新建岩石地层单位的基本要求——以多索曲组的创建为例

本文介绍了岩石地层单位的基本概念,今后新创或修订岩石地层单位应提供的资料和说明,并以多索曲组的创建为例,对有关基本要求进一步予以说明。     

应用氢氧同位素方法研究兰州市傍河水源地地下水水体的形成和循环机理

本文通过测定水中氢氧同位素的变化来对兰州市傍河水源地地下水体的形成和循环机理进行分析探讨。分析了兰州市马滩水源地水质恶化的程度,探讨了恶化的原因。对其工作原理及方法作了较详尽的论述。     

Magnetic properties of soils from sites with different geological and environmental settings

Measurements of magnetic susceptibility of soils, reflecting magnetic enhancement of topsoils due to atmospherically deposited magnetic particles of industrial origin, are used recently in studies dealing with outlining polluted areas, as well as with approximate determination of soil contamination with heavy metals. One of the natural limitations of this method is magnetic enhancement of soils caused by weathering magnetically rich parent rock material. In this study we compare magnetic properties of soils from regions with different geological and environmental settings. Four areas in the Czech Republic and Austria were investigated, representing both magnetically rich and poor geology, as well as point-like and diffuse pollution sources. Topsoil and subsoil samples were investigated and the effect of geology and pollution was examined. Magnetic data including mass and volume magnetic susceptibility, frequency-dependent susceptibility, and main magnetic characteristics such as coercivity (Hc and Hcr) and magnetization (Ms and Mrs) parameters are compared with heavy metal contents. The aim of the paper is to assess the applicability of soil magnetometry under different geological-environmental conditions in terms of magnetic discrimination of dominant lithogenic/anthropogenic contributions to soil magnetic signature. Our results suggest that lithology represents the primary effect on soil magnetic properties. However, in case of significant atmospheric deposition of anthropogenic particles, this contribution can be clearly recognized, independent of the type of pollution source (point-like or diffuse), and discriminated from the lithogenic one. Different soil types apparently play no role. Possible effects of climate were not investigated in this study.     

Uplift and subsidence from oblique slip: the Ganos–Marmara bend of the North Anatolian Transform, western Turkey

Bends that locally violate plate-motion-parallel geometry are common structural elements of continental transform faults. We relate the vertical component of crustal motion in the western Marmara Sea region to the NNW-pointing 18° bend on the northern branch of the North Anatolian Fault (NAF-N) between the Ganos segment, which ruptured in 1912, and the central Marmara segment, a seismic gap. Crustal shortening and uplift on the transpressive west side of the bend results in the Ganos Mountain; crustal extension and subsidence on the transtensional east side produce the Tekirdağ Basin. We propose that this vertical component of deformation is controlled by oblique slip on the non-vertical north-dipping Ganos and Tekirdağ segments of the North Anatolian Fault. We compare Holocene with Quaternary structure across the bend using new and recently published data and conclude the following. First, bend-related vertical motion is occurring primarily north of the NAF-N. This suggests that this bend is fixed to the Anatolian side of the fault. Second, current deformation is consistent with an antisymmetric pattern centered at the bend, up on the west and down on the east. Accumulated deformation is shifted to the east along the right-lateral NAF-N, however, leading to locally opposite vertical components of long- and short-term motion. Uplift has started as far west as the landward extension of the Saros trough. Current subsidence is most intense close to the bend and to the Ganos Mountain, while the basin deepens gradually from the bend eastward for 28 km along the fault. The pattern of deformation is time-transgressive if referenced to the material, but is stable if referenced to the bend. The lag between motion and structure implies a 1.1–1.4 Ma age for the basin at current dextral slip rate (2.0–2.5 cm/year). Third, the Tekirdağ is an asymmetric basin progressively tilted down toward the NAF-N, which serves as the border fault. Progressive tilt suggests that the steep northward dip of the fault decreases with depth in a listric geometry at the scale of the upper crust and is consistent with reactivation of Paleogene suture-related thrust faults. Fourth, similar thrust-fault geometry west of the bend can account for the Ganos Mountain anticline/monocline as hanging-wall-block folding and back tilting. Oblique slip on a non-vertical master fault may accommodate transtension and transpression associated with other bends along the NAF and other continental transforms.     

Acidities of confined water in interlayer space of clay minerals

The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5 e and 1.0 e per cell), layer charge locations (tetrahedral and octahedral) and interlayer counterions (Na⁺ and Mg²⁺). For all models, the interlayer structures are characterized in detail. Na⁺ and Mg²⁺ show significantly different hydration characteristics: Mg²⁺ forms a rigid octahedral hydration shell and resides around the midplane, whereas Na⁺ binds to a basal oxygen atom and forms a very flexible hydration shell, which consists of five waters on average and shows very fast water exchanges. The method of constraint is employed to enforce the water dissociation reactions and the thermodynamic integration approach is used to derive the free-energy values and the acidity constants. Based on the simulations, the following points have been gained. (1) The layer charge is found to be the direct origin of water acidity enhancement in smectites because the neutral pore almost does not have influences on water dissociations but all charged pores do. (2) With a moderate charge density of 0.5 e per cell, the interlayer water shows a pKa value around 11.5. While increasing layer charge density to 1.0 e, no obvious difference is found for the free water molecules. Since 1.0 e is at the upper limit of smectites’ layer charge, it is proposed that the calculated acidity of free water in octahedrally substituted Mg²⁺-smectite, 11.3, can be taken as the lower limit of acidities of free waters. (3) In octahedrally and tetrahedrally substituted models, the bound waters of Mg²⁺ show very low pKa values: 10.1 vs 10.4. This evidences that smectites can also promote the dissociations of the coordinated waters of metal cations. The comparison between the two Mg²⁺-smectites reveals that different layer charge locations do not lead to obvious differences for bound and free water acidities.     

东昆仑西端布喀达坂峰地区二叠纪孢粉型化石的发现

在东昆仑西端布喀达坂峰地区二叠纪地层中首次发现陆相孢粉与海相疑源类化石一起保存的孢粉—疑源类化石组合。经对两个样品较为丰富的孢粉型化石研究后发现,上部组合以裸子植物花粉占优势,双囊无肋花粉最多,可与塔里木盆地的卡伦达尔组的孢粉组合做粗略的比较,但组合中出现了时代偏晚的Ephedripites及Taeniae-sporites,因此,研究区马尔争组中段复理石地层的时代当为中二叠世—晚二叠世。     

河南省煤系地层地震反射波发育特征

对河南省不同区域的煤系地层反射波发育特点进行分析研究、归类总结和正反演对比,建立了地震波-地质层位的对应关系,有利于解释人员从时间剖面上准确分辨出新生界、煤系地层和煤系基底反射波组,确定煤层反射波及煤层赋存状况,为类似地区的地震资料解释工作提供科学的指导。