Reactions of the feldspar surface with metal ions: Sorption of Pb(II), U(VI) and Np(V), and surface analytical studies of reaction with Pb(II) and U(VI)

Feldspar minerals are thermodynamically unstable in the near-surface environment and their surfaces are well known to react readily with aqueous solutions, leading to incongruent dissolution at low pH values, but congruent dissolution at neutral and high pH values. Interactions with mineral surfaces are an important control on the environmental transport of trace elements and detrital feldspars are abundant in soils and sediments. However, the interactions of metal ions in solution with the reacting feldspar surface have not been widely explored. The interactions of Pb(II), U(VI) and Np(V) ions with the feldspar surface have therefore been studied. Lead is taken up by the microcline surface at pH 6 and 10, but no uptake could be measured at pH 2. There was measurable uptake of Pb(II) on the plagioclase surface at pH 2, 6 and 10. Uptake always increased with pH. In most conditions, Pb(II) reacts through cation exchange process although, at high pH, a discrete phase, probably hydrocerrusite, is observed by atomic force microscopy (AFM) to precipitate on the plagioclase surface. Supersaturation with hydrocerrusite in these conditions is expected from thermodynamic calculations. Uptake of uranyl ion , generally through surface complex formation, could only be measured at pH 6 and 10. At pH 6 and an initial U(VI) concentration above 21.0 μM, precipitation of becquerelite (Ca[(UO₂)₃O₂(OH)₃]₂·8H₂O), identified by AFM and characterised by grazing incidence X-ray diffraction and X-ray photoelectron spectroscopy, is observed on plagioclase. The U(VI) concentration range in which becquerelite precipitation begins (dissolved U(VI) 1-5 μM) is consistent with that predicted from thermodynamic modelling. On plagioclase feldspar, secondary ion mass spectrometry showed diffusion of uranium into the altered surface layer. Uptake of the neptunyl ion (Np(V)) was found at pH 6 and 10 for microcline and at pH 2, 6 and 10 for plagioclase, and was generally lower than uptake of U(VI). By combining batch sorption experiments with imaging and surface analysis, and thermodynamic modelling, it has been possible to gain a mechanistic insight into the reactions of the feldspar surface with metal ions in solution.     

Geochemistry and tectonic significance of metamorphic sole rocks beneath the Beyşehir–Hoyran ophiolite (SW-Turkey)

The Beyşehir–Hoyran ophiolite is situated in the western part of the Tauride belt (SW Turkey) and crops out at two localities north of the lake Beyşehir. It mainly comprises harzburgitic peridotites that were tectonically emplaced to their present position during the Late Eocene. The ophiolites themselves are tectonically overlain by either slope basin deposits with lava blocks (Eğirler formation) or massive Triassic limestone blocks (Deliktaş formation). High-grade sub-ophiolitic metamorphic rocks, i.e. epidote amphibolite, amphibolite, and pyroxene amphibolite, together with minor quartzite and calcschist, are observed at the base of the ophiolite sequence, where they occur as thin tectonic slices with an inverted metamorphic gradient. Average P–T conditions of 630–770 °C and c. 6 ± 1.5 kbar are calculated for the metamorphism of the amphibolites by conventional geothermobarometry, corresponding to a burial depth of 18–20 km. Both the sub-ophiolitic metamorphic rocks and the overlying mantle tectonites were intruded by isolated tholeiitic (Nb/Y = 0.041–0.108) diabase dikes, which do not transect the tectonic contact between the two units. Geochemical investigations of the amphibolites of the sub-ophiolitic rock suite show two different geochemical affinities, with the first group being alkaline in character (Nb/Y = 1–3.86) and the second one being tholeiitic (Nb/Y = 0.064–0.13). REE patterns, trace element plots and tectonomagmatic discrimination diagrams indicate that the most probable protoliths for alkaline amphibolites are within-plate type alkali basalts, whereas those of the tholeiitic group resemble tholeiitic island arc basalts. Similarities between the geochemical characteristics of the amphibolites and those of the volcanic rocks of the Eğirler formation strongly suggest that the latter are the protoliths of the amphibolites.     

Identification and Modelling of Translational and Axial Symmetries and their Hierarchical Structures in Building Footprints by Formal Grammars

Buildings and other man‐made objects, for many reasons such as economical or aesthetic, are often characterized by their symmetry. The latter predominates in the design of building footprints and building parts such as façades. Thus the identification and modeling of this valuable information facilitates the reconstruction of these buildings and their parts. This article presents a novel approach for the automatic identification and modelling of symmetries and their hierarchical structures in building footprints, providing an important prior for façade and roof reconstruction. The uncertainty of symmetries is explicitly addressed using supervised machine learning methods, in particular Support Vector Machines (SVMs). Unlike classical statistical methods, for SVMs assumptions on the a priori distribution of the data are not required. Both axial and translational symmetries are detected. The quality of the identified major and minor symmetry axes is assessed by a least squares based adjustment. Context‐free formal grammar rules are used to model the hierarchical and repetitive structure of the underlying footprints. We present an algorithm which derives grammar rules based on the previously acquired symmetry information and using lexical analysis describing regular patterns and palindrome‐like structures. This offers insights into the latent structures of building footprints and therefore describes the associated façade in a relational and compact way.     

Numerical studies of anchored sheet pile wall behavior constructed in cut and fill conditions

The construction of sheet pile walls may involve either excavation of soils in front or backfilling of soils behind the wall. These construction procedures generate different loading conditions in the soil and therefore different wall behavior should also be expected. The conventional methods, which are based on limit equilibrium approach, commonly used in the design of anchored sheet pile walls do not consider the method of construction. However, continuum mechanics numerical methods, such as finite element method, make it possible to incorporate the construction method during the analyses and design of sheet pile walls. The effect of wall construction type for varying soil conditions and wall heights were investigated using finite element modeling and analysis. The influence of construction method on soil behavior, wall deformations, wall bending moments, and anchor forces were investigated. The study results indicate that walls constructed by backfill method yield significantly higher bending moments and wall deformations. This paper presents the results of the numerical parametric study performed and comparative analyses of the anchored sheet pile walls constructed by different construction methods.     

Evaluating the salinity distribution of a shallow coastal aquifer by vertical multielectrode profiling (Denmark)

A monitoring system, including five groups of piezometers and five vertical multielectrode profiling probes (VMEP), has been installed in an aquifer beneath a coastal dune in Denmark. In order to assess the salinity distribution within the aquifer, geoelectrical data were gathered in March, June and September 2008, by measuring a dipole-dipole and gradient array using multielectrode profiling. Interpretation of the processed resistivity data was performed by regularized inversion using a one-dimensional, horizontally layered model of formation resistivity. The standard deviation on estimated layer log-resistivity was 0.01–0.03. By estimating two parameters of a power function, observed fluid conductivities derived from samples of porewater were related to corresponding estimated formation resistivities. The conductivity profiles correlate with a winter situation in March with high sea level, active recharge and significant wave activity, causing increased hydraulic heads, a thicker freshwater lens and salt water overlying freshwater close to the sea. In June, the thickness of the freshwater lens is reduced due to less recharge and prevailing offshore winds, imposing density-stable conditions and a sharper transition between fresh and brackish water. During the autumn, aquifer recharge is enhanced and hydraulic heads increase, resulting in a thicker freshwater lens.     

Geometry of obstacle marks at instream boulders—integration of laboratory investigations and field observations

Obstacle marks are instream bedforms, typically composed of an upstream frontal scour hole and a downstream sediment accumulation in the vicinity of an obstacle. Local scouring at infrastructure (e.g. bridge piers) is a well-studied phenomenon in hydraulic engineering, while less attention is given to the time-dependent evolution of frontal scour holes at instream boulders and their geometric relations (depth to width, and length ratio). Furthermore, a comparison between laboratory studies and field observations is rare. Therefore, the morphodynamic importance of such scour features to fluvial sediment transport and morphological change is largely unknown. In this study, obstacle marks at boulder-like obstructions were physically modelled in 30 unscaled process-focused flume experiments (runtime per experiment ≥ 5760 min) at a range of flows (subcritical, clear-water conditions, emergent and submerged water levels) and boundary conditions designed to represent the field setting (i.e. obstacle tilting, and limited thickness of the alluvial layer). Additionally, geometries of scour holes at 90 in-situ boulders (diameter ≥ 1 m) located in a 50-km segment of the Colorado River in Marble Canyon (AZ) were measured from a 1 m-resolution digital elevation model. Flume experiments reveal similar evolution of local scouring, irrespective of hydraulic conditions, controlled by the scour incision, whereas the thickness of the alluvial layer and obstacle tilting into the evolving frontal scour hole limit incision. Three temporal evolution phases—(1) rapid incision, (2) decreasing incision, and (3) scour widening—are identified based on statistical analysis of spatiotemporal bed elevation time series. A quantitative model is presented that mechanistically predicts enlargement in local scour length and width based on (1) scour depth, (2) the inclination of scour slopes, and (3) the planform area of the frontal scour hole bottom. The comparison of field observations and laboratory results demonstrates scale invariance of geometry, which implies similitude of processes and form rather than equifinality.     

The effect of asymmetric dune roughness on tidal asymmetry in the Weser estuary

The bed of estuaries is often characterized by ripples and dunes of varying size. Whereas smaller bedforms adapt their morphological shape to the oscillating tidal currents, large compound dunes (here: asymmetric tidal dunes) remain stable for periods longer than a tidal cycle. Bedforms constitute a form roughness, that is, hydraulic flow resistance, which has a large-scale effect on tidal asymmetry and, hence, on hydrodynamics, sediment transport, and morphodynamics of estuaries and coastal seas. Flow separation behind the dune crest and recirculation on the steep downstream side result in turbulence and energy loss. Since the energy dissipation can be related to the dune lee slope angle, asymmetric dune shapes induce variable flow resistance during ebb and flood phases. Here, a noncalibrated numerical model has been applied to analyze the large-scale effect of symmetric and asymmetric dune shapes on estuarine tidal asymmetry evaluated by residual bed load sediment transport at the Weser estuary, Germany. Scenario simulations were performed with parameterized bed roughness of symmetric and asymmetric dune shapes and without dune roughness. The spatiotemporal interaction of distinct dune shapes with the main drivers of estuarine sediment and morphodynamics, that is, river discharge and tidal energy, is shown to be complex but substantial. The contrasting effects of flood- and ebb-oriented asymmetric dunes on residual bed load transport rates and directions are estimated to be of a similar importance as the controls of seasonal changes of discharge on these net sediment fluxes at the Lower Weser estuary. This corroborates the need to consider dune-induced directional bed roughness in numerical models of estuarine and tidal environments.     

Stability Assessment of Avanos Underground Congress Centre (Cappadocia, Turkey) in Soft Tuffs Through an Integrated Scheme of Rock Engineering Methods

The Cappadocia Region is one of the seven sites in Turkey included in the World Heritage List in 1985 by the United Nations Educational, Scientific and Cultural Organization (UNESCO) and includes structures carved into thick and soft tuffs that have survived and kept their integrity for a number of centuries. Besides existing ancient structures, new underground constructions have been undertaken. Considering the historical characteristics of the region, the construction of an underground structure was planned by the Municipality of Avanos Town to utilize a hill remnant from an abandoned quarry as an underground congress centre in the 1980s, but its construction has not yet been completed due to financial problems. In this study, integrated experimental, analytical and numerical analyses and an in situ monitoring program were undertaken to assess the stability conditions of the congress centre, which was carved into a soft tuff susceptible to long-term degradation processes. The experimental results indicate that the surrounding rock is quite vulnerable to cyclic freezing–thawing and wetting–drying processes. The strength of the rock is drastically reduced under saturated conditions, and the processes of freezing and thawing further accelerate the rock degradation under such conditions. Simple short-term stability analyses clearly show that some tensile cracking may take place and that the opening may suffer from some cracking problems 28–30 years after excavation. The analyses carried out for the long-term safety of the structure indicate that the most critical condition exists for the widest opening and that some supports at the middle of the widest opening may be necessary. Nevertheless, further studies on the long-term characteristics of this tuff are necessary to check this conclusion. The in situ monitoring clearly showed that some further crack propagation will occur, especially after rainy and freezing–thawing periods.