Simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation: conditions for precise shipboard measurements

Appropriate conditions have been achieved for the accurate, rapid, and highly precise shipboard simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation. A nitrogen-specific Antek 705D chemiluminescence detector and a CO₂-specific LiCor Li6252 IRGA have been coupled in-series with a Shimadzu TOC-5000 organic carbon analyser. Precision of both simultaneous measurements is ≤1.5%, i.e. ±1 μmol C l⁻¹ and ±0.3 μmol N l⁻¹, respectively. Quality of analysis is not compromised by vibrations associated with ocean going research vessels.     

Relationships between lightning activity and various thundercloud parameters: satellite and modelling studies

The lightning frequency model developed by Baker et al. [Baker, M.B., Christian, H.J., Latham, J., 1995. A computational study of the relationships linking lightning frequency and other thundercloud parameters, Q. J. R. Meteorol. Soc., 121, 1525–1548] has been refined and extended, in an effort to provide a more realistic framework from which to examine computationally the relationships that might exist between lightning frequency f (which is now being routinely measured from a satellite, using the NASA/MSFC Optical Transient Detector (OTD)) and a variety of cloud physical parameters. Specifically, superior or more comprehensive representations were utilised of: (1) glaciation via the Hallett–Mossop (H–M) process; (2) the updraught structure of the model cloud; (3) the liquid-water-content structure of the model cloud; (4) the role of the reversal temperature T_rev in influencing lightning characteristics; (5) the critical breakdown field for lightning initiation; and (6) the electrical characteristics of the ice crystal anvil of the model cloud. Although our extended studies yielded some new insights into the problem, the basic pattern of relationships between f and the other parameters was very close to that reported by Baker et al. (1995). The more elaborate treatment of T_rev restricted somewhat the range of conditions under which reverse-polarity lightning could be produced if the cloud glaciated via H–M, but confirmed the earlier conclusion that such lightning would not occur if the glaciation was of the Fletcher type. The computations yielded preliminary support for the hypothesis that satellite measurements of f might be used to determine values of the ice-content of cumulonimbus anvils: a parameter of climatological importance. The successful launch and continuing satisfactory functioning of the OTD [Christian, H.J., Goodman, S., 1992. Global observations of lightning from space, Proc. 9th Int. Conf. on Atmospheric Electricity, St. Petersburg, pp. 316–321; Christian, H.J., Blakesee, R.J., Goodman, S.J., 1992. Lightning imaging sensor (LIS) for the earth observing system. NASA Tech. Memorandum, 4350] make it possible—with a high degree of precision—to measure lightning location, occurrence time and frequency f over extensive areas of the Earth's surface. Measured global distributions of lightning and associated lightning stroke radiance demonstrate that: lightning activity is particularly pronounced over the tropics, much greater over land than over the oceans, and exhibits great seasonal variability; lightning radiance tends to be greater over the oceans, less when lightning activity is high, and greater in the Northern Hemisphere winter than summer.     

Comparison of trends in stream water quality

A method is described for assessing the strength of evidence for differences in the trends in chemical concentrations in stream water between catchments. A smoothing spline technique is used to model changes in water quality as a result of changes in flow rates, seasonal effects and an underlying trend. The method involves fitting the model twice, once with the underlying trends constrained to be identical for each river and once with the trends unconstrained. Statistical properties are assessed by simulation methods that allow for the autocorrelation in the residuals from the unconstrained fit. The method is applied to data from two streams in the Balquhidder catchments in the Highlands of Scotland and to data from the Dee, Don and Ythan rivers in the north‐east of Scotland. Copyright © 2003 John Wiley & Sons, Ltd.     

Evaluating a process‐based model for use in streambank stabilization: insights on the Bank Stability and Toe Erosion Model (BSTEM)

Streambank retreat is a complex cyclical process involving subaerial processes, fluvial erosion, seepage erosion, and geotechnical failures and is driven by several soil properties that themselves are temporally and spatially variable. Therefore, it can be extremely challenging to predict and model the erosion and consequent retreat of streambanks. However, modeling streambank retreat has many important applications, including the design and assessment of mitigation strategies for stream revitalization and stabilization. In order to highlight the current complexities of modeling streambank retreat and to suggest future research areas, this paper reviewed one of the most comprehensive streambank retreat models available, the Bank Stability and Toe Erosion Model (BSTEM), which has recently been integrated with several popular hydrodynamic and sediment transport models including the Hydrologic Engineering Center's River Analysis System (HEC‐RAS). The objectives of this paper were to: (i) comprehensively review studies that have utilized BSTEM and report their findings, (ii) address the limitations of the model so that it can be applied appropriately in its current form, and (iii) suggest directions of research that will help make the model a more useful tool in future applications. The paper includes an extensive overview of peer reviewed studies to guide future users of BSTEM. The review demonstrated that the model needs further testing and evaluation outside of the central United States. Also, further development is needed in terms of accounting for spatial and temporal variability in geotechnical and fluvial erodibility parameters, incorporating subaerial processes, and accounting for the influence of riparian vegetation on streambank pore‐water pressure dynamics, applied shear stress, and erodibility parameters. Copyright © 2016 John Wiley & Sons, Ltd.     

Pre‐drill Groundwater Geochemistry in the Karoo Basin,South Africa

Enhanced production of unconventional hydrocarbons in the United States has driven interest in natural gas development globally, but simultaneously raised concerns regarding water quantity and quality impacts associated with hydrocarbon extraction. We conducted a pre‐development assessment of groundwater geochemistry in the critically water‐restricted Karoo Basin, South Africa. Twenty‐two springs and groundwater samples were analyzed for major dissolved ions, trace elements, water stable isotopes, strontium and boron isotopes, hydrocarbons and helium composition. The data revealed three end‐members: a deep, saline groundwater with a sodium‐chloride composition, an old, deep freshwater with a sodium‐bicarbonate‐chloride composition and a shallow, calcium‐bicarbonate freshwater. In a few cases, we identified direct mixing of the deep saline water and shallow groundwater. Stable water isotopes indicate that the shallow groundwater was controlled by evaporation in arid conditions, while the saline waters were diluted by apparently fossil meteoric water originated under wetter climatic conditions. These geochemical and isotopic data, in combination with elevated helium levels, suggest that exogenous fluids are the source of the saline groundwater and originated from remnant seawater prior to dilution by old meteoric water combined with further modification by water‐rock interactions. Samples with elevated methane concentrations (>14 ccSTP/kg) were strongly associated with the sodium‐chloride water located near dolerite intrusions, which likely provide a preferential pathway for vertical migration of deeply sourced hydrocarbon‐rich saline waters to the surface. This pre‐drill evaluation indicates that the natural migration of methane‐ and salt‐rich waters provides a source of geogenic contamination to shallow aquifers prior to shale gas development in the Karoo Basin.     

Geomasking sensitive health data and privacy protection: an evaluation using an E911 database

Geomasking is used to provide privacy protection for individual address information while maintaining spatial resolution for mapping purposes. Donut geomasking and other random perturbation geomasking algorithms rely on the assumption of a homogeneously distributed population to calculate displacement distances, leading to possible under-protection of individuals when this condition is not met. Using household data from 2007, we evaluated the performance of donut geomasking in Orange County, North Carolina. We calculated the estimated k-anonymity for every household based on the assumption of uniform household distribution. We then determined the actual k-anonymity by revealing household locations contained in the county E911 database. Census block groups in mixed-use areas with high population distribution heterogeneity were the most likely to have privacy protection below selected criteria. For heterogeneous populations, we suggest tripling the minimum displacement area in the donut to protect privacy with a less than 1% error rate.     

Quantitative elemental mapping of granulite-facies monazite: Textural insights and implications for petrochronology

Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.     

Guidelines on the use of structure-from-motion photogrammetry in geomorphic research

As a topographic modelling technique, structure-from-motion (SfM) photogrammetry combines the utility of digital photogrammetry with a flexibility and ease of use derived from multi-view computer vision methods. In conjunction with the rapidly increasing availability of imagery, particularly from unmanned aerial vehicles, SfM photogrammetry represents a powerful tool for geomorphological research. However, to fully realize this potential, its application must be carefully underpinned by photogrammetric considerations, surveys should be reported in sufficient detail to be repeatable (if practical) and results appropriately assessed to understand fully the potential errors involved. To deliver these goals, robust survey and reporting must be supported through (i) using appropriate survey design, (ii) applying suitable statistics to identify systematic error (bias) and to estimate precision within results, and (iii) propagating uncertainty estimates into the final data products. © 2019 John Wiley & Sons, Ltd.     

Field testing of modular borehole monitoring with simultaneous distributed acoustic sensing and geophone vertical seismic profiles at Citronelle,Alabama

A modular borehole monitoring concept has been implemented to provide a suite of well‐based monitoring tools that can be deployed cost effectively in a flexible and robust package. The initial modular borehole monitoring system was deployed as part of a CO₂ injection test operated by the Southeast Regional Carbon Sequestration Partnership near Citronelle, Alabama. The Citronelle modular monitoring system transmits electrical power and signals, fibre‐optic light pulses, and fluids between the surface and a reservoir. Additionally, a separate multi‐conductor tubing‐encapsulated line was used for borehole geophones, including a specialized clamp for casing clamping with tubing deployment. The deployment of geophones and fibre‐optic cables allowed comparison testing of distributed acoustic sensing. We designed a large source effort (>64 sweeps per source point) to test fibre‐optic vertical seismic profile and acquired data in 2013. The native measurement in the specific distributed acoustic sensing unit used (an iDAS from Silixa Ltd) is described as a localized strain rate. Following a processing flow of adaptive noise reduction and rebalancing the signal to dimensionless strain, improvement from repeated stacking of the source was observed. Conversion of the rebalanced strain signal to equivalent velocity units, via a scaling by local apparent velocity, allows quantitative comparison of distributed acoustic sensing and geophone data in units of velocity. We see a very good match of uncorrelated time series in both amplitude and phase, demonstrating that velocity‐converted distributed acoustic sensing data can be analyzed equivalent to vertical geophones. We show that distributed acoustic sensing data, when averaged over an interval comparable to typical geophone spacing, can obtain signal‐to‐noise ratios of 18 dB to 24 dB below clamped geophones, a result that is variable with noise spectral amplitude because the noise characteristics are not identical. With vertical seismic profile processing, we demonstrate the effectiveness of downgoing deconvolution from the large spatial sampling of distributed acoustic sensing data, along with improved upgoing reflection quality. We conclude that the extra source effort currently needed for tubing‐deployed distributed acoustic sensing vertical seismic profile, as part of a modular monitoring system, is well compensated by the extra spatial sampling and lower deployment cost as compared with conventional borehole geophones.