Non-glacial paleoenvironments and the extent of Weichselian ice sheets on Severnaya Zemlya, Russian High Arctic

The extent of the Barents-Kara Sea ice sheet (northern Europe and Russia) during the Last Glacial Maximum (LGM), in Marine Isotope Stage (MIS) 2 is controversial, especially along the southern and northeastern (Russian High Arctic) margins. We conducted a multi-disciplinary study of various organic and mineral fractions, obtaining chronologies with ¹⁴C and luminescence dating methods on a 10.5 m long core from Changeable Lake (4 km from the Vavilov Ice Cap) on Severnaya Zemlya. The numeric ages indicate that the last glaciation at this site occurred during or prior to MIS 5d-4 (Early Middle Weichselian). Deglaciation was followed by a marine transgression which affected the Changeable Lake basin. After the regression the basin dried up. In late Middle Weichselian time (ca 25–40 ka), reworked marine sediments were deposited in a saline water body. During the Late Weichselian (MIS 2), the basin was not affected by glaciation, and lacustrine sediments were formed which reflect cold and arid climate conditions. During the termination of the Pleistocene and into the Holocene, warmer and wetter climate conditions than before led to a higher sediment input. Thus, our chronology demonstrates that the northeastern margin of the LGM Barents-Kara Sea ice sheet did not reach the Changeable Lake basin. This result supports a modest model of the LGM ice sheet in northern Europe determined from numeric ice sheet modelling and geological investigations.     

Energetics of radiation damage in natural zircon (ZrSiO4)

Transposed temperature drop calorimetry at 1000 °C was performed on natural zircons (ZrSiO₄) from Sri Lanka that were partially to completely metamict due to α-decay event damage (0.06 to 11.7×10¹⁵ α-decay events/mg). The enthalpy of annealing at room temperature (ΔH_anneal) varies sigmoidally as a function of radiation dose. ΔH_anneal reaches a saturation plateau at radiation doses greater than 5×10¹⁵ α-decay events/mg. The annealing of several samples to a crystalline structure with broadened diffraction peaks does not significantly affect the enthalpy of annealing. The large magnitude of the enthalpy of annealing plateau, ?59±3 kJ/mol, suggests that the damage to the structure is pervasive on the scale of Angstroms, consistent with the loss of mid-range order characteristic of a glass. The energetics are consistent with, but do not require, chemical heterogeneity caused by micro-domains of amorphous SiO₂-rich and ZrO₂-rich regions in the metamict state.     

Evolution of fluids associated with metasedimentary sequences from Chaves (North Portugal)

In order to identify and characterise fluids associated with metamorphic rocks from the Chaves region (North Portugal), fluid inclusions were studied in quartz veinlets, concordant with the main foliation, in graphitic-rich and nongraphitic-rich lithologies from areas with distinct metamorphic grade. The study indicates multiple fluid circulation events with a variety of compositions, broadly within the C–H–O–N–salt system. Primary fluid inclusions in quartz contain low salinity aqueous–carbonic, H₂O–CH₄–N₂–NaCl fluids that were trapped near the peak of regional metamorphism, which occurred during or immediately after D2. The calculated P–T conditions for the western area of Chaves (CW) is P=300–350 MPa and T500 °C, and for the eastern area (CE), P=200–250 MPa and T=400–450 °C. A first generation of secondary fluid inclusions is restricted to discrete cracks at the grain boundaries of quartz and consists of low salinity aqueous–carbonic, H₂O–CO₂–CH₄–N₂–NaCl fluids. P–T conditions from the fluid inclusions indicate that they were trapped during a thermal event, probably related with the emplacement of the two-mica granites.

A second generation of secondary inclusions occurs in intergranular fractures and is characterised by two types of aqueous inclusions. One type is a low salinity, H₂O–NaCl fluid and the second consists of a high salinity, H₂O–NaCl–CaCl₂ fluid. These fluid inclusions are not related to the metamorphic process and have been trapped after D3 at relatively low P (hydrostatic)–T conditions (P<100 MPa and T<300 °C).

Both the early H₂O–CH₄–N₂–NaCl fluids in quartz from the graphitic-rich lithologies and the later H₂O–CO₂–CH₄–N₂–NaCl carbonic fluid in quartz from graphitic-rich and nongraphitic-rich lithologies seem to have a common origin and evolution. They have low salinity, probably resulting from connate waters that were diluted by the water released from mineral dehydration during metamorphism. Their main component is water, but the early H₂O–CH₄–N₂–NaCl fluids are enriched in CH₄ due to interaction with the C-rich host rocks.

From the early H₂O–CH₄–N₂–NaCl to the later aqueous–carbonic H₂O–CO₂–CH₄–N₂–NaCl fluids, there is an enrichment in CO₂ that is more significant for the fluids associated with nongraphitic-rich lithologies.

The aqueous–carbonic fluids, enriched in H₂O and CH₄, are primarily associated with graphitic-rich lithologies. However, the aqueous–carbonic CO₂-rich fluids were found in both graphitic and nongraphitic-rich units from both the CW and CE studied areas, which are of medium and low metamorphic grade, respectively.     

Jarosite stability on Mars

Jarosite, a potassium (sodium) iron sulphate hydrated mineral, has recently been identified on the martian surface by the Opportunity rover. Using recent thermochemical data [Drouet and Navrotsky, 2003, Geochim. Cosmochim. Acta 67, 2063-2076; Forray et al., 2005, Geochim. Cosmochim. Acta, in press], we calculate the equilibrium decomposition curve of jarosite and show that it is thermodynamically stable under most present martian pressures and temperatures. Its stability makes jarosite potentially useful to retain textural, chemical, and isotopic evidence of past history, including possible biological activity, on Mars.     

Carbon and suspended sediment transport in an impounded alpine river (Isère,France)

Carbon and total suspended sediment (TSS) loads were investigated from April 2006 to March 2008 in the mountainous watershed of the Isère River, French Alps (5570 km²). The river bed has been highly impounded for hydroelectricity production during the last century. Hydraulic flushes are managed every year to prevent TSS storage within upstream dams. The Isère River has been instrumented for high‐frequency monitoring of water, TSS by turbidity and carbon (organic, inorganic, dissolved and particulate) in order to evaluate the impact of natural floods and hydraulic flushes on annual loads. Annual TSS load which was estimated between 1.3 and 2.3 MT y^?1 (i.e. 233 to 413 T km^?2 y^?1) highlighted the high erodibility of the Isère watershed. Annual carbon load was estimated between 173 10³ T y^?1 and 199 10³ T y^?1 (i.e 31 to 36 T km^?2 y^?1). About 80% of the annual carbon loads were inorganic. The impact of hydraulic flushes on annual loads appeared limited (less than 3% for annual TSS load and about 1.5% for annual carbon load), whereas the most important natural flood event contributed to 20% of the annual TSS load and 10% of the annual carbon load. Copyright © 2012 John Wiley & Sons, Ltd.     

Adaptation financing for projects focused on food systems through the UNFCCC

Investments in adaptation are required to reduce vulnerability and strengthen the resilience of food systems to the impacts of climate change. For low-income nations, international financing plays a central role in supporting adaptation. In this article, we document and examine adaptation projects targeting food systems financed through funding bodies of the United Nations Framework Convention on Climate Change (UNFCCC). We find that between 2004 and 2015, 3% (n?=?96) of adaptation projects supported through the UNFCCC explicitly focused on the production, processing, distribution, preparation and/or consumption of food, with US$546 m mobilized through funding bodies directly and US$1.44bn through co-financing. Agriculture is the most common sector supported, with extreme weather events the primary climate change-related impact motivating nations to apply for adaptation financing. The majority of actions are documented to adapt the food production component of food systems, with limited focus within projects on the full range of food system vulnerability and the implications on food security.

Key policy insights

• Enhanced international adaptation financing targeting food systems is needed, and in particular financing to address limited adaptation readiness

• Supported food system projects should include holistic assessments of the entire food system in order to prioritize sector and food system component issue areas for short- and long-term efficiency

• To better analyse food system linkages and aid in the prioritization of adaptation activities, adaptation-directed funds should consider placing a higher emphasis on a cross-sectoral approach within projects

• Linkages between official development assistance and adaptation-directed funds could help optimize financing for food systems and mainstream food system adaptation efforts

     

Intellectual property rights and low carbon technology transfer: Conflicting discourses of diffusion and development

Intellectual property rights (IPRs) and the transfer of low carbon technologies to developing countries have been the focus of sustained disagreement between many developed and developing country Parties to the United Nations Framework Convention on Climate Change (UNFCCC). We argue that this disagreement stems from two conflicting political discourses of economic development and low carbon technology diffusion which tend to underpin developing and developed countries’ respective motivations for becoming party to the Convention. We illustrate the policy implications of these discourses by examining empirical evidence on IPRs and low carbon technology transfer and highlight how the two discourses are based on an incomplete understanding of the role of technological capacity in either economic development or technology diffusion. This has important implication for the success of post-2012 international climate agreements.     

Ni2SiO4-enthalphy of the olivine-spinel transition by solution calorimetry at 713°C

The high pressure spinel polymorph of Ni₂SiO₄ persists metastably at 713°C and atmospheric pressure. The enthalpy of the olivine-spinel transition was obtained by measuring the heats of solution of both polymorphs in a molten oxide solvent, 2PbO · B₂O₃, at that temperature. For Ni₂SiO₄(ol)→Ni₂SiO₄, ΔH₉₈₆⁰ = +1.4 ± 0.7kcal/mol. The heat content increments, H₉₈₆ ? H₂₉₇, were found to be: olivine, 25.73 ± 0.42kcal/mol, and spinel, 25.39 ± 0.20kcal/mol. The measured enthalpy of the transformation is consistent with the low slope of the phase boundary, ?P/?T = ～ 12b/deg, observed by Akimoto and others. The entropy of the olivine-spinel transition in Ni₂SiO₄ is accordingly about a factor of three smaller in magnitude (ΔS = ～ ?1cal/deg mol) than that for Co₂SiO₄,Fe₂SiO₄,Mg₂SiO₄or Mg₂GeO₄ (ΔS = ?3to?3.5cal/deg mol).