Evolution of geochemistry and depositional settings of Early Palaeozoic siliciclastics of the Barrandian (Teplá-Barrandian Unit,Bohemian Massif,Czech Republic)

Cambrian and Ordovician-Middle Devonian sequences of two successive Early Palaeozoic basins of the Barrandian unconformably overlie Cadomian basement in the Bohemian Massif NW interior (Teplá-Barrandian unit) which is the easternmost peri-Gondwanan remnant within the Variscides. Correlation of stratigraphy and geochemistry of the Early Palaeozoic siliciclastic rocks elucidated sediment provenances. Sandstones of the Middle Cambrian Píbram-Jince Basin were derived from a Cadomian Neoproterozoic island arc. The source area of the Ordovician shallow-marine siliciclastics of the successor Prague Basin is a dissected Cadomian orogen. Late Cambrian acid volcanics of the Barrandian and Cambrian (meta)granitoids emplaced in the W part of the Teplá-Barrandian Cadomian basement are also discernible in these sediments. Old sedimentary component increased during the Ordovician. Early Llandovery siliciclastic rocks show characteristics of an abruptly weakened supply of terrigenous material and an elevated proportion of synsedimentary basic volcanics as a result of Silurian transgression. Emsian siliciclastics (intercalated in the Late Silurian to Early Devonian limestone suite) presumably comprise an addition of coeval basic/ultrabasic volcaniclastics. Middle Devonian flysch-like siliciclastics indicate reappearance of Cadomian source near the Barrandian during early Variscan convergences of Armorican microplates that preceeded accretion of the Teplá-Barrandian unit within the Bohemian Massif terrane mosaic.Dr. Patoka deceased in July 2004.     

Detection and quantification of local anthropogenic and regional climatic transient signals in temperature logs from Czechia and Slovenia

The paper reports on detection and quantification of the impact of local anthropogenic structures and regional climatic changes on subsurface temperature field. The analyzed temperature records were obtained by temperature monitoring in a borehole in Prague-Spo?ilov (Czechia) and by repeated logging of a borehole in ?empeter (Slovenia). The observed data were compared with temperatures yielded by mathematical 3D time-variable geothermal models of the boreholes’ sites with the aim to decompose the observed transient component of the subsurface temperature into the part affected by construction of new buildings and other anthropogenic structures in surroundings of the boreholes and into the part affected by the ground surface temperature warming due to the surface air temperature rise. A direct human impact on the subsurface temperature warming was proved and contributions of individual anthropogenic structures to this change were evaluated. In the case of Spo?ilov, where the mean annual warming rate reached 0.034°C per year at the depth of 38.3?m during the period 1993–2008, it turned out that about half of the observed warming can be attributed to the air (ground) surface temperature change and half to the human activity on the surface in the immediate vicinity of the borehole. The situation is similar in ?empeter, where the effect of the recently built surface anthropogenic structures is detectable down to the depth of 80?m and the share of the anthropogenic signal on the non-stationary component of the observed subsurface temperature amounts to 30% at the depth of 50?m.     

Sensitivity of sea ice to wind-stress and radiative forcing since 1500: a model study of the Little Ice Age and beyond

Three different reconstructed wind-stress fields which take into account variations of the North Atlantic Oscillation, one general circulation model wind-stress field, and three radiative forcings (volcanic activity, insolation changes and greenhouse gas changes) are used with the UVic Earth System Climate Model to simulate the surface air temperature, the sea-ice cover, and the Atlantic meridional overturning circulation (AMOC) since 1500, a period which includes the Little Ice Age (LIA). The simulated Northern Hemisphere surface air temperature, used for model validation, agrees well with several temperature reconstructions. The simulated sea-ice cover in each hemisphere responds quite differently to the forcings. In the Northern Hemisphere, the simulated sea-ice area and volume during the LIA are larger than the present-day area and volume. The wind-driven changes in sea-ice area are about twice as large as those due to thermodynamic (i.e., radiative) forcing. For the sea-ice volume, changes due to wind forcing and thermodynamics are of similar magnitude. Before 1850, the simulations suggest that volcanic activity was mainly responsible for the thermodynamically produced area and volume changes, while after 1900 the slow greenhouse gas increase was the main driver of the sea-ice changes. Changes in insolation have a small effect on the sea ice throughout the integration period. The export of the thicker sea ice during the LIA has no significant effect on the maximum strength of the AMOC. A more important process in altering the maximum strength of the AMOC and the sea-ice thickness is the wind-driven northward ocean heat transport. In the Southern Hemisphere, there are no visible long-term trends in the simulated sea-ice area or volume since 1500. The wind-driven changes are roughly four times larger than those due to radiative forcing. Prior to 1800, all the radiative forcings could have contributed to the thermodynamically driven changes in area and volume. In the 1800s the volcanic forcing was dominant, and during the first part of the 1900s both the insolation changes and the greenhouse gas forcing are responsible for thermodynamically produced changes. Finally, in the latter part of the 1900s the greenhouse gas forcing is the dominant factor in determining the sea-ice changes in the Southern Hemisphere.

The Mammoth Peak sheeted complex,Tuolumne batholith,Sierra Nevada,California: a record of initial growth or late thermal contraction in a magma chamber?

The Mammoth Peak sheeted intrusive complex formed in the interior of a ~7–10 km deep magma chamber, specifically in the Half Dome granodiorite of the Tuolumne batholith, central Sierra Nevada, CA (USA). The sheets consist of fractionated melts with accumulated hornblende, biotite, magnetite, titanite, apatite, and zircon. The accumulation, especially of titanite, had a profound effect on minor and trace elements (Nb, Ta, Ti, REE, U, Th, P, Zr, Hf, etc.), increasing their contents up to five to six times. Our thermal–mechanical modeling using the finite element method shows that cooling-generated tensile stresses resulted in the inward propagation of two perpendicular sets of dilational cracks in the host granodiorite. We interpret the sheeted complex to have formed by a crack-seal mechanism in a high strength, crystal-rich mush, whereby outward younging pulses of fractionated magma were injected into these syn-magmatic cracks at the margin of an active magma chamber. Thermal–mechanical instabilities developed after the assembly of the sheeted complex, which was then overprinted by late ~NW–SE magmatic foliation. This case example provides a cautionary note regarding the interpretation that sheeted zones in large granitoid plutons imply a diking mechanism of growth because the sheeted/dike complexes in plutons (1) may display inverse growth directions from the growth of the overall intrusive sequence; (2) need not record initial chamber construction and instead may reflect late pulsing of magma within an already constructed magma chamber; (3) have an overprinting magmatic fabric indicating the continued presence of melt after construction of sheeted complexes and thus a prolonged thermal history as compared to dikes; and (4) because the scale of the observed sheeted complexes may be small (<1%) in comparison to large homogenous parts of plutons, in which there is no evidence for sheeting or diking. Thus, where extensive dike complexes in plutons are absent, such as in much of the Tuolumne batholith, the application of an incremental diking model to explain chamber construction is at best speculative.     

Anion chemistry on Titan: A possible route to large N-bearing hydrocarbons

The reaction of CN^? with cyanoacetylene (HC₃N), has been studied as a function of the HC₃N pressure in a quadrupole tandem mass spectrometer. The mass spectra revealed the fast depletion of the CN^? parent ion and formation of larger anions of rapidly growing size. Most of the ions observed were found to belong to two series of products: (HC₃N)_x·C_2p+1N^? and (HC₃N)_x·C_2pN^? resulting from the sequential additions of HC₃N molecules and loss of HCN or HCCN molecules. The mechanism and energetics of the first two reaction steps are briefly discussed. The laboratory data are compared with those from the Cassini CAPS-ELS spectrometer. It is believed that the reactions observed could account for the growth of anions in Titan’s ionosphere.     

Did humans and natural forests coexist in close proximity? A case study of the Lateglacial and Holocene Mollusca in the Moravian Karst,Czech Republic

Prehistoric settlements are usually perceived as being in opposition to the natural development of the landscape. Indeed, for woodland snail assemblages in anthropogenic landscapes in central Europe, considerable impoverishment is typical. However, it remains unclear whether this has been caused by humans only or also by climate effects. From an archaeological point of view, the Moravian Karst is one of the classic prehistorical locations in central Europe, but with a more humid climate than the previously studied anthropogenic areas. To learn more about coexistence of humans and natural forests during the Lateglacial and Holocene, we analysed 11 mollusc successions covering this entire area, a unique data set for such a relatively small area. These mollusc successions show several specific features compared to the standard development known from other mid‐European areas. One is that although the Moravian Karst is not far from the Western Carpathians, Carpathian species appeared relatively late, only during the second half of the Holocene climatic optimum. Similarly, some western European and Alpine elements appeared later than expected. In contrast to this, however, a number of forest species with central European range appeared relatively early during the Lateglacial or Early Holocene. Two even survived the Last Glacial Maximum in the Moravian Karst. This would suggest an early occurrence of forest patches in a mosaic landscape. Humans have apparently inhabited this area since the Lateglacial amongst islands of forests, which later changed during the Boreal and then the climatic optimum into humid canopy forests. Thus, a mosaic of anthropogenic and natural habitats persisting in close vicinity was possible in rugged and humid landscapes practically until the Industrial Revolution.