New insights into rare earth element (REE) particulate generated by cigarette lighters: an electron microscopy and materials science investigation of a poorly understood indoor air pollutant and constraints for urban geochemistry

Cigarette smoking is a well-recognized cause of lung cancer and other diseases and is a major contributor to indoor air pollution in numerous settings worldwide. Most cigarette lighters use rare earth element (REE) mischmetal in their flints in order to aid ignition, and these lighters thus have pyrophoric properties. REE particulate emitted from these lighters presents a complexity in the role of health of smokers that has yet to be explored fully. Furthermore, these particles are likely present in numerous urban settings and contribute to the complexities of urban geochemistry. Details of the material properties of rare earth element (REE) particulate derived from smoking lighters are determined first the first time. Particulate was investigated using back-scatter detection scanning electron microscopy techniques and transmission electron microscopy techniques. Several particle types were observed and demonstrate a diverse range of size and textures, many of which are previously not documented and are much smaller than previous basic scanning electron microscopy investigations. These include irregularly shaped fragments of mischmetal, micrometer-scale spherules, aggregates of nanospherules, and platy sponge-like nanoparticles. All of these particles have significant REE content, and most are of a particle size that can be deposited deep in the lung. The available literature regarding toxicity of REEs and the material science data presented here argues very strongly for cause for concern.     

Predicting Sea Surface Salinity Using an Improved Genetic Algorithm Combining Operation Tree Method

The purpose of this study is to demonstrate the use of an improved genetic algorithm combining operation tree method (IGAOT) and apply it to monitor the salinity of the Taiwan Strait by using remote-sensing data. The genetic algorithm combining operation tree (GAOT) is a data mining method used to automatically discover relationships among nonlinear systems. Based on genetic algorithms (GAs), the relationships between input and output can be expressed as parse trees. The GAOT method typically has the disadvantages of premature convergence, which means it cannot produce satisfying solutions and performs satisfactorily when applied to only low-dimensional problems. Therefore, the GAOT method is enhanced using an automatic incremental procedure to improve the search ability of the method and avoid trapping in a local optimum. In this case study, an IGAOT is used to determine the relationship between the in situ data on the salinity of the Taiwan Strait and the data on the spectral parameters, seven wavebands, of a Moderate-Resolution Imaging Spectroradiometer (MODIS) sensor. The results indicate that the IGAOT model performs more favorably than do the GAOT and linear regression (LR₁ and LR₂) models, exhibits higher correlation coefficients, and involves fewer estimating errors. The results of this study indicate that the proposed technique is useful for estimating the Taiwan Strait salinity.     

Deformation features of garnet-bearing granites from Huwan,western Dabie Mountains

Foliated garnet-bearing granite, usually associated with high pressure and ultrahigh -pressure (UHP) metamophic rocks, is a particular rock-type extensively exposed in the Mesozoic Dabie-Sulu orogenic belt of China. This study focuses on deformation features and SHRIMP zircon dating of foliated garnet granite in a high-pressure metamorphic unit from Huwan, western Dabie Mountains in order to resolve discrepancies in current versions of its petrogenesis and structural evolution. SHRIMP dating reveals a zircon age of 762 ± 15 Ma (MSWD=1.7) for Huwan granites, representing the Middle to Late Neoproterozoic age of intrusion and crystallization. Field and microstructural studies show that the Huwan granite body underwent multiple-stage deformation. The deformation was manifested by an early stage of rootless folding and imposition of relict foliation (S₁); an Indosinian main stage marked by imposition of north-dipping penetrative gneissosity (S₂) and development of ductile shear zones under NNE-SSW directed compression; and a final Indosinian stage of southward thrusting of the Huwan high-pressure unit. Shallow level extension prevailed after the Late Triassic, giving rise to south-dipping thrust faults and north-dipping normal faults. Supported by the National Natural Science Foundation of China (Grant Nos. 40802046 and 40334037) and the Project of Science & Technology Research and Development from Sinopec (Grant No. P02009)     

Comparative study of different wavelets for developing parsimonious Volterra model for rainfall-runoff simulation

Although the Volterra models are non-parsimonious ones, they are being used because they can mimic dynamics of complex systems. However, applying and identification of the Volterra models using data may result in overfitting problem and uncertainty. In this investigation we evaluate capability of different wavelet forms for decomposing and compressing the Volterra kernels in order to overcome this problem by reducing the number of the model coefficients to be estimated and generating smooth kernels. A simulation study on a rainfall?runoff process over the Cache River watershed showed that the method performance is successful due to multi-resolution capacity of the wavelet analysis and high capability of the Volterra model. The results also revealed that db2 and sym2 wavelets have the same high potential in improving the linear Volterra model performance. However, QS wavelet was more successful in yielding smooth kernels. Moreover, the probability of overfitting while identifying the nonlinear Volterra model may be less than the linear model.     

Automatic mapping of lunar landforms using DEM-derived geomorphometric parameters

Developing approaches to automate the analysis of the massive amounts of data sent back from the Moon will generate significant benefits for the field of lunar geomorphology. In this paper, we outline an automated method for mapping lunar landforms that is based on digital terrain analysis. An iterative self-organizing (ISO) cluster unsupervised classification enables the automatic mapping of landforms via a series of input raster bands that utilize six geomorphometric parameters. These parameters divide landforms into a number of spatially extended, topographically homogeneous segments that exhibit similar terrain attributes and neighborhood properties. To illustrate the applicability of our approach, we apply it to three representative test sites on the Moon, automatically presenting our results as a thematic landform map. We also quantitatively evaluated this approach using a series of confusion matrices, achieving overall accuracies as high as 83.34% and Kappa coefficients (K) as high as 0.77. An immediate version of our algorithm can also be applied for automatically mapping large-scale lunar landforms and for the quantitative comparison of lunar surface morphologies.     

利用大地电磁资料对玄武岩成像的可行性

The magnetotelluric （MT） method has been among the favorite supporting tools for seismic imaging of sub-salt and sub-basalt targets. In this paper we present an example from Kachchh, India （where basaltic rocks overlie Mesozoic sedimentary rocks）, and discuss the feasibility of using MT method as an exploration tool in this geological setting. Our results highlight the difference in magnetotelluric response caused by the thin intrabasalt layering. The key issue addressed in this paper is what MT can and cannot provide in such geological settings. First, we compute apparent resistivity and phase response curves using representative resistivity-depth models and borehole data from the study area. Later, we compare these results to assess the plausibility of using MT to image the sub-volcanic sediments at Kachchh. Finally, we substantiate our discussion through one-dimensional inversion of the field observed MT data from this region that exhibits poor sensitivity of MT for thin basalt layers.     

信息与通信技术对空间组织的影响及其空间效率的测算

为了更好地展示工业时代的空间组织模式,给出了一个包括时空背景、组织主体、组织客体、要素组成、要素状态、空间效率和技术7个部分的概念性框架;以该框架为基础,逐步分析了信息与通信技术对空间组织其他6个部分的具体作用;最后提出了一个判定空间组织效率的新视角。研究发现,信息与通信技术导致了传统空间组织模式的根本性重构,其对空间组织的影响是全方位的;在过去的30多年间,信息与通信技术对劳动生产率增长的贡献显著,这也证明了其作用下空间组织的高效率。     

Identification of buried sinkholes using refraction tomography at Ft. Campbell Army Airfield,Kentucky

Karst aquifers are highly susceptible to contamination, with numerous points of entry for contaminants through recharge features such as sinkholes, swallow holes and solutionally enlarged fractures. These recharge features may be filled or obscured at the surface, requiring the use of geophysical or remote sensing techniques for their identification. This study uses seismic refraction data collected at the Ft. Campbell Army Airfield (CAAF), Kentucky, USA, to test the hypothesis that refraction tomography is a useful tool for imaging bedrock depressions beneath thick overburden (greater than 20 m of unconsolidated sediment). Southeast of the main taxiway of CAAF seismic velocity tomograms imaged a bedrock low, possibly a closed depression, at a depth of 25 m that had been earlier identified through delay-time analysis of the same refraction data. Tomography suggests the bedrock low is about 250-m wide by 10-m deep at its widest point. High rates of contaminant vapor extraction over the western extension of this feature suggest a high concentration of contaminants above, and within, this filled bedrock low, the base of which may contain solutionally enlarged fractures (i.e. karst conduits) that could funnel these contaminants to the upper or lower bedrock aquifers. This study thus demonstrates the viability of seismic refraction tomography as a tool for identification of filled sinkholes and bedrock depressions in karst areas.     

Comparison of spectral and spatial methods for a Moho recovery from gravity and vertical gravity-gradient data

In global studies investigating the Earth’s lithospheric structure, the spectral expressions for the gravimetric forward and inverse modeling of the global gravitational and crustal structure models are preferably used, because of their numerical efficiency. In regional studies, the applied numerical schemes typically utilize the expressions in spatial form. Since the gravity-gradient observations have a more localized support than the gravity measurements, the gravity-gradient data (such as products from the Gravity field and steady-state Ocean Circulation Explorer - GOCE - gravity-gradiometry satellite mission) could preferably be used in regional studies, because of reducing significantly the spatial data-coverage required for a regional inversion or interpretation. In this study, we investigate this aspect in context of a regional Moho recovery. In particular, we compare the numerical performance of solving the Vening Meinesz-Moritz’s (VMM) inverse problem of isostasy in spectral and spatial domains from the gravity and (vertical) gravity-gradient data. We demonstrate that the VMM spectral solutions from the gravity and gravity-gradient data are (almost) the same, while the VMM spatial solutions differ from the corresponding spectral solutions, especially when using the gravity-gradient data. The validation of the VMM solutions, however, reveals that the VMM spatial solution from the gravity-gradient data has a slightly better agreement with seismic models. A more detailed numerical analysis shows that the VMM spatial solution formulated for the gravity gradient is very sensitive to horizontal spatial variations of the vertical gravity gradient, especially in vicinity of the computation point. Consequently, this solution provides better results in regions with a relatively well-known crustal structure, while suppressing errors caused by crustal model uncertainties from distant zones. Based on these findings we argue that the gravity-gradient data are more suitable than the gravity data for a regional Moho recovery.     

Reconstruction of paleocoastlines for the northwestern South China Sea since the Last Glacial Maximum

The range of relative sea level rise in the northwestern South China Sea since the Last Glacial Maximum was over 100 m. As a result, lowland regions including the Northeast Vietnam coast, Beibu Gulf, and South China coast experienced an evolution from land to sea. Based on the principle of reconstructing paleogeography and using recent digital elevation model, relative sea level curves, and sediment accumulation data, this paper presents a series of paleogeographic scenarios back to 20 cal. ka BP for the northwestern South China Sea. The scenarios demonstrate the entire process of coastline changes for the area of interest. During the late glacial period from 20 to 15 cal. ka BP, coastline slowly retreated, causing a land loss of only 1×10⁴ km², and thus the land-sea distribution remained nearly unchanged. Later in 15–10 cal. ka BP coastline rapidly retreated and area of land loss was up to 24×10⁴km², causing lowlands around Northeast Vietnam and South China soon to be underwater. Coastline retreat continued quite rapidly during the early Holocene. From 10 to 6 cal. ka BP land area had decreased by 9×10⁴km², and during that process the Qiongzhou Strait completely opened up. Since the mid Holocene, main controls on coastline change are from vertical crustal movements and sedimentation. Transgression was surpassed by regression, resulting in a land accretion of about 10×10⁴km². Supported by Key Laboratory of Marginal Sea Geology, Chinese Academy of Sciences (Grant No. MSGL0711), the Guangdong Natural Science Foundation (Grant No. 04001309) and Open Fund of the Key Laboratory of Marine Geology and Environment, Chinese Academy of Sciences (Grant No. MGE2007KG04)