Elemental characterization of black shales of Khyber Pakthunkhawa (KPK) region of Pakistan using AAS

Black shale samples were collected from Chimiari Khyber Pakthunkhawa region of Pakistan and were analyzed for elemental compositions. Atomic Absorption Spectrophotometry (AAS) was utilized for the determination of elements in the digested solutions. The analysis of black shale was performed precisely with relative standard deviation (RSD) lower than 2%. Results showed that the samples contained high concentrations of Ca (11.98 %), Al (7.09%), Fe (3.03%), Mg (0.59%) and Ti (0.58%).     

Cut Slope Design Recommendations for Sub-Horizontal Hard Sedimentary Rock Units in Ohio, USA

Although most cut slopes in Ohio consist of inter-layered, sub-horizontal units of hard and soft sedimentary rocks (sandstone, limestone, dolostone, shale, claystone, mudstone), slopes consisting of relatively thick hard rock units are not uncommon. Design of stable cut slopes in hard rock units needs to consider rock mass strength and orientation of discontinuities with respect to slope face. Results of kinematic stability analyses show that hard-rock cut slopes are less likely to have conventional plane and wedge failures, caused by unfavorable orientation of discontinuities. The main cause of failure is identified to be the undercutting-induced toppling, which is not amenable to traditional kinematic or rock mass strength-based analyses. Therefore, to recommend a suitable slope angle, numerical models, using UDEC software, were employed to study how various slope angles affect the process of undercutting-induced toppling failures. The UDEC models showed a slope angle of 45° (1H:1 V) to be the most stable angle. However, a 63° (0.5H:1 V) slope angle can significantly reduce the potential for such failures and is therefore more appropriate than the widely used angle of 76° (0.25H:1 V).     

Rotational failure mechanisms for the face stability analysis of tunnels driven by a pressurized shield

The aim of this paper is to determine the collapse and blow‐out face pressures of a circular tunnel driven by a pressurized shield. The analysis is performed in the framework of the kinematical approach of the limit analysis theory. Two rotational failure mechanisms are proposed for the active and passive cases. These mechanisms have two significant advantages with respect to the available ones: (i) they take into account the entire circular tunnel face instead of an inscribed ellipse to this circular area, and (ii) they are more consistent with the rotational rigid‐block movement observed in the experimental tests. For both the active and passive cases, the three‐dimensional failure surface was generated ‘point by point’ instead of simple use of the existing standard geometric shapes such as cones or cylinders. This was achieved by employing a spatial discretization technique. The numerical results have shown that the present rotational mechanisms provide, in the case of frictional soils (with or without cohesion), a significant improvement with respect to the translational mechanisms. Finally, an extension of the proposed collapse mechanism to include a tension cut‐off in the classical Mohr–Coulomb failure criterion is presented and discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

Time lapse chemical fertilizer monitoring in agriculture sandy soil

Geoelectrical resistivity, hydrogeochemical and soil properties analysis methods were used for chemical fertilizer monitoring in sandy soil at a palm oil plantation in Machang, Malaysia. The time lapse monitoring was done using these methods five times within a three-month period. The hydrogeochemical analysis was conducted over three auger holes to a depth of 1 m and sampled at 25 cm intervals. Chemical fertilizer was applied to the 21 × 21 m² area after the first data set measurement. The areas outside of this fertilized zone are considered a nonfertilized zone. The other four data sets were acquired at about equal time intervals, thus giving a four-post fertilization data set. The hydrogeochemical measurements indicate that the cations content are relatively similar for every time lapse measurement. However, relatively higher changes of anions content occur at the surface level to a depth of 1 m. The nitrate concentration above the limit for safe human consumption as it returns to the initial value about 100 days after fertilization. The geoelectrical model prior to fertilization showed similar resistivity values at near surface to a depth of about 75 cm with no significant occurrences of low resistivity values. Lower resistivity values were obtained during the second, third, fourth and fifth measurements within the chemically fertilized zone. In the last measurement, the resistivity values in the fertilized zone are almost similar to the nonfertilized zone. This indicates that the contaminant has dissolved into the surrounding environment within this time period.     

Sources of deep groundwater salinity in the southwestern zone of Bangladesh

Twenty groundwater samples were collected from two different areas in Satkhira Sadar Upazila to identify the source of salinity in deep groundwater aquifer. Most of the analyzed groundwater is of Na–Cl–HCO₃ type water. The trends of anion and cation are Cl⁻ > HCO₃ ⁻ > NO₃ ⁻ > SO₄ ²⁻ and Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, respectively. Groundwater chemistry in the study area is mainly governed by rock dissolution and ion exchange. The dissolved minerals in groundwater mainly come from silicate weathering. The salinity of groundwater samples varies from ~1 to ~5%, and its source is possibly the paleo-brackish water which may be entrapped during past geologic periods.     

Tectonics in the Cuddapah fold-thrust belt in the Indian shield,Andhra Pradesh,India and its implication on the crustal amalgamation of India and Rayner craton of Antarctica during Neoproterozoic orogenesis

Neoproterozoic orogenesis in East Antarctica and India led to the amalgamation of northern Prince Charles Mountains-Rayner complex of Antarctica with the Krishna Province of India along the present eastern coast of India with the development of ~990–900 Ma old fold-thrust belt. The frontal part of the fold-thrust belt [henceforth called the Cuddapah fold-thrust belt (CFTB)], recognized in the intercratonic, Palaeoproterozoic–Neoproterozoic Cuddapah Basin, includes two frontal thrust sheets carried by the eastern Velikonda and the western Nallamalai thrusts, along with a part of the undeformed foreland, constituting frontal part of a larger fold-thrust belt now fragmented and separated in different continents of Gondwanaland. Therefore, the intercratonic deformation now preserved in the Palaeoproterozoic–Neoproterozoic Cuddapah Basin is related to the collision of the Indian shield to the Antarctic block during the amalgamation of the Rodinia Supercontinent. CFTB is dominated by quasi-plastic deformational structures, representing exhumed deeper level fault-propagation folding related to the Velikonda thrust, while the Nallamalai thrust represents the forelandward thrust of the CFTB dominated by elastico-frictional deformation structures.     

Photo-induced degradation of emamectin benzoate: effect of iron amendments and solvent system

Photodegradation is the major dissipation pathway for emamectin benzoate (EB) in water. Therefore, the photolysis of EB was studied in distilled water (DW) and methanol under different irradiation conditions such as natural sunlight, UV tube, and artificially stimulated light (mercury lamp 125 W). The results of the study showed that EB degrades rapidly in DW than in methanol as evidenced by a photodegradation efficiency of about 75 % achieved in DW, after 24 h of irradiation with UV light, while in methanol, it was only 59.3 %. The addition of iron to EB solution in DW further enhanced its photodegradation. The rate of photodegradation of EB was recorded to be increased from 5.5 × 10^?2 to 1.0 × 10^?1 k/h after amendment with iron. The order for the rate of photodegradation of EB was DW + Fe > DW > methanol, with their respective t _1/2 values of 6.5, 12.6, and 18.7 h. Fe amendment was also found to enhance the degradation efficiency of EB even in the absence of any light (dark).     

Mean runoff coefficient estimation for ungauged streams in the Kingdom of Saudi Arabia

Runoff coefficient estimation in ungauged watersheds has a priority for rain water harvesting and management of runoff water, for domestic and agriculture activities, in semi-arid and arid regions. To estimate mean runoff coefficient (C _Re) for ungauged streams, Pearson's coefficient of linear correlation (r) was measured. The method of linear regression (y?=?mx?+?c) was applied for 16 gauged catchments representing several regions in the Kingdom of Saudi Arabia, such as Al Qassim, Al Madinah, Riyadh, Asir, Makkah, and Jazan. The studied catchments were equally divided into two groups based on their main streams slopes; group A includes eight gauged streams having main stream slope less than 0.01, where group B includes eight gauged streams having main stream slope equal to or greater than 0.01. The result yields the constant of the linear regression for each group and the mean runoff coefficient of basin by an independent value (basin slope) for group A and an independent value (stream slope) for group B. The results indicate that the measured runoff coefficient (C _Rm) and the estimated runoff coefficient (C _Re) are almost equal to each other.     

A new magnetostratigraphic framework for the Lower Miocene (Burdigalian/Ottnangian, Karpatian) in the North Alpine Foreland Basin

Oligocene–Miocene chronostratigraphic correlations within the Paratethys domain are still highly controversial. This study focuses on the late Early Miocene of the Swiss and S-German Molasse Basin (Late Burdigalian, Ottnangian–Karpatian). Previous studies have published different chronologies for this time interval that is represented by the biostratigraphically well constrained Upper Marine Molasse (OMM, lower and middle Ottnangian), Upper Brackish Molasse (OBM, Grimmelfingen and Kirchberg Formations, middle and upper Ottnangian to lower Karpatian, MN 4a–MN 4b) and Upper Freshwater Molasse (OSM, Karpatian–Badenian, MN 5). Here, we suggest a new chronostratigraphic framework, based on integrated magneto-litho-biostratigraphic studies on four sections and three boreholes. Our data indicate that the OBM comprises chrons 5D.1r and 5Dn (Grimmelfingen Fm), chron 5Cr (lower Kirchberg Fm) and the oldest part of chron 5Cn.3n (upper Kirchberg Fm). The OSM begins during chron 5Cn.3n, continues through 5Cn, and includes a long reversed segment that can be correlated to chron 5Br. The OMM-OSM transition was completed at 16.0 Ma in the Swiss Molasse Basin, while the OBM-OSM changeover ended at 16.6 Ma in the S-German Molasse Basin. As the lower Kirchberg Fm represents a facies of the Ottnangian, our data suggest that the Ottnangian–Karpatian boundary in the Molasse Basin is approximately at 16.8 Ma, close to the 5Cr–5Cn.3n magnetic reversal, and thus 0.4 Myr younger than the inferred age of 17.2 Ma used in recent Paratethys time scales. Notably, this would not be problematic for the Paratethys stratigraphy, because chron 5Cr is mainly represented by a sedimentation gap in the Central Paratethys. We also realise, however, that additional data is still required to definitely solve the age debate concerning this intriguing time interval in the North Alpine Foreland Basin. We dedicate this work to our dear friend and colleague Jean-Pierre Berger (8 July 1956–18 January 2012).