Seasonal Investigations of Dissolved Organic Carbon Dynamics in the Tamar Estuary, U.K.

A high temperature catalytic oxidation (HTCO) technique was used to measure dissolved organic carbon (DOC) during seasonal surveys of the Tamar Estuary, U.K. At the time of the programme, the field of DOC analysis had been plagued by numerous analytical difficulties. However, using thorough calibration of the analytical systems and the systematic analysis of an internal reference material, a valuable estuarine DOC data set was produced. The range of DOC concentrations observed (478–110 μM C) is consistent with the published data for riverine and coastal sea waters respectively. The Tamar Estuary is a freshwater DOC-dominated system, with strong correlation between lateral DOC distribution and salinity. However, mixing behaviour was not strictly conservative. During tidal cycle studies at a fixed station, DOC concentrations appeared to be uncoupled from salinity, and were inversely related to turbidity. It is concluded that tidally-induced resuspension of bottom sediments provided the dominant control mechanism for DOC concentration. The Tamar Estuary shows contrasting behaviour to the larger, more heavily impacted, Severn Estuary. Hence it is likely that the behaviour of DOC in estuaries cannot be classified as typical per se, but is a function of the natural and anthropogenic characteristics of the catchment and hydrology.     

The Environment Act 1995 and quiet enjoyment: implications for countryside recreation in the national parks of England and Wales, UK

Summary National parks in England and Wales have traditionally been seen as places of quiet, less hurried recreation. The phrase 'quiet enjoyment' was adopted to represent this notion, and this paper traces the policy-making process involved in attempting to conserve this view. The debate during the enactment of the Environment Act 1995 brought the use and meaning of the phrase to prominence; amongst other issues, the use of the phrase in tenancy law precluded its use in legislation. The loss of the phrase 'quiet enjoyment' could have prolonged effects on the way in which national parks are used for recreational purposes.     

Photosynthetic responses of selected Antarctic plants to solar radiation in the southern maritime Antarctic

The effects of UV-B exclusion and enhancement of solar radiation on photosynthesis of the two phanerogams which occur in the maritime Antarctic, Deschampsia antarctica and Colobanthus quitensis , and the moss Sanionia uncinats were investigated. Data on air temperature and solar radiation illustrate a drastic seasonal variation. Daily O₃ column mean values and UV-B measured at ground level document the occurrence of the O₃"hole" in the spring of 1997, with a concomitant increase in UV-B. The grass, D. antarctica , exhibited a broad temperature optimum for photosynthesis between 10–25°C while photosynthesis did not saturate even at high irradiance. The high water use efficiencies measured in the grass may be one of the features explaining the presence of this species in the maritime Antarctic. The net photosynthesis response to intercellular CO₂ (A/c_i) for D. antarctica was typical of a C₃ plant. Exposure to a biologically effective UV-B irradiance of 0.74 W M^-2 did not result in any significant change in either the maximum rate of photosynthesis at saturating CO₂ and light, or in the initial carboxylation efficiency of Rubisco. (V_c,max). Furthermore while ambient (or enhanced) solar UV-B did not affect photochemical yield, measured in the field, of C. quitensis and D. antarctica , UV-B enhancement did affect negatively photochemical yield in S. uncinata . In D. antarctica plants, exposure to UV-B at low irradiances elicited increased flavonoid synthesis. The observed effects of UV-B enhancement on the moss (decreased photochemical yield) and the grass (increase in flavonoids) require further, separate investigation.     

The Effects of Probe-Induced Flow Distortion on Velocity Covariances: Field Observations

We carried out measurements to test a simple theory of the effect of probe-induced flow distortion on turbulence measurements. We used two three-component sonic anemometers mounted 1.8m apart at a height of 6.7 m. Behind one was a horizontal circular cylinder of radius 0.15 m and length 1.2 m, chosen to model two-dimensional probe-induced flow distortion in the limit where the scale of the turbulence is very large compared to the scale of the probe. The second sonic anemometer measured the undistorted flow. The measured flow-distortion effects on the Reynolds shearing stress and the variances of streamwise and vertical velocity agree well with the theory.     

Paleoecology of a >90,000-year lacustrine sequence from Fog Lake, Baffin Island, Arctic Canada

A 137 cm sediment core from Fog Lake, a small upland basin that was not glaciated during the Late Wisconsinan, reveals the following stratigraphic succession: (I) basal diamicton, (II) laminated silts, (III) compacted dewatered gyttja, (IV) stratified minerogenic sediments, and (V) overlying gyttja. Units I–III, and most of unit IV, were deposited prior to the Holocene; unit V represents approximately the last 8000 ¹⁴C years. Alternate luminescence dating techniques (TL and IRSL) place unit III in latter oxygen isotope stage (OIS) 5, >74,000 years BP. A suite of 20 AMS ¹⁴C dates suggests that much of the post-OIS 5 paleoenvironmental record is characterized by either extremely low continuous sediment accumulation, or by one or more episodes of more rapid sedimentation. Diverse pollen and spore assemblages have concentrations that are unexpectedly high throughout the pre-Holocene sediments (>10,000 grains cm⁻³), by comparison to the Holocene (5000 grains cm⁻³). Exceedingly low sediment accumulation rates appear to have resulted in the concentration of atmospherically derived pollen and spores. Diatom assemblages record the evolution of the lake's chemistry and past algal production. Several abrupt changes occurred synchronously in both the terrestrial and aquatic components of the system, and these appear to represent ecological responses to pre-Holocene climatic variability. The sediments of Fog Lake provide the first integrated paleoecological record older than Holocene for a vast region of the Canadian Arctic, thereby refining our understanding of long-term arctic ecosystem ontogeny.     

Bioavailability and bacterial degradation rates of dissolved organic matter in a temperate coastal area during an annual cycle

The bioavailability and bacterial degradation rates of dissolved organic matter (DOM) were determined over a seasonal cycle in Loch Creran (Scotland) by measuring the decrease in dissolved organic carbon (DOC), nitrogen (DON) and phosphorous (DOP) concentrations during long-term laboratory incubations (150 days) at a constant temperature of 14 °C. The experiments showed that bioavailable DOC (BDOC) accounted for 29 ± 11% of DOC (average ± SD), bioavailable DON (BDON) for 52 ± 11% of DON and bioavailable DOP (BDOP) for 88 ± 8% of DOP. The seasonal variations in DOM concentrations were mainly due to the bioavailable fraction. BDOP was degraded at a rate of 12 ± 4% d^– 1 (average ± SD) while the degradation rates of BDOC and BDON were 7 ± 2% d^– 1 and 9 ± 2% d^– 1 respectively, indicating a preferential mineralization of DOP relative to DON and of DON relative to DOC. Positive correlations between concentration and degradation rate of DOM suggested that the higher the concentration the faster DOM would be degraded. On average, 77 ± 9% of BDOP, 62 ± 14% of BDON and 49 ± 19% of BDOC were mineralized during the residence time of water in Loch Creran, showing that this coastal area exported C-rich DOM to the adjacent Firth of Lorne. Four additional degradation experiments testing the effect of varying temperature on bioavailability and degradation rates of DOM were also conducted throughout the seasonal cycle (summer, autumn, winter and spring). Apart from the standard incubations at 14 °C, additional studies at 8 °C and 18 °C were also conducted. Bioavailability did not change with temperature, but degradation rates were stimulated by increased temperature, with a Q₁₀ of 2.6 ± 1.1 for DOC and 2.5 ± 0.7 for DON (average ± SD).