Correlations between OH,NaD and OI 5577 Å emissions in the airglow

Simultaneous measurements of the night airglow OI 5577 Å and OH (8,3) band have been carried out at Cachoeira Paulista (23°S, 45°W), Brazil since 1976. Cross correlation analyses between the nocturnal variations of these emissions and also with the OH rotational temperature (ROT) for various time shifts are presented. It is found that OH (8,3) is well correlated with ROT but with a time lag of about 1 h. The variations of OI 5577 Å lead OH (8,3) by about 2–3 h and ROT covaries with 5577 Å with a time lag less than 1 h. For the sake of comparison, OI 5577 Å, OH and NaD data from a number of IQSY stations have been analysed. It is noted that (1) OI 5577 Å leads OH by about 2 h at mid-latitude stations and (2) OH is well correlated with Na 5893 Å with a time lag of less than 1 h. The presence of the phase lagged correlation patterns between OH/5577 Å, OH/ROT and OH/NaD indicates vertical propagation of a wavelike perturbation of the upper atmosphere.     

The effect of salinity on Fucus ceranoides (Ochrophyta,Phaeophyceae) in the Mondego River (Portugal)

Algae(and their extracts) are increasingly important for pharmaceutical applications due to the diversity of useful compounds they contain. The genus Fucus contains one of the most studied species,Fucus vesiculosus. The species F. ceranoides differs from the others of the genus by presenting longitudinal air-vesicles and a capacity to survive at low salinities. It is an alga that inhabits the Mondego River estuary(Portugal), at the southern limit of its distribution, and can serve as a role model to understand the effect of a salt gradient on the production of bioactive compounds. We assessed the phenolic content and antioxidant activity of different F. ceranoides extracts(e.g. methanolic, aqueous and polysaccharide) prepared from samples harvested from two different zones to evaluate if the adaptation of F. ceranoides to different salinity levels influenced its chemical composition. The antioxidant activity of the extracts was determined using 1,2-diphenyl-picrylhydrazyl(DPPH) and 2.2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS)radicals. These assays demonstrated that the methanolic extract of lyophilized F. ceranoides that grew at low salinities was the most bioactive, i.e. DPPH(IC_(50)=50.39 μg/mL) and ABTS(TEAC=2.42). The total phenolic content(Folin-Ciocalteu method) and the methanolic extract of the lyophilized F. ceranoides collected from a low salinity habitat exhibited the highest phenolic content(PGE=49.48 μg/mg of lyophilized extract)amongst those sampled. Thin layer chromatography(TLC) and Fourier transform infrared spectroscopy(FTIR) were used for the identification of compounds in the extracts. This characterization allowed confirmation that the various extracts contained almost the same compounds but with notable quantitative differences. Based on these results, we conclude that there were differences in the quantity of the compounds due to the effect of salinity. The drying methods used were also found to have influenced the quality of the extracted compounds.     

Studying the errors in the estimation of the variation of energy by the “patched-conics” model in the three-dimensional swing-by

The swing-by maneuver is a technique used to change the energy of a spacecraft by using a close approach in a celestial body. This procedure was used many times in real missions. Usually, the first approach to design this type of mission is based on the “patched-conics” model, which splits the maneuver into three “two-body dynamics.” This approach causes an error in the estimation of the energy variations, which depends on the geometry of the maneuver and the system of primaries considered. Therefore, the goal of the present paper is to study the errors caused by this approximation. The comparison of the results are made with the trajectories obtained using the more realistic restricted three-body problem, assumed here to be the “real values” for the maneuver. The results shown here describe the effects of each parameter involved in the swing-by. Some examples using bodies in the solar system are used in this part of the paper. The study is then generalized to cover different mass parameters, and its influence is analyzed to give an idea of the amount of the error expected for a given system of primaries. The results presented here may help in estimating errors in the preliminary mission analysis using the “patched-conics” approach.     

Biological Reduction of Nitrate and Perchlorate in Soil Microcosms: An Electron Donor Comparison of Glycerol,Emulsified Oil,and Mulch Extract

Diverse technologies have been developed and tested for their efficacy in remediating perchlorate-contaminated surface water, groundwater, and soil. Biological reduction, particularly when coupled with electron donor augmentation, has been shown to be one of the most cost-effective alternatives. Numerous electron donors have been evaluated in the literature, but few studies have compared standard vs. slow-release electron donors for sequential nitrate and perchlorate reduction. This study evaluated the efficacy and kinetics of biological reduction in soil microcosms augmented with emulsified oil (EO), glycerol, and mulch extract. Results indicated that EO and glycerol spiked at approximately 100 times stoichiometric excess (i.e., 100x) achieved similar overall reductions and degradation rates for nitrate and perchlorate, although nitrate appeared to exhibit zero order kinetics while perchlorate exhibited first order kinetics. The zero order rate constants for nitrate reduction were 3.32 mg/L d and 2.57 mg/L d for EO and glycerol, respectively. The first order rate constant for perchlorate reduction was 0.36 day⁻¹ for both EO and glycerol. Stable chemical oxygen demand (COD) concentrations also highlighted the slow-release properties of EO, which would reduce electron donor consumption in comparison to soluble substrates in soil remediation applications. The microcosms augmented with mulch extract failed to demonstrate any nitrate or perchlorate reduction due to the extract's lower COD concentration. Augmentation with compost or additional processing (i.e., concentration) would be necessary to make the extract a viable alternative.     

Equatorial ionization anomaly and thermospheric meridional winds during two major storms over Brazilian low latitudes

The equatorial ionosphere responses over Brazil to two intense magnetic storms that occurred during 2001 are investigated. The equatorial ionization anomaly (EIA) and variations in the zonal electric field and meridional winds at different storms phases are studied using data collected by digisondes and GPS receivers. The difference between the F layer peak density (foF2) at an equatorial and a low latitude sites was used to quantify the EIA; while the difference between the true heights (h_F) at the equatorial and an off-equatorial site was used to calculate the magnetic meridional winds. The vertical drift was calculated as dh_F/dt. The results show prompt penetration electric fields causing unusual early morning development of the EIA, and disturbed dynamo electric field producing significant modification in the F region parameters. Variations to different degrees in the vertical drift, the thermospheric meridional winds and the EIA developments were observed depending on the storm phases.     

A 14-year monthly climatology and trend in the 35–65 km altitude range from Rayleigh Lidar temperature measurements at a low latitude station

A sodium resonance lidar at 589 nm has been operated in São José dos Campos, Brazil (23°S, 46°W) since 1972 mainly for studies related to the origin, chemistry and dynamics of the mesospheric sodium layer. Beginning in 1993, the improved laser capability has also enabled the processing of the Rayleigh signal from which the temperatures from 35 to 65 km are retrieved on a nightly mean basis. We used these nightly profiles to determine the monthly temperature profiles from 1993 to 2006. The mean temperature characteristics for each year and for the whole period are obtained. Seasonal thermal amplitude is small (6 K peak to peak at 40 and 60 km). Compared with the MSISE-90 model, a large difference is noted, with temperature lower than the model below the stratopause and higher above. Also the seasonal variation has a large difference with better agreement occurring around local winter, but with temperatures higher by 8–10 K at the equinoxes. The semiannual component is dominant over the annual at all altitudes. Linear trends with decreasing temperature of 1.09, 2.29 and 1.42 K/decade are observed at 40, 50 and 60 km, respectively.     

Seasonal and event-controlled export of organic matter from the shelf towards the Gulf of Lions continental slope

To investigate the role of coastal canyons in the transfer of organic matter from the shelf to the slope and basin, we deployed sediment trap/current meter pairs at the head of five canyons in the Gulf of Lions (GoL) between November 2003 and May 2004. Analysis of organic carbon, biogenic silica, Corg isotopic composition, Corg/total nitrogen, chloropigments, and amino acids clearly shows the seasonal influence and effect of extreme meteorological events on the composition of collected particles. The sampling period was divided into three “scenarios”. The first corresponded to a large easterly storm and flood of the Rhone river during stratified water column conditions; the composition of material collected during this event was influenced by increased transfer of riverine and coastal particulate matter, with a lower Corg content. During the second “fall-winter” scenario, northern and northwestern winds blowing over the shelf caused cooling and homogenization of the shelf water column; particles collected at this time reflected the homogeneous source of particulate matter transported through canyons; particles sitting in the vicinity of canyon heads are most likely swept downslope by the general south-westward circulation. Organic tracers indicate a degraded origin for organic matter transported during this period. A third “spring” scenario corresponded to northern winds alternating with eastward windstorms that triggered and/or enhanced the cascading of dense waters accumulated on the bottom of the shelf due to previous cooling. These conditions occurred in conjunction with increased phytoplankton productivity in shelf surface waters. Organic matter advected mainly by dense shelf water cascading was fresher due to the transport of newly produced particles and a variable terrestrial fraction; this fraction depended on the proportion of resuspended material accumulated during previous high discharge periods that was involved in each transport pulse. The tight link shown between meteorological conditions and organic matter transport is important for continental margin geochemical studies as future changes in climatic conditions may lead to dramatic changes in carbon sequestration capability and in the ecosystems of deep margin environments.     

Lidar observations of atmospheric sodium at an equatorial location

Lidar measurements of upper atmospheric sodium were made at Alcântara (2°20′ S, 44°30′ W), Brazil, on 8 days during the month of November 1996. These are the first sodium measurements to be reported from an almost equatorial location. The average sodium distribution at Alcântara was found to be very similar to the annual mean for São José dos Campos (23° S), but about 1 km higher than the November mean value of 92 km for the latter site. Only one, weak, sporadic sodium layer was observed during more than 26 h of observations, an occurrence frequency much less than that seen at low latitude sites in the northern hemisphere. A survey of the observations of sporadic layers at various locations suggests that both magnetic dip and declination angles might influence their rate of occurrence.     

Expansion of an invasive coral species over Abrolhos Bank,Southwestern Atlantic

Invasive coral species of the genus Tubastraea have been increasingly recorded in Southwestern Atlantic waters since the 1980s. Their invasion and infestation are mainly related to port and oil exploration activities. For the first time the presence of Tubastraea tagusensis colonies is reported in Espírito Santo State, colonizing a port shore area, and incrusting oil/gas platform structures situated in the southern Abrolhos Bank, which is part of the most important coral reef system of the South Atlantic Ocean. Tubastraea colonies exhibit fast growth and high recruitment rates, and colonized 40% of the analyzed structures in just four years. The projection of port and oil/gas industry growth for the Espírito Santo State (more than 300%) highlights an alert to the dispersal of this alien species to natural areas.     

Supercontinent evolution and the Proterozoic metallogeny of South America

The cratonic blocks of South America have been accreted from 2.2 to 1.9 Ga, and all of these blocks have been previously involved in the assembly and breakup of the Paleoproterozoic Atlantica, the Mesoproterozoic to Neoproterozoic Rodinia, and the Neoproterozoic to Phanerozoic West Gondwana continents. Several mineralization phases have sequentially taken place during Atlantica evolution, involving Au, U, Cr, W, and Sn. During Rodinia assembly and breakup and Gondwana formation, the crust-dominated metallogenic processes have been overriding, responsible for several mineral deposits, including Au, Pd, Sn, Ni, Cu, Zn, Mn, Fe, Pb, U, P₂O₅, Ta, W, Li, Be and precious stones. During Rodinia breakup, epicontinental carbonate-siliciclastic basins were deposited, which host important non-ferrous base metal deposits of Cu–Co and Pb–Zn–Ag in Africa and South America. Isotope Pb–Pb analyses of sulfides from the non-ferrous deposits unambiguously indicate an upper crustal source for the metals. A genetic model for these deposits involves extensional faults driving the circulation of hydrothermal mineralizing fluids from the Archean/Paleoproterozoic basement to the Neoproterozoic sedimentary cover. These relations demonstrate the individuality of metal associations of every sediment-hosted Neoproterozoic base-metal deposit of West Gondwana has been highly influenced by the mineralogical and chemical composition of the underlying igneous and metaigneous rocks.