Mineral magnetic signatures in a long core from Lake Qarun, Middle Egypt

The analysis and interpretation of changes in mineral magnetic signatures from a long (ca. 8.2 m) sedimentary sequence recovered from Lake Qarun, Middle Egypt in 2003 spanning a timescale of approximately the last 2,000 years is reported. A suite of mass specific susceptibility and magnetic remanence measurements were made at irregular intervals downcore on 39 samples. These samples were selected on the basis of trends and abrupt changes in whole-core magnetic susceptibility measured using a Bartington^® MS2E sensor and were analysed for low and high temperature loss on ignition and their particle size distribution. Trends in all mineral magnetic concentration parameters are remarkably similar and were initially used to divide the core into three magnetically distinct zones. The upper and lower sections of the core (0–119 cm and 445–822 cm depth) are characterised by low values for all magnetic concentration parameters. Between 153 and 380 cm depth, concentration parameters are considerably higher, although somewhat variable. The S ratio and percentage loss of remanence after 24 h (IRM_loss) follow a different trend and are inversely related to each other. A low S ratio (<0.7) is associated with a loss of remanence of >4%. On the basis of these parameters, the core can be divided into four zones, and differences in magnetic mineralogy between these four zones were confirmed by measurement of IRM acquisition curves. The major difference between concentration parameters and ratios or percentage loss of IRM lies in the identification of an additional zone below 619 cm depth where the S ratio is high and IRM_loss is low. There is little evidence to suggest that the magnetic signatures are controlled by particle size or by trends in organic matter and/or carbonate content. The signatures appear to be predominantly detrital and show little evidence of post-depositional alteration through dissolution or authigenic addition of bacterial magnetite or greigite. Analysis of Saharan dust deposition rates in Northern Egypt suggests that atmospheric fallout is likely to make only a very minor contribution (<1%) to sedimentation rates in Lake Qarun. The downcore trends therefore appear to reflect major changes in fluvial sediment sources over the ca. 2,000 year time period spanned by this ～8 m core. Preliminary mineral magnetic characterisations of potential local sources suggest that these cannot account for the range of signatures recorded in the Qarun sediments and it is hypothesised that these sediments are derived from Nile river floods.     

Cenozoic geodynamic evolution of the Andaman–Sumatra subduction margin: Current understanding

The Andaman–Sumatra margin displays a unique set‐up of extensional subduction–accretion complexes, which are the Java Trench, a tectonic (outer arc) prism, a sliver plate, a forearc, oceanic rises, inner‐arc volcanoes, and an extensional back‐arc with active spreading. Existing knowledge is reviewed in this paper, and some new data on the surface and subsurface signatures for operative geotectonics of this margin is analyzed. Subduction‐related deformation along the trench has been operating either continuously or intermittently since the Cretaceous. The oblique subduction has initiated strike–slip motion in the northern Sumatra–Andaman sector, and has formed a sliver plate between the subduction zone and a complex, right‐lateral fault system. The sliver fault, initiated in the Eocene, extended through the outer‐arc ridge offshore from Sumatra, and continued through the Andaman Sea connecting the Sagaing Fault in the north. Dominance of regional plate dynamics over simple subduction‐related accretionary processes led to the development and evolution of sedimentary basins of widely varied tectonic character along this margin. A number of north–south‐trending dismembered ophiolite slices of Cretaceous age, occurring at different structural levels with Eocene trench‐slope sediments, were uplifted and emplaced by a series of east‐dipping thrusts to shape the outer‐arc prism. North–south and east–west strike–slip faults controlled the subsidence, resulting in the development of a forearc basins and record Oligocene to Miocene–Pliocene sedimentation within mixed siliciclastic–carbonate systems. The opening of the Andaman Sea back‐arc occurred in two phases: an early (～11 Ma) stretching and rifting, followed by spreading since 4–5 Ma. The history of inner‐arc volcanic activity in the Andaman region extends to the early Miocene, and since the Miocene arc volcanism has been associated with an evolution from felsic to basaltic composition.     

Analytical and experimental investigations on seismic performance of exterior beam–column subassemblages of existing RC‐framed building

Seismic performance of exterior beam–column subassemblages of reinforced concrete structure designed and detailed on the basis of the provisions of Eurocode and Indian Standards at different stages of their evolution is evaluated. Performance of the subassemblages designed and detailed according to the three different stages of codal evolution (gravity load design, ‘Nonductile’, and ‘Ductile’) is evaluated through analytical formulations and experimental investigations. In the ‘NonDuctile’ specimens, it has been observed that the shear distortion and degradation in stiffness and strength are significantly high. Performance of the ‘Ductile’ specimens based on Eurocode and Indian Standards is almost similar in terms of strength and stiffness degradation. Nevertheless, the specimen designed on the basis of Indian Standard shows higher energy dissipation at a given drift ratio. In the analytical study, shear and flexural failure of members of subassemblage and shear failure of the joint are considered as possible modes of failure of the beam–column subassemblage. For evaluating the shear strength of the joint region, a soften strut‐and‐tie model is used. Analytically obtained strengths based on the failure criteria of different components of the specimens have been first validated with experimental results and then used to determine the strength of the specimens. The investigation could indicate even the mode of failure at local level. It is utmost important to mention here that even the ductile specimens dissipate most of the energy through the development of damage in the joint region, which is neither desirable nor safe for the stability of whole structure. Copyright © 2013 John Wiley & Sons, Ltd.     

Whole-rock and sulfide lead-isotope data from the hydrothermal JADE field in the Okinawa back-arc trough

The mineralization of the active hydrothermal JADE field resembles in many aspects the Kuroko-type mineralization. The JADE field is located in a back-arc graben and is associated with a bimodal volcanism. Lead isotope data from igneous rocks, sediments, and ores further emphasize the similarities with the Kuroko ores and suggest that both sediments and volcanic rocks contributed comparable amounts of lead to the deposit. When compared to the sediments, a much larger volume of volcanic rocks must have contributed lead to the deposit, because of the considerably lower lead concentration of volcanic rocks. In contrast to the crustal type lead of the JADE field and the Kuroko-type sulfide deposits the lead isotope signatures of VMS-type deposits at mid-ocean ridges is distinctly different. In the absence of a sedimentary cover it reflects the composition of the mantle source, whereas in the presence of a sedimentary cover it is either a mixture of mantle and sedimentary lead or it may even be completely dominated by the latter. Received: 5 October 1995 / Accepted: 10 May 1996     

The dip equator over Peninsular India and its secular movement

A ground geomagnetic survey conducted in peninsular India has demarkated the dip equator for the epoch 1991.0. A well-defined southward migration in the last two decades is evident. The secular trend in the vertical component and the direction of the migration in the India zone are shown to be consistent. The migratory movement of the dip equator in different longitude sectors is compared to highlight the complex nature of the secular trends.     

Effectiveness of structural control based on control energy perspectives

A computational algorithm for maximizing the control efficiency in actively controlling the elastic structural responses during earthquake is proposed. Study of optimal linear control using a single degree of freedom shows that applying active control is very effective in reducing the structural displacement and velocity responses for long‐period structures, but at the same time it has an adverse effect in increasing the absolute acceleration response. The extent of this adverse effect reduces the effectiveness of the control system, and therefore it poses a limit on the maximum control force in order to provide maximum control efficiency. In view of this shortcoming, maximum control energy dissipation is used to define the most effective optimal linear control law. Less displacement and velocity response are expected as larger control force is applied, but there is always a limit that maximum control energy can be dissipated. This study shows that this limit depends on the structural characteristics as well as the input ground motion, and a general trend is that the maximum control energy decreases as damping increases. Finally, application of the proposed algorithm on a six‐storey hospital building is presented to show the effectiveness of using optimal linear control on a multi‐degree‐of‐freedom system from the control energy perspectives. Copyright © 2001 John Wiley & Sons, Ltd.     

Numerical simulation of a South China Sea typhoon Leo (1999)

Summary ?A South China Sea typhoon, Leo (1999), was simulated using the Penn State/NCAR mesoscale model MM5 with the Betts-Miller convective parameterization scheme (BMEX). The simulation had two nested domains with resolutions at 54 and 18 km, and the forecast duration was 36 hours. The model was quite successful in predicting the track, the rapid deepening, the central pressure, and the maximum wind speed of typhoon Leo as verified with reports from the Hong Kong Observatory (HKO). The structure of the eye, the eye wall, and the spiral convective cloud band simulated in the model are found to be comparable to corresponding features identified in satellite images for the storm, and also with those reported by other authors. A trajectory analysis was performed. Three kinds of trajectory were found: (1) spirally rising trajectories near the eye wall; (2) spirally rising/descending trajectories in the convective/cloud free belt; (3) straight and fast rising trajectories in a heavy convection zone along one of the cloud bands on the periphery of the tropical cyclone. Both the HKO and the U.S. Joint Typhoon Warning Center (JTWC) reported the rapid deepening of Leo started around 00 UTC 29 April. In the model, the eye was first formed in the lower troposphere, and it extended to the upper troposphere within a few hours. We speculate that the spin-up of cyclonic rotation in the low-level eye enhanced the positive vorticity along the low-level eye wall. The positive vorticity was then transported to the upper troposphere by convection, leading to an extension and growth of the eye into the upper troposphere. To examine the impact of convective parameterization scheme (CPS) on the simulation, the Grell scheme (GLEX) was also tested. The GLEX predicted a weaker typhoon with a wilder eye that extended not as high up in the upper troposphere as BMEX. The different structures of the eye between the BMEX and GLEX suggest that the mesoscale features of the eye are dependent on the convection. In other words, the vertical and horizontal distribution of convective heating is essential to the development and structure of the eye. Received December 18, 2001; accepted May 7, 2002 Published online: March 20, 2003     

Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.     

Soldier crab (Dotilla myctiroides) distribution,food resources and subsequent role in organic matter fate in Ao Tang Khen,Phuket, Thailand

This study aimed to elucidate Dotilla myctiroides (H. Milne-Edwards) food resources and how the soldier crab influences the organic matter composition on the intertidal flat. A preliminary assessment of D. myctiroides size, sex, and population distribution was conducted to clarify the characteristics of the inhabiting population. Overall, D. myctiroides size and abundance was normal across the tidal flat area. Comparison of different sediment types from the soldier crab habitat (surface sediments, igloos, burrow lining, burrow pellets, feeding pellets, and feces) using the fatty acid (FA) analysis technique revealed D. myctiroides removes organic matter via the significantly lower contributions of polyunsaturated FAs, essential FAs, and dinoflagellates in the feeding pellets. Dotilla myctiroides tissue analysis of the hepatopancreas and hindgut in individuals that had been starved for 24 h confirmed not only the consumption of dinoflagellates, but diatoms and macroalgae as well. In addition, the FA metabolism within the digestive system implied the ability of the soldier crab to synthesize highly unsaturated FAs (HUFAs) such as 20:4n–6, 20:5n–3 and 22:6n–3.