Spatial concentration and variability of rainfall in the Iguaçu River Basin,State of Paraná−Brazil

The analysis of rainfall as an environmental factor that influences landscape dynamics is an important and ongoing topic of discussion. This discussion can be centred on the discovery of impacts caused by the increase or decrease in rainfall frequency and intensity. From this perspective, this study sought to analyse the rainfall variability in the Iguaçu River basin, located in the State of Paraná, southern Brazil. The main objective was focused on the temporal-spatial rainfall distribution in the study area and its interaction with landscape dynamics (different land uses). Precipitation data for the period 1988−2018 were obtained from the ‘Águas Paraná’ Institute. To calculate the Concentration Index−CI values of the study area, data analysis was performed using the ‘R’ software with Climatol and Precindicon subroutines of the software, and analysis of Landsat 8 satellite images through ArcGIS. The results indicated that there was a well-defined spatial variability in the study area, as the CIs defined higher rainfall concentrations upstream from the river basin and lower rainfall concentrations downstream—implying that these processes may be strongly associated with land use.     

Building footprint database improvement for 3D reconstruction: A split and merge approach and its evaluation

We present a general framework to improve a vectorial building footprint database consisting of a set of 2D polygons. The aim of this improvement is to make the database more proper to subsequent 3D building reconstruction at a large scale. Each polygon is split into several simple polygons guided by a digital elevation model (DEM). We say that this segmentation is vectorial as we produce segmentations that intrinsically have simple polygonal shapes, instead of doing a raster segmentation of the DEM within the polygon then trying to simplify it in a vectorization step. The method is based on a Mumford and Shah like energy functional characterizing the quality of the segmentation. We simplify the problem by imposing that the segmentation edges have directions present in the input polygon over which the DEM is defined. We evaluate the validity of the proposed method on a very large dataset and discuss its pros and cons based on this evaluation.     

Nitrogen functionality in “oil window” rank range vitrinite rich coals and chars

X-ray photoelectron spectroscopy (XPS) was used to characterize organic nitrogen species in coals and chars. The coals comprise a set of vitrinite-rich samples from the Penn State Coal Bank set, ranging from vitrinite reflectance (R_r) 0.42-1.60%. Chars were obtained after coal pyrolysis under an inert atmosphere at 800 °C and fast heating rate. In the coals, pyrrolic nitrogen was the predominant form, steadily decreasing with coal rank, while pyridinic and quaternary nitrogen showed pronounced variation with rank. In contrast to the coals, the chars show much less pyrrolic and pyridinic nitrogen, and more quaternary nitrogen. The chars were also characterized by having oxidized nitrogen and nitro sub-peaks, which were not observed for the coals. Apparently the occurrence of these forms is related to the decrease in the pyridinic nitrogen.     

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.     

Update of Canadian Historical Snow Survey Data and Analysis of Snow Water Equivalent Trends, 1967–2016

ABSTRACT

In situ observations of snow water equivalent (SWE) from manual snow surveys and automated sensors are made at approximately 1000 sites across Canada in support of water resource planning for flood control and hydroelectricity production. These data represent an important source of information for research (e.g., validation of hydrological and climate models), for applied studies (e.g., ground snow loads), and for climate monitoring. This note describes the process to update a Canadian historical snow survey dataset to 2016 and the production of a 0.1° gridded version for research applications. Analysis of trends in SWE, snow depth (SD), and density over the 50-year period from 1967 to 2016 revealed large spatial variability in trend sign and strength, with a relatively small percentage of points showing statistically significant trends. Where SWE and SD trends were significant, they tended to be negative, which is consistent with previous investigations of snow cover changes in Canada. The results show evidence of a latitudinal dependence in SWE trends, with the largest negative trends occurring over lower latitudes, and a tendency for mainly positive trends in Arctic SWE, which is consistent with observations from Russia and climate model projections of the response of Arctic snow cover to climate warming. Arctic sites also showed evidence of an increasing trend in 1 April snowpack density of 6.6?kg m^?3 per decade but little corresponding change in SD. This has potentially important consequences for the soil thermal regime because it provides a cooling influence from an increase in the snowpack effective thermal conductivity. The snow survey dataset is available from the Government of Canada Open Data portal.     

Classes of Families of Generalized Periodic Solutions to the Beletsky Equation

For the equation describing plane oscillations and rotations of a satellite, we consider families of symmetric generalized periodic solutions with integral rotation number p. We give new confirmations of the hypothesis: there are only four classes of these families with topologically different structures, namely, the classes of families of periodic solutions with p≥ 1, p= 0, p=−1, and p≤−2. Besides, we demonstrate that the vertices of cusps of these families are placed on some analytical curves, and the same is true for the multiple intersections of these families with other families.