Photo-induced degradation of emamectin benzoate: effect of iron amendments and solvent system

Photodegradation is the major dissipation pathway for emamectin benzoate (EB) in water. Therefore, the photolysis of EB was studied in distilled water (DW) and methanol under different irradiation conditions such as natural sunlight, UV tube, and artificially stimulated light (mercury lamp 125 W). The results of the study showed that EB degrades rapidly in DW than in methanol as evidenced by a photodegradation efficiency of about 75 % achieved in DW, after 24 h of irradiation with UV light, while in methanol, it was only 59.3 %. The addition of iron to EB solution in DW further enhanced its photodegradation. The rate of photodegradation of EB was recorded to be increased from 5.5 × 10^?2 to 1.0 × 10^?1 k/h after amendment with iron. The order for the rate of photodegradation of EB was DW + Fe > DW > methanol, with their respective t _1/2 values of 6.5, 12.6, and 18.7 h. Fe amendment was also found to enhance the degradation efficiency of EB even in the absence of any light (dark).     

Mean runoff coefficient estimation for ungauged streams in the Kingdom of Saudi Arabia

Runoff coefficient estimation in ungauged watersheds has a priority for rain water harvesting and management of runoff water, for domestic and agriculture activities, in semi-arid and arid regions. To estimate mean runoff coefficient (C _Re) for ungauged streams, Pearson's coefficient of linear correlation (r) was measured. The method of linear regression (y?=?mx?+?c) was applied for 16 gauged catchments representing several regions in the Kingdom of Saudi Arabia, such as Al Qassim, Al Madinah, Riyadh, Asir, Makkah, and Jazan. The studied catchments were equally divided into two groups based on their main streams slopes; group A includes eight gauged streams having main stream slope less than 0.01, where group B includes eight gauged streams having main stream slope equal to or greater than 0.01. The result yields the constant of the linear regression for each group and the mean runoff coefficient of basin by an independent value (basin slope) for group A and an independent value (stream slope) for group B. The results indicate that the measured runoff coefficient (C _Rm) and the estimated runoff coefficient (C _Re) are almost equal to each other.     

Analysis of QCD ghost F(\tilde{R}) gravity

Flux variability is a common feature of Young Stellar Objects (YSOs), which is often related to intermittent events of disk accretion (EXors events in case of 3–4 magnitudes variations). Recently, thanks to the surveys carried out by the space missions Spitzer and WISE, it has become possible to perform statistical studies on the mid-IR variability on large samples of YSOs. As a follow-up of our recent statistical study on five star forming regions (Antoniucci et al., Astrophys. J. 782:51, 2014), we present the 3–5 μm variability study of the YSOs population of the Vela-D star forming region. We have compared the 3.6 μm and 4.5 μm Spitzer-IRAC fluxes of 181 YSOs in Vela-D with their WISE fluxes at 3.4 μm and 4.6 μm and selected those objects simultaneously varying in both bands. We have identified a robust sample of 34 variables. On the base of the infrared excess of the Spectral Energy Distribution (SED) and the magnitude vs. color variations, we select 5 EXors candidates, which will be systematically monitored to firmly ascertain their nature. The selected 34 variables represent ～18 % of the YSOs detected with Spitzer and WISE, a percentage higher than that of other young star forming regions. Conversely, the percentage of candidate EXors (2.7 %) is quite similar to that measured in Perseus, Ophiuchus and Serpens, and also equals that found in Vela-D on the base of Spitzer variability (Giannini et al., Astrophys. J. 704:606, 2009). Consistently with our finding presented in Antoniucci et al. (2014), this fraction equals the probability of observing the source once in burst and once in quiescence, under the hypothesis that the time elapsed between the two events is of about 0.5–1 year. Of the 5 selected EXors candidates, 3 are Class I sources, and 2 are flat-spectrum sources, a circumstance that suggests that accretion-driven variability is a common phenomenon during the earlier phases of the protostellar evolution. In the light of the new WISE data, we also re-examine a sample of 10 variables, which we had already selected in Giannini et al. (2009). From the inspection of their light curves, we select two flat-spectrum sources as the best EXors candidates.     

Reconstruction of the variability of the southwest monsoon during the past 3 ka,from the continental margin of the southeastern Arabian Sea

From temporal variation in δ¹⁸O in Globigerinoides ruber and G. sacculifer and geochemical indices of weathering/erosion (chemical index of alteration, Al and Ti), we infer rapid southwest monsoon (SWM) deterioration with dwindling fluvial and detrital fluxes at ca. 450–650, 1000 and 1800–2200 cal. a BP during the late Holocene. We have evaluated the role of solar influx (reconstructed) and high‐latitude climate variability (archived in GRIP and GISP‐2 cores) on SWM precipitation. Broadly, our δ¹⁸O climate reconstruction is concordant with GRIP and GISP‐2, and supports a teleconnection through atmospheric connection between the SWM and the North Atlantic climate – albeit temporal extents of the Little Ice Age and Medieval Warm Period from high latitude are not entirely coeval. Moreover, there is a humid climate and enhanced precipitation during the terminal stages of the Little Ice Age. The medieval warming (ca. AD 800–1300) is not synchronous either, and is punctuated by an arid event centred at 1000 a BP. Although the delineation of the specific influence of solar influx on SWM precipitation is elusive, we surmise that SWM precipitation is a complex phenomenon and local orography along southwestern India may have a role on the entrapment of moisture from the southwest trade winds, when these hit land. Copyright © 2009 John Wiley & Sons, Ltd.     

Spectroscopic Studies on Astrophysically Interesting TaO TaS, ZrS and SiO+ Molecules

The true experimental potential energy curves for the electronic ground states of astrophysically important TaO, TaS, ZrS and SiO⁺molecules are constructed by using the Rydberg–Klein–Rees method as modified by Vanderslice et al. The ground state dissociation energies are determined by curve fitting techniques using the five parameters Hulburt-Hirschfelder (H-H) function. The estimated dissociation energies are 8.19 ± 0.17, 6.9 ±0.14, 5.89 ± 0.12 and 5.75 ± 0.12 eVfor TaO, TaS, ZrS and SiO⁺ respectively. These values are in good agreement with the literature values. The r-centriods and Franck–Condon factors (FC Factors) for the bands of K ² φ _5/2 - X ² Δ _3/2 (K-X) system of TaO, A-X ² Δ (A-X) and B-X ² Δ (B-X)systems of TaS, B ¹ Π - X¹ Σ⁺ (B-X) system of ZrS and B ²Σ⁺ - X² Σ⁺ (B-X) and A ² Π - X² Σ⁺ (A-X)systems of SiO⁺ molecules have been calculated. The Franck–Condon factors (FC factors) are evaluated by the approximate analytical methods of Jarmain and Fraser. The absence of the bands of these systems is explained. This revised version was published online in July 2006 with corrections to the Cover Date.     

13C/12C ratio double cyclicity in a Miocene browncoal: isotopic signals and orbital forcing

A detailed stable carbon isotopic profile of a late Miocene browncoal seam from the Lower Rhine Embayment, Germany, reveals two clear separate cycles of different frequency: this is the first instance of this type of isotopic signature being recognized within coals. The ratio of the two frequencies suggests this isotopic signal possibly resulted from climatic or vegetational responses to orbital forcing. The cyclicity has been enhanced by the application of conventional filtering methods on the data set. An analysis of the seam's palynology indicates a correlation between heavier isotopic compositions and the presence of Sequoiapollenites polyformosus , whose parent plant is believed to have favoured moist climates and higher groundwater tables.     

Millimeter and Submillimeter Emissions from Galactic and Extragalactic Photodissociation Regions

The galactic and Extragalactic photodissociation regions are primarily heated by photoelectrons ejected from the surface of interstellar dust grains by Far-ultraviolet (FUV) photons. But there is no direct mechanism to measure the photoelectric heating efficiency. To understand the role of dust grains in processing the Interstellar Radiation Field (ISRF) and heating the gas, we compare the intensities I _CII, I _CO and I _FIR for (² P _3/2→² P _1/2) & (J = 1→ 0) line emission of CII & CO at 158 μm & 2.6 mm and integrated far-infrared from number of photodissociation regions, HII regions, planetary nebulae, reflection nebulae and high latitude translucent clouds (HLCs). It is found that I _CII is linearly correlated with I _FIR. In the cold medium where cloud is exposed to weak radiations temperature is low and most of the cooling is due to [CII] emissions. As a result the ratio of I _CII/I _FIR provide indirect method to evaluate the photoelectric heating efficiency. For the neutral cold medium it is evaluated to be ∼0.028. The FUV radiation field G ₀ are estimated through the model calculation of I _CII and I _CO for different galactic and photodissociation regions. The intensity of FIR radiation I _FIR are well represented as 1.23×10⁻⁴ G ₀(ergs cm⁻² s⁻¹ sr⁻¹) almost same as estimated for HLCs by Ingalls et al (2002). Hydrogen density for each source has also been estimated.     

Studies of clump structure of photodissociation regions at millimeter and sub-millimeter wavelengths

To interpret the millimeter and sub-millimeter line emissions of atomic and molecular species from galactic and extragalactic photodissociation regions, warm gas components and molecular clouds, generally, escape probability formalism of Tielens & Hollenbach (herein referred as TH) are employed which is based on the assumption of plane parallel geometry of infinite slab allowing photons to escape only from the front. Contrary to the assumption observationally it is found that these lines are optically thin except OI(63μ m) and low rotational transitions of CO and some other molecules. This observational evidence led us to assume that emitting regions are finite parallel plane slab in which photons are allowed to escape from both the surfaces (back and front). Therefore, in the present study escape of radiations from both sides of the homogeneous and also clumpy PDR/molecular clouds are taken into consideration for calculating the line intensities at millimeter and sub-millimeter wavelengths (hereinafter referred as QA). Results are compared with that of the TH model. It is found that thermal and chemical structures of the regions are almost similar in both the formalisms. But line intensities are modified by differing factors. Particularly at low density and low kinetic temperature and also for optically thin lines line intensities calculated from TH and QA model differ substantially. But at density higher than the critical density and also for optically thick lines TH and QA models converge to almost same values. An attempt has been made to study the physical conditions of the M17 region employing the present formalism.