Double ionization of atomic oxygen by electron impact

Laboratory measurements of the cross-sections for double ionization of atomic oxygen by electrons are presented for energies from threshold to ～ 400 eV. A maximum cross-section of about 5.6 × 10^?18 cm² is observed at an electron energy of approx. 200 eV. Absolute cross-sections are obtained from measurements of the ratio of the cross-sections for double and single ionization, coupled with absolute cross-sections for single ionization previously measured by other investigators. The possible effects of excited oxygen reactants are examined, and the reported cross-sections are considered to be characteristic of ground state oxygen atoms.     

Petrogenesis of Miller Range 07273, a new type of anomalous melt breccia: Implications for impact effects on the H chondrite asteroid

Miller Range 07273 is a chondritic melt breccia that contains clasts of equilibrated ordinary chondrite set in a fine‐grained (<5 μm), largely crystalline, igneous matrix. Data indicate that MIL was derived from the H chondrite parent asteroid, although it has an oxygen isotope composition that approaches but falls outside of the established H group. MIL also is distinctive in having low porosity, cone‐like shapes for coarse metal grains, unusual internal textures and compositions for coarse metal, a matrix composed chiefly of clinoenstatite and omphacitic pigeonite, and troilite veining most common in coarse olivine and orthopyroxene. These features can be explained by a model involving impact into a porous target that produced brief but intense heating at high pressure, a sudden pressure drop, and a slower drop in temperature. Olivine and orthopyroxene in chondrule clasts were the least melted and the most deformed, whereas matrix and troilite melted completely and crystallized to nearly strain‐free minerals. Coarse metal was largely but incompletely liquefied, and matrix silicates formed by the breakdown during melting of albitic feldspar and some olivine to form pyroxene at high pressure (>3 GPa, possibly to ~15–19 GPa) and temperature (>1350 °C, possibly to ≥2000 °C). The higher pressures and temperatures would have involved back‐reaction of high‐pressure polymorphs to pyroxene and olivine upon cooling. Silicates outside of melt matrix have compositions that were relatively unchanged owing to brief heating duration.     

Cycling of two carbon substrates of contrasting lability by heterotrophic biofilms across a nutrient gradient of headwater streams

Anthropogenic impacts can significantly alter stream nutrient and dissolved organic carbon (DOC) delivery and composition. Nutrient and DOC cycling in headwater streams, however, are linked via a variety of complex feedbacks that are, in part, influenced by DOC composition emphasizing the need to investigate coupled nutrient–DOC interactions. This study assessed differential incorporation and mineralization of ¹³C labeled glucose and vanillin by heterotrophic microbes within epilithic biofilm communities in four temperate headwater streams spanning a 100-fold range in total dissolved nitrogen and soluble reactive phosphorous concentrations. The substrates were traced via ¹³C analyses of DOC, dissolved inorganic carbon, bulk biofilm, and individual biofilm phospholipid fatty acids (PLFA) to assess total incorporation of the substrates and the distribution of substrate use within the heterotrophic community. Results indicate greater nutrient uptake by high nutrient streams with glucose additions relative to vanillin additions and support the hypothesis that nutrient retention in high nutrient streams is hampered by a lack of labile C sources. Vanillin-derived C uptake was only detectable in PLFA from the highest nutrient stream and was dominated by eukaryotic organisms, likely including fungi. This suggests biofilms in high nutrient streams are better adapted to access relatively slow turnover substrates perhaps due to their composition and overall structure. PLFA-based glucose use efficiencies were greatest in the lowest nutrient stream supporting the hypothesis that labile DOC sources are used more efficiently by heterotrophs in less impacted streams, while biofilms of high nutrient streams are better adapted to utilizing a wider array of DOC sources. This adaption is likely a result of exposure to the lower quality DOC pools in high-nutrient streams resulting from high DOC uptake supported, in part, by fast turnover autochthonous sources of DOC. Nutrient retention in nutrient-rich streams, however, is still likely limited by readily bioavailable DOC leading to lower nutrient retention and downstream nutrient enrichment.     

Interstorm surface preparation and sediment detachment by vehicle traffic on unpaved mountain roads

Road survey and field rainfall simulation experiments have shown that the erodibility of a road surface is dynamic. In the absence of extreme runoff events, dynamic erodibility results from the generation and removal of easily entrained surface material by human road surface maintenance activities, vehicular detachment and overland flow events. Maintenance activities introduce easily transportable material to the road surface where it can be entrained by overland flow. Traffic in dry conditions detaches material that is quickly removed during subsequent overland flow events. The pre‐storm erodibility of a road is therefore largely a function of maintenance and vehicle activity since the last overland flow event. During rainstorms, vehicle passes increase sediment production by detaching/redistributing surface material and creating efficient overland flow pathways for sediment transport. However, if incision of tracks by overland flow does not occur, post‐pass sediment transport quickly returns to pre‐pass rates. Field rainfall simulation data suggest that sediment transport resulting from during‐storm vehicle passes is greatly influenced by the presence of existing loose material, which again is a function of prior road usage and maintenance activities. Incorporation of vehicular effects into physically based road erosion models may be possible by parameterizing both during‐storm and inter‐storm changes in the supply of loose surface material as changes in surface erodibility. Copyright © 2001 John Wiley & Sons, Ltd.     

Backshore coarsening processes triggered by wave‐induced sand transport: the critical role of storm events

Spatial backshore processes were investigated through field observations of topography and median sand grain size at a sandy beach facing the Pacific Ocean in Japan. A comparison of the backshore profile and cross‐shore distribution of the median sand grain size in 1999 and 2004 revealed an unusual sedimentary process in which sand was coarsened in a depositional area in the 5‐year period, although sediment is generally coarsened in erosional areas. In support of these observations, monthly spatial field analyses carried out in 2004 demonstrated a remarkable backshore coarsening process triggered by sedimentation in the seaward part of the backshore during a storm event. In order to elucidate mechanisms involved in the backshore coarsening process, thresholds of movable sand grain size under wave and wind actions (a uniform parameter for both these cases) in the onshore and offshore directions were estimated using wave, tide, and wind data. The cross‐shore distributions of the estimated thresholds provided reasonable values and demonstrated a coarsening mechanism involving the intermediate zone around the shoreline under alternating wave and wind actions as a result of which coarse sand was transported toward the seaward part of the backshore by large waves during storms and then toward the landward part by strong onshore winds. The 5‐year backshore coarsening is most certainly explained by repetition of short‐term coarsening mechanisms caused by wave‐induced sand transport occurring from the nearshore to the intermediate zone. Copyright © 2010 John Wiley & Sons, Ltd     

Mountain pastures and grasslands in the SW Tien Shan, Kyrgyzstan �� Floristic patterns, environmental gradients, phytogeography, and grazing impact

Vast grasslands are found in the walnut-fruit forest region of southern Kyrgyzstan,Middle Asia.Located above the worldwide unique walnutfruit forests and used for grazing,they play a pivotal role in the mixed mountain agriculture of local farmers.Accordingly,these pastures are subject to an increasing utilization pressure reflecting the changing political and social conditions in the transformation process from a Soviet republic to an independent state.A first detailed analysis of mountain pasture vegetation in the Ferghana Range answers the following questions:What are the main plant community types among Kyrgyzstan’s mountain pastures? What are the main environmental gradients that shape their species composition? Which phytogeographical distribution types are predominant? How does grazing affect community composition and species richness in these grasslands? Species composition was classified by cluster analysis;underlying environmental gradients were explored using DCA.A dataset of 395 relevés was used for classification,and a subset of 79 relevés was used in a DCA to analyze the correlation between vegetation,environment,and grazing impact.The investigated pastures were classified into four distinctive plant communities.The site factors altitude,heat load,inclination and grazing impact were found to be the major determinants of the vegetation pattern.A significant overlap between floristic composition and structural and spatial properties was shown.The majority of the species pool consisted of Middle Asian endemics and Eurosiberian species.However,disturbance-tolerant species played a significant role with respect to species composition and coverage of the herbaceous layer in vast areas of southern Kyrgyzstan’s mountain pastures.In general,an intense grazing impact is clearly reflected by both species composition and structural variables of plant communities.The highly diverse and unique ecosystem is modified by an increasing utilization pressure.In order to maintain vital processes and functioning of this valuable ecosystem-in both economical and ecological terms-,it is indispensable to adopt appropriate pasture management strategies.     

The Santa Filomena meteorite shower: Trajectory,classification, and opaque phases as indicators of metamorphic conditions

On August 19, 2020, at 13:18—UTC, a meteor event ended as a meteorite shower in Santa Filomena, a city in the Pernambuco State, northeast Brazil. The heliocentric orbital parameters resulting from images by cameras of the weather broadcasting system were semimajor axis a = 2.1 ± 0.1 au, eccentricity e = 0.55 ± 0.03, and inclination i = 0.15^o ± 0.05. The data identified the body as an Apollo object, an Earth-crossing object with a pericenter interior to the Earth's orbit. The chemical, mineralogical, and petrological evaluations, as well as the physical analysis, followed several traditional techniques. The meteorite was identified as a H5-6 S4 W0 ordinary chondrite genomict breccia. The large amount of metal in the meteorite made a metallographic evaluation based on the opaque phases possible. The monocrystalline kamacite crystals suggest a higher petrological type and the distorted Neumann lines imply at least two different shock events. The absence of the plessite phase shows that the meteorite did not reach the highest shock levels S5 and S6. The well-defined polycrystalline taenite is indicative of petrologic types 4 and 5 due to the conserved internal tetrataenite rim at the boundaries. The presence of polycrystalline taenites and the characteristics of the Agrell Effect suggest that the Santa Filomena meteorite did not reheat above 700°C. The absence of martensite confirms reheating temperatures <800°C and a slow cooling rate. The Ni contents and sizes of the zoned taenite particles indicate a slow cooling rate ranging from 1 to 10 K Myr⁻¹.