A model of neptune according to the Savić-Kašanin theory

A model of the internal structure of Neptune has been calculated according to the Savi?-Ka?anin theory of behaviour of materials under high pressure.     

High-pressure phase transitions — examples of classical predictability

We present 19 examples of materials whose high pressure phase transition points can be determined within a particular classical theory of dense matter. Theoretical predictions are compared with experimental results, and some possible causes of discrepancies are discussed.     

Evaluation of the Mytilus galloprovincialis Lam. digestive gland metallothionein as a biomarker in a long-term field study: seasonal and spatial variability

A study was made of seasonal and spatial variability of metallothionein (MT) concentrations, determined spectrophotometrically in the soluble fraction of the digestive gland of mussels Mytilus galloprovincialis, collected between 1999 and 2001 from several coastal and estuarine locations along the central Eastern Adriatic coast (Croatia). The seasonal influence on the MT and metal concentrations (higher values in winter-spring season, than in summer-autumn season) is more pronounced than the local site-specific influence. Furthermore, within each season a significant site-specific dependence on the MT and trace metal variations can be detected. An inverse relationship of mussel condition index (CI) and temperature with MT and trace metals levels indicates the influence of food abundance and mussel annual reproductive cycle. Substantially higher concentrations of both MT and Cd were recorded in mussels inhabiting estuarine locations, possibly indicating a markedly higher Cd bioavailability at these locations. The positive correlations obtained between MT and Cd in all seasons except autumn support an argument for application of digestive gland MT as a biomarker of Cd exposure, providing evidence for assessing the most appropriate season for mussel sampling.     

The halo population G and K subdwarfs

The photometry of G and K subdwarfs in the Vilnius photometric system permits us to recognize them photometrically and to determine their metallicity, despite the presence of interstellar reddening. The weakening of the strong metallic lines in their spectra can also be used to estimate their metallicity.     

Identification of heterogeneous aquifer transmissivity using an AE-based method

Determination of hydraulic head, H, as a function of spatial coordinates and time, in ground water flow is the basis for aquifer management and for prediction of contaminant transport. Several computer codes are available for this purpose. Spatial distribution of the transmissivity, T(x,y), is a required input to these codes. In most aquifers, T varies in an erratic manner, and it can be characterized statistically in terms of a few moments: the expected value, the variance, and the variogram. Knowledge of these moments, combined with a few measurements, permits one to estimate T at any point using geostatistical methods. In a review of transmissivity data from 19 unconsolidated aquifers, Hoeksema and Kitanidis (1985) identified two types of the logtransmissivity Y= ln(T) variations: correlated variations with variance sigma2Yc and correlation scale, I(Y), on the order of kilometers, and uncorrelated variations with variance sigma2Yn. Direct identification of the logtransmissivity variogram, Gamma(Y), from measurements is difficult because T data are generally scarce. However, many head measurements are commonly available. The aim of the paper is to introduce a methodology to identify the transmissivity variogram parameters (sigma2Yc, I(Y), and sigma2Yn) using head data in formations characterized by large logtransmissivity variance. The identification methodology uses a combination of precise numerical simulations (carried out using analytic element method) and a theoretical model. The main objective is to demonstrate the application of the methodology to a regional ground water flow in Eagle Valley basin in west-central Nevada for which abundant transmissivity and head measurements are available.     

Attenuation Correction Procedures for Water Vapour Fluxes from Closed-Path Eddy-Covariance Systems

Evapotranspiration is a source of water vapour to the atmosphere, and as a crucial indicator of landscape behaviour its accurate measurement has widespread implications. Here we investigate errors that are prevalent and systematic in the closed-path eddy-covariance measurement of latent heat flux: the attenuation of fluxes through dampened cospectral power at high frequencies. This process is especially pronounced during periods of high relative humidity through the adsorption and desorption of water vapour along the tube walls. These effects are additionally amplified during lower air temperature conditions. Here, we quantify the underestimation of evapotranspiration by a closed-path system by comparing its flux estimate to simultaneous and adjacent measurements from an open-path sensor. We apply models relating flux loss to relative humidity itself, to the lag time of the cross-correlation peak between the water vapour and vertical wind velocity signals, and to models of cospectral attenuation relative to the cospectral power of simultaneous sensible heat-flux measurements. We find that including the role of temperature in modifying the attenuation–humidity relationship is essential for unbiased flux correction, and that physically based cospectral attenuation methods are effective characterizers of closed-path instrument signal loss relative to the unattenuated flux value.     

Characterization of atmospheric surfactants in the bulk precipitation by electrochemical tools

Characterization of atmospheric surfactants in bulk precipitations was carried out by adsorption study at the mercury electrode/solution interface using phase sensitive AC voltammetry. The structure and permeability of the adsorbed organic films at the mercury electrode was tested using the redox processes of lead and cadmium ions as electrochemical tools. The effects of organic matter from the bulk precipitations (rainwater and melted snow) were compared to those obtained for aqueous solutions of model substances: aromatic hydrocarbon (naphtalene), anionic surfactant (sodium dodecylbenzene sulfonate, NDBS), protein (albumine) and selected model substances suggested to be representative of water soluble organic compounds (WSOC) in atmospheric water (monocarboxylic, dicarboxylic, and polyacidic compounds and levoglucosan). It was found that substances like humic acid and 3-hydroxybutanoic acid may play an important role in atmospheric heterogeneous chemistry because of their surface active potential.     

Improvement of Vertical Diffusion Analytic Schemes Under Stable Atmospheric Conditions

Based on gradient transport theory or K-theory, turbulent transport in the atmosphere has long been parameterized using the eddy diffusivity. Due to its simplicity, this approach has often been applied in many numerical models but rarely tested with observations. Here, the widely used O’Brien cubic polynomial approach has been validated together with an exponential approach against eddy diffusivity profiles determined from measurements and from large-eddy simulation data in stable conditions. Verification is completed by analyzing the variability effects on pollutant concentrations of two different vertical diffusion (K(z)) schemes incorporated in an atmospheric chemical model. It is shown that the analytical, exponential solution agrees better with observations than the O’Brien profile and should be used henceforth in practical applications.     

An analysis of heat waves in Serbia

In this study, heat waves at three meteorological stations in Serbia were analyzed based on the daily maximum temperature during the summer (June, July and August). The warmest summers as regards heat wave duration and severity occurred within the periods 1951–1952, 1987–1998 (especially 1994) and 2000–2007. The longest heat waves were recorded in 1952, lasting 16 days in Smederevska Palanka and 21 days in Ni?, while in 1994 in Belgrade lasting 18 days. The summer of 1994 in Belgrade and Smederevska Palanka, and 2003 in Ni? were characterized with the highest number of consecutive tropical days (21 and 29, respectively).The autoregressive-moving-average models were applied to generate long series of the daily maximum temperature, from which the relative frequencies of heat waves were estimated. The relationships between the longest heat waves, and the circulation conditions were analyzed using the subjective Hess–Brezowsky catalogue of weather types.