Generic identification of fragmentary Quaternary molluscs by amino acid chromatography: A tool for Quaternary and palaeontological research

The amino acid signature of fourteen genera of Mollusca, both Bivalvia and Gastropoda, was determined on over 300 individual valves. Examination of eight specific sets of amino acid ratios (for example: aspartic acid/glutamic acid, leucine/valine) indicates that these 14 genera (Patella, Littorina, Nucella, Buccinum, Turritella, Macoma, Scrobicularia, Mytilus, Cerastoderma, Arctica, Gtycymeris, Venus, Mya, and Hiatelld) can be distinguished one from another with a high degree of certainty. Discrimination between genera can be based on quantitative assessment of the probability of an individual analysis belonging to a specific genus. We conclude that the amino acid signature is sufficiently distinct that small shell fragments can be assigned to a genus on the basis of the amino acid chromatography. In some instances, for example Littorina, it may even be possible to identify fragments to specific species.     

Age of granitoids in the Pripechora fault zone of the basement of Pechora Basin: First U–Pb (SIMS) data

Upper Precambrian basement of the Pechora Basin that is located between the Urals and Timan and is a part of the Pechora plate lies beneath 1–7 km of Ordovician-Cenozoic sediment cover. On the base of geophysical data and drilling the basement of the Pechora plate is subdivided into the Timan crustal block and the Bolshezemel crustal block which differ by composition and the character of magmatism. The boundary between the crustal blocks is a system of deep faults called the Pripechora and Ilych-Chikshino faults that strike in a northwestern direction, extending from the Urals to the Pechora Sea. Granitoids of Charkayu complex which were penetrated by several deep boreholes in Pripechora fault zone are interpreted as suprasubduction (island arc and collision) magmas associated with the Timan orogeny. First U–Pb dating (SIMS, using SHRIMP-II and SHRIMP-RG) of zircons from granitoids indicate that granitoid magmatism which accompanied the final stages of the Timanide orogeny occurred in the Late Vendian about 555–544 Ma. The age of zircons from granites of the 1-Charkayu borehole is 544 ± 6 Ma, from granites of 1-East Charkayu borehole is 545 ± 5 Ma, and from granodiorites of 1-South Charkayu borehole is 555 ± 2 Ma.     

Adsorption of carbonate and bicarbonate salts at the air–brine interface

Previous research has shown that the flotation of soluble salt is determined by interfacial water structure, thermal stability, and viscosity. These salts include alkali halide and alkali oxyanion salts. Of particular interest are the carbonate salts such as those associated with the great trona deposit of the Green River basin in Wyoming. In this study, we investigated the adsorption of carbonate and bicarbonate salts at the air–brine interface and correlated the adsorption behavior with water structure. Specifically, the equilibrium and dynamic surface tensions of sodium carbonate and sodium bicarbonate salts have been measured as a function of the salt concentration up to saturation and compared with the model prediction using the Gibbs–Langmuir adsorption theory. The results show that the negative adsorption of sodium carbonate leads to a significant increase in surface tension of the brine solution. For sodium bicarbonate, both the negative adsorption and the increase in surface tension are significantly lower when compared with the sodium carbonate case. The negative adsorption is correlated with the water structure making/breaking character of carbonate and bicarbonate solutions. In particular, sodium ions are significantly more hydrated than carbonate and bicarbonate ions, and, therefore, tend to be excluded from the air–brine interface. On the other hand, carbonate and bicarbonate ions are accommodated at the air–brine interface. In any event, the balance between sodium exclusion and carbonate/bicarbonate accommodation results in an increase in the surface tension of these solutions with an increase in salt concentration.     

A survey of the age relations of Shetland Rocks

The survey is based on field work by Flinn, on forty-two K-Ar age determinations by Miller, and on previously published work on Shetland. Most of the metamorphic rocks give K-Ar ages of about 420 m.y. It is clear from petrological and stratigraphical evidence that this age is not the age of the metamorphisms and migmatizations responsible for the more obvious features of the rocks, and also that the metamorphic rocks in different areas have had different histories of development. Ages up to 515 m.y. have been found in various areas, and these may be more closely related to the main metamorphisms than the more common 420 m.y. ages. In the Mainland the 420 m.y. age may be related to a late porphyroblast metamorphism: in Unst and Fetlar it seems to be the age of Read's second metamorphism which accompanied the emplacement of nappes and the formation of orogenic sediments. About 400 m.y. ago a series of postorogenic granitic and appinitic complexes were emplaced in the southern part of Shetland. By 380 m.y. ago erosion had reached migmatitic rocks and they were being buried again beneath Old Red sediments and contemporaneous volcanics. Later still, possibly 350 m.y. ago, in Upper Devonian times, granites were emplaced in the west of Shetland cutting the Old Red rocks. Finally the Walls Boundary Fault (Great Glen Fault ?) cut one of these late granites.     

Towards an integrated science of movement: converging research on animal movement ecology and human mobility science

There is long-standing scientific interest in understanding purposeful movement by animals and humans. Traditionally, collecting data on individual moving entities was difficult and time-consuming, limiting scientific progress. The growth of location-aware and other geospatial technologies for capturing, managing and analyzing moving objects data are shattering these limitations, leading to revolutions in animal movement ecology and human mobility science. Despite parallel transitions towards massive individual-level data collected automatically via sensors, there is little scientific cross-fertilization across the animal and human divide. There are potential synergies from converging these separate domains towards an integrated science of movement. This paper discusses the data-driven revolutions in the animal movement ecology and human mobility science, their contrasting worldviews and, as examples of complementarity, transdisciplinary questions that span both fields. We also identify research challenges that should be met to develop an integrated science of movement trajectories.     

Modeling an Urban Heat Island during Extreme Frost in Moscow in January 2017

Izvestiya, Atmospheric and Oceanic Physics - Using the example of an analysis of an extreme lowering of temperature in Moscow in January 2017, the horizontal and vertical extent of the urban heat...     

Early Miocene sequence development across the New Jersey margin

Sequence stratigraphy provides an understanding of the interplay between eustasy, sediment supply and accommodation in the sedimentary construction of passive margins. We used this approach to follow the early to middle Miocene growth of the New Jersey margin and analyse the connection between relative changes of sea level and variable sediment supply. Eleven candidate sequence boundaries were traced in high-resolution multi-channel seismic profiles across the inner margin and matched to geophysical log signatures and lithologic changes in ODP Leg 150X onshore coreholes. Chronologies at these drill sites were then used to assign ages to the intervening seismic sequences. We conclude that the regional and global correlation of early Miocene sequences suggests a dominant role of global sea-level change but margin progradation was controlled by localized sediment contribution and that local conditions played a large role in sequence formation and preservation. Lowstand deposits were regionally restricted and their locations point to both single and multiple sediment sources. The distribution of highstand deposits, by contrast, documents redistribution by along shelf currents. We find no evidence that sea level fell below the elevation of the clinoform rollover, and the existence of extensive lowstand deposits seaward of this inflection point indicates efficient cross-shelf sediment transport mechanisms despite the apparent lack of well-developed fluvial drainage.     

Compositional gradients surrounding spherulites in obsidian and their relationship to spherulite growth and lava cooling

Spherical masses of crystal fibers (spherulites) crystalize from rhyolitic melt/glass mainly in response to significant undercooling while lava cools. Spherulite growth should induce compositional gradients in the surrounding glass from expulsion of incompatible constituents and diffusion of those constituents away from the spherulite. Finite-difference numerical modeling of one-dimensional diffusion, in which diffusivities are allowed to vary with temperature, is used to investigate how compositional gradients reflect spherulite growth and lava cooling. Overall, three forms of gradients are identified. Elements that diffuse quickly are expelled from the spherulite but then migrate away too quickly to become enriched at the boundary of the spherulite. Elements that diffuse slowly are trapped within the growing spherulite. Between those endmembers are elements that are not trapped, yet diffuse slow enough that they become enriched at the contact. Their slow diffusion away then elevates their concentrations in the surrounding glass. How enriched those elements are at the spherulite-matrix interface and how far their enrichments extend outwards into the glass reflect how spherulites grow and thermal conditions during growth. Concentrations of H₂O, Rb, F, Li, Cl, Na, K, Sr, Cs, Ba, and Be were measured in and around spherulites in obsidian from a 4.7?±?1?km³ rhyolite lava dome erupted from Tequila volcano, Mexico. Measurable concentration gradients are found for H₂O, Rb, and F. Attributes of those gradients and the behaviors of the other elements are in accord with their experimentally constrained diffusivities. Spherulites appear to have grown following radial, rather than volumetric, growth. The observed gradients (and lack of others) are more consistent with growth mainly below the glass transition, which would necessitate the dome cooling at ca. 10^?5 to 10^?7?°C?s^?1. Such slow cooling is consistent with the relatively large volume of the dome.     

A Practical Approach to the Design, Monitoring, and Optimization of In Situ MTBE Aerobic Biobarriers

A paradigm for the design, monitoring, and optimization of in situ methyl tert -butyl ether (MTBE) aerobic biobarriers is presented. In this technology, an oxygen-rich biologically reactive treatment zone (the "biobarrier") is established in situ and downgradient of the source of dissolved MTBE contamination in groundwater, typically gasoline-impacted soils resulting from leaks and spills at service station sites or other fuel storage and distribution facilities. The system is designed so that groundwater containing dissolved MTBE flows to, and through, the biobarrier treatment zone, ideally under natural gradient conditions so that no pumping is necessary. As the groundwater passes through the biobarrier, the MTBE is converted by microorganisms to innocuous by-products. The system also reduces concentrations of other aerobically degradable chemicals dissolved in the groundwater, such as benzene, toluene, xylenes, and tert -butyl alcohol. This design paradigm is based on experience gained while designing, monitoring, and optimizing pilot-scale and full-scale MTBE biobarrier systems. It is largely empirically based, although the design approach does rely on simple engineering calculations. The paradigm emphasizes gas injection–based oxygen delivery schemes, although many of the steps would be common to other methods of delivering oxygen to aquifers.