular Problem

Starting from 80 families of low-energy fast periodic transfer orbits in the Earth–Moon planar circular Restricted Three Body Problem (RTBP), we obtain by analytical continuation 11 periodic orbits and 25 periodic arcs with similar properties in the Sun–Earth–Moon Quasi-Bicircular Problem (QBCP). A novel and very simple procedure is introduced giving the solar phases at which to attempt continuation. Detailed numerical results for each periodic orbit and arc found are given, including their stability parameters and minimal distances to the Earth and Moon. The periods of these orbits are between 2.5 and 5 synodic months, their energies are among the lowest possible to achieve an Earth–Moon transfer, and they show a diversity of circumlunar trajectories, making them good candidates for missions requiring repeated passages around the Earth and the Moon with close approaches to the last.     

On-line recognition of supernova neutrino bursts in the LVD

In this paper we show the capabilities of the Large Volume Detector (INFN Gran Sasso National Laboratory) to identify a neutrino burst associated with a supernova explosion, in the absence of an “external trigger”, e.g., an optical observation. We describe how the detector trigger and event selection have been optimized for this purpose, and we detail the algorithm used for the on-line burst recognition. The on-line sensitivity of the detector is defined and discussed in terms of supernova distance and intensity at the source.