Tephrostratigraphy and glass compositions of post-15 kyr Campi Flegrei eruptions: implications for eruption history and chronostratigraphic markers

Volcanic ash (tephra) erupted from the frequently active Campi Flegrei volcano forms layers in many palaeoenvironmental archives across Italy and the Mediterranean. Proximal deposits of 50 of the post-15 ka eruptions have been thoroughly sampled and analysed to produce a complete database of glass compositions (>1900 analyses) to aid identification of these units. The deposits of individual eruptions are compositionally diverse and this variability is often greater than that observed between different units. Many of the tephra units do not have a unique glass chemistry, with compositionally similar tephra often erupted over long periods of time (1000s years). Thus, glass chemistry alone is not enough to robustly correlate most of the tephra from Campi Flegrei, especially in the last 10 kyrs. In order to reliably correlate the eruption units it is important to take into account the stratigraphy, chronology, magnitude, and dispersal of the eruptions, which has been collated to aid identification. An updated chronology is also presented, which was constrained using Bayesian analysis (OxCal) of published radiocarbon dates and ⁴⁰Ar/³⁹Ar ages. All the data presented can be employed to help correlate post-15 ka tephra units preserved in archaeological and Holocene palaeoenvironmental archives. The new database of proximal glass compositions has been used to correlate proximal volcanic deposits through to distal tephra layers in the Lago di Monticchio record (Wulf et al., 2004, Wulf et al., 2008) and these correlations provide information on eruption stratigraphy and the tempo of volcanism at Campi Flegrei.     

Rare earth element mobility during granite alteration: Evidence from southwest England

Geochemical analyses of granitic rocks from southwest England reveal that the rare earth elements (REE) were potentially mobile during hydrothermal and supergene alteration. In particular, trivalent REE were removed from the system during K-silicate alteration, Eu was lost during sericitic alteration; all REE were lost during tourmalinization, and light REE were lost during chloritization and argillic alteration. The fluids themselves had low concentrations of REE; in only one case (chloritization) were heavy REE introduced during alteration. Analysis of separated minerals indicated that the behaviour of the REE could be partly explained in terms of their different affinities for the primary and secondary assemblages. Thermodynamic calculations indicated that REE mobility is enhanced by the presence of fluorine in the alteration fluids partly because REE form more stable complexes with F than with Cl and partly because elements such as Ti, Zr and P that form REE-bearing minor phases are themselves potentially mobile.     

Marine sand and gravel production in areas off the northeast coast of the United States

Agencies responsible for issuing permits authorizing excavation of marine sands and gravels have provided information on the amounts of aggregates removed from coastal waters off the New England and Middle Atlantic states. This information is reported herein. Major increases in marine mining are projected. The significance to fisheries of mining marine aggregates is discussed.     

The magnetic properties and morphology of metallic iron produced by subsolidus reduction of synthetic Apollo 11 composition glasses

Metallic iron has been precipitated from a synthetic high-iron, high-titanium Apollo 11 composition glass powder in a furnace with the oxygen fugacity controlled by gas mixing techniques. Measurable quantities of iron, as determined with a vibrating sample magnetometer capable of detecting 0.01 wt% iron in the absence of ferromagnetic minerals, were produced in experiments at temperatures between 700°C and 1045°C, with run times between 3 hr and 95 hr, and oxygen fugacities between 1 and 2 orders of magnitude below the iron-wustite (IW) buffer curve. Such conditions of ?_O2 and T are probably not greatly different from those occurring in a large lunar ejecta blanket. The oxygen fugacity determines the amount of iron produced for a given time and temperature, with about 1% produced if log ?_O2 is 1.4 units below the IW buffer curve and about 3.5% produced if log ?_O2 is 1.7 units below at 990°C. Above 950°C essentially all the iron is multidomain (>300Å) while below 950°C as much as 15% is single domain (150Å–300Å) and an appreciable quantity remains even smaller. Compaction of the sample slows the rate of reduction but does not influence the grain size of metal. The quantities and size distribution of the reduced iron in a number of the experimental runs are strongly analogous to certain lunar soils and breccias and indicate that reduction in an ejected blanket could partly account for the excess iron of lunar soils and breccias relative to the igneous rocks.     

A Hybrid Multi-Agent/Spatial Interaction Model System for Petrol Price Setting

This paper examines the use of multi‐agent simulations (MAS) to model the petrol market. The development of a purely agent based model for petrol prices is presented. Failings within this model are discussed and an alternative strategy for controlling the price of each petrol station based on population of customers is considered. Individual level modelling of customers is too computationally intensive; therefore a spatial interaction model was used to estimate the sales and linked to the agent system to create a hybrid model. To evaluate how effective this hybrid model was, a comparison was made with an existing data set of real petrol prices collected over a two month period. This was achieved both statistically and visually with the use of a Geographical Information System (GIS). Experimentation revealed that the hybrid model outperformed the agent model. Investigation into the behaviour and sensitivity of the system (for example, how prices diffuse spatially) was undertaken by means of idealised simulations.     

Hydro-geomechanical modelling of seal behaviour in overpressured basins using discontinuous deformation analysis

A coupled hydro-geomechanical modelling environment, developed to evaluate the coupled responses of fluid flow in deforming discontinuous media, is described. A staggered computational framework is presented, where the two simulations tools, HYDRO and DDA, communicate via the mapping of an equivalent porosity (and related permeabilities) from the rock system to the fluid phase and an inverse mapping of the pressure field. Several algorithmic and modelling issues are discussed, in particular the computational procedure to map the current geometry of the discontinuous rock blocks assembly into an equivalent porosity (and permeability) field. A generic, geometrically simple, overpressured reservoir/seal system is analysed for illustration. Further examples investigate discontinuous, fractured configurations in flexure causing a degree of spatial variability in the induced stresses. Model predictions show that the combination of hydraulic and mechanical loads causes a dilational opening of some pre-existing fractures and closure of others, with strong localisation of the modified flow pattern along wider fracture openings.