骨架矿物—粘土矿物碱耗协同效应研究

选择了克拉玛依油田二中区Ｔ２ｋ１砂砾岩储层中的六种储层矿物,石英,正长石,微斜长石,Ｃａ－蒙脱石,高岭石,伊利石。在不同的条件下研究了这六种矿物的碱耗量,还研究骨架矿物与粘土矿物按照一定的质量配比而成的复配矿物的碱耗量,探讨了矿物碱耗的协同效应,结果表明单矿物的碱耗序列为,蒙脱石（Ｓ）〉高岭石（Ｋ）〉伊利石（Ｉ）〉微斜长石（Ｍ）〉石英（Ｑ）〉正长石（Ｊ）,复配物的碱耗总体上受粘土矿物控制,尤其是蒙     

蒙古国东南部巴音苏赫图晚古生代—早中生代二长花岗岩地球化学特征及其对构造环境的约束

巴音苏赫图二长花岗岩位于西伯利亚板块东南缘陆缘增生带与二连—贺根山板块对接带北缘之间。该岩体由石炭纪及三叠—侏罗纪两期花岗岩组成,均以高硅、富Al2O3、K2O、Na2O,贫MgO、CaO为特征。微量元素表现为富集LILE、亏损HFSE。弱富集LREE,Eu负异常明显。岩石学和地球化学综合研究表明:两期花岗岩早期为高钾钙碱性、准铝质-过铝质花岗岩碰撞期I型花岗岩,晚期花岗岩具有A型花岗岩特点。Sr-Nd同位素研究表明:石炭纪二长花岗岩(87Sr/86Sr)i比值较低(0.700 62～0.704 82),εNd(t)为正值(0.9～1.5),岩浆来自于增生的岛弧或年轻的幔源物质,在岩浆上升过程中遭受了少量地壳物质的混染;晚三叠世—早侏罗世花岗岩(87Sr/86Sr)i比值较高(0.709 96～0.710 19),εNd(t)较低,为-0.3～0.3,该期次花岗岩与晚石炭世花岗岩同源,受地壳混染程度相对较高。应用LA-ICP-MS法测得石炭纪花岗岩U-Pb年龄为(296±3.5)Ma,结合区域构造演化特点及所测三叠纪花岗岩的地球化学特征认为,在晚石炭世,南蒙古额尔德尼查干地区已进入碰撞期构造环境,在三叠—侏罗纪仍有同碰撞花岗岩侵入,晚石炭世以后的碰撞期持续时间较长。     

Heavy metals pollution on the sediments in lakes Dianchi, Erhai and Poyanghu and historical records

In this paper²¹⁰ Pb and ¹³⁷Cs dating methods were used to determine sedimentation rates of lakes Dianchi, Erhai and Poyanghu, and to establish the time scale of the sediments. Also based on geochemical records in the sediment column, the historical variation in heavy metal content over the past one hundred years was determined. Some element concentration increased rapidly after the 1970s, such as Cu, Zn and Mn in the sediments of northern Lake Dianchi, Cd and Mn in southern Lake Erhai and in the west central parts of Lake Poyanghu, Our investigations indicate that the increase in element concentration is caused by human activities. In order to understand the extent of the effect caused by human activities, we have calculated the flux of Zn, Cd and Mn. Results show that the flux caused by human activities is seven times greater than the natural one and the ratio is about 2 times in Lake Erhai and Lake Poyanghu.     

High- and low-Cr chromitite and dunite in a Tibetan ophiolite: evolution from mature subduction system to incipient forearc in the Neo-Tethyan Ocean

The microstructures, major- and trace-element compositions of minerals and electron backscattered diffraction (EBSD) maps of high- and low-Cr# [spinel Cr# = Cr³⁺/(Cr³⁺ + Al³⁺)] chromitites and dunites from the Zedang ophiolite in the Yarlung Zangbo Suture (South Tibet) have been used to reveal their genesis and the related geodynamic processes in the Neo-Tethyan Ocean. The high-Cr# (0.77–0.80) chromitites (with or without diopside exsolution) have chromite compositions consistent with initial crystallization by interaction between boninitic magmas, harzburgite and reaction-produced magmas in a shallow, mature mantle wedge. Some high-Cr# chromitites show crystal-plastic deformation and grain growth on previous chromite relics that have exsolved needles of diopside. These features are similar to those of the Luobusa high-Cr# chromitites, possibly recycled from the deep upper mantle in a mature subduction system. In contrast, mineralogical, chemical and EBSD features of the Zedang low-Cr# (0.49–0.67) chromitites and dunites and the silicate inclusions in chromite indicate that they formed by rapid interaction between forearc basaltic magmas (MORB-like but with rare subduction input) and the Zedang harzburgites in a dynamically extended, incipient forearc lithosphere. The evidence implies that the high-Cr# chromitites were produced or emplaced in an earlier mature arc (possibly Jurassic), while the low-Cr# associations formed in an incipient forearc during the initiation of a new episode of Neo-Tethyan subduction at ~130–120 Ma. This two-episode subduction model can provide a new explanation for the coexistence of high- and low-Cr# chromitites in the same volume of ophiolitic mantle.     

珍珠陶石的夹层化合物法鉴定

应用联氨、使珍珠陶石形成其夹层物，然后再用水洗获是水合珍珠陶石，这种水合珍珠陶石具有十分特征的０．８３５ｎｍＸ射线衍射峰，而高岭石族的其它矿物却保持不变，利用这一明显的特征，可以容易地区分出混合在高岭石中的少量珍珠陶石。     

Lead isotope geochemical characteristics of Pb-Zn-Cu deposits on the southwestern margin of Tarim, and their significance

The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt.     

鲁中碳酸岩中磷灰石同位素地球化学研究

鲁中地区分布着100多个碳酸岩体，微量元素含量及稀土配分等均与世界典型碳酸岩相近。而碳酸岩的碳氧及斑晶磷灰石的锶、钛同位素组成与典型地幔物质有差异，与富集地幔颇为近似，从而证实在山东地区陆壳下存在富集地幔源区。     

塔中古溶洞见证晚奥陶世抬升幅度

塔中隆起区上奥陶统良里塔格组灰岩与桑塔木组砂—粉砂岩之间为不整合接触,昭示着这两个组沉积期之间存在一次历时约百万年的区域性构造抬升事件。中古31井良里塔格组三段的4 125.6～4 133.9 m井段为垮塌型溶洞沉积,洞顶距良里塔格组二段顶部190.6 m,溶洞中角砾状充填物主要来自良里塔格组洞壁本身的礁相灰岩,且见数厘米厚的暗河流水沉积纹层,未发现源于其它时代的颗粒混杂其间。这一事实指证了溶洞的形成和充填时代均为良里塔格组沉积之后、桑塔木组覆盖之前的晚奥陶世凯迪中期。具溶蚀力的淡水潜流带的深度一般不低于周围的海平面,由此可推断出该井区这次抬升出海平面之上的高度,即使忽略良里塔格组顶部可能经地表剥蚀的良里塔格组一段,抬升出水面部分至少也应该有190 m,藉生态地层学恢复洞壁礁灰岩沉积时的海水深度约为30 m±,因此总抬升幅度至少能达到220 m。     

南祁连山前区中生代晚期古构造特征的研究

南祁连山前区可以分为露头和盆地区两个不同的大地构造单元,本区晚中生代构造活动强烈,控制了新生代的沉积过程和现今中生界残余层序的分布。本文提出了均匀平板状沉积体后期的构造变形可以利用古地质图以及高精度残余地层厚度的变化规律判断古构造带的分析方法,并且对于研究区中生代晚期的古构造特征进行了分析。露头区主要利用古地质图分析方法,研究区集中在赛什腾山-埃姆尼克山北缘的鱼卡和红山地区。盆地区主要利用中生界残余厚度图的分析方法,研究区集中在赛什腾山-埃姆尼克山南侧的赛什腾南部凹陷和马海凸起地区。通过这4个地区古构造特征的研究,提出南祁连山前区中生代晚期在区域性隆升的背景下,形成了一系列古构造带,古构造活动的特点是形成北西-北北西走向的背斜和向斜构造,这些褶皱的波长为15～20 km,为中尺度规模。同时指出,中国西部多数地区均缺失上白垩统,暗示着当时的中亚地区存在一个广阔的晚白垩世古高原。     

Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications

Organic matter was experimentally extracted by supercritical fluids(CO2 1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.