湘中锡矿山式锑矿成矿地质条件分析

湘中锡矿山式锑矿形成于晚白垩-古新世,空间上与岩脉关系密切,各锑矿床、矿化点都伴有或附近发育有煌斑岩及中-酸性岩脉群,在锑矿成矿同期地质事件中,还有周缘一些中-新生代红色盆地的形成及基性火山岩喷发,据之,提出湘中锡矿山式锑矿成矿与燕山晚期拉张构造-岩浆活化作用有关.锑矿床(点)基本上都产出于两组或两组以上断裂的交汇点附近,3组断裂的交汇部位对应于最主要的锑矿床(点).矿体具体受断裂交汇部位附近的次级短轴背斜轴部、倾伏背斜的倾伏端及其翼部被纵向陡倾角断裂构造所切穿的部位控制,是断裂导矿与背斜构造圈闭的体现.岩性组合控矿表现为易于硅化蚀变交代的砂质碳酸盐岩与隔挡层泥质岩所构成的岩性圈闭.根据包裹体均-温度和盐度测定成果,推算成矿压力为(200～300)×105Pa,成矿深度约为1 km.     

Contributors to chromium isotope variation of meteorites

We report the results of a comprehensive, high precision survey of the Cr isotopic compositions of primitive chondrites, along with some differentiated meteorites. To ensure complete dissolution of our samples, they were first fused with lithium borate-tetraborate at 1050-1000 °C. Relative to the NIST Cr standard SRM 3112a, carbonaceous chondrites exhibit excesses in ⁵⁴Cr/⁵²Cr from 0.4 to 1.6ε (1ε = 1 part in 10,000), and ordinary chondrites display a common ⁵⁴Cr/⁵²Cr deficit of ∼0.4ε. Analyses of acid-digestion residues of chondrites show that carbonaceous and ordinary chondrites share a common ⁵⁴Cr-enriched carrier, which is characterized by a large excess in ⁵⁴Cr/⁵²Cr (up to 200ε) associated with a very small deficit in ⁵³Cr/⁵²Cr (<2ε). We did not find ⁵⁴Cr anomalies in either bulk enstatite chondrites or in leachates of their acid-digestion residues. This either requires that the enstatite chondrite parent bodies did not incorporate the ⁵⁴Cr anomaly carrier phase during their accretion, or the phase was destroyed by parent body metamorphism. Chromium in the terrestrial rocks and lunar samples analyzed here show no deviation from the NIST SRM 3112a Cr standard. The eucrite and Martian meteorites studied exhibit small deficits in ⁵⁴Cr/⁵²Cr. The ⁵⁴Cr/⁵²Cr variations among different meteorite classes suggest that there was a spatial and/or temporal heterogeneity in the distribution of a ⁵⁴Cr-rich component in the inner Solar System.We confirm the correlated excesses in ⁵⁴Cr/⁵²Cr and ⁵³Cr/⁵²Cr for bulk carbonaceous chondrites, but the new data yield a steeper slope (∼6.6) than that reported in Shukolyukov and Lugmair (2006). The correlated excesses may affect the use of the Mn-Cr chronometer in carbonaceous chondrites. We could not confirm the bulk carbonaceous chondrite Mn-Cr isochron reported by Shukolyukov and Lugmair (2006) and Moynier et al. (2007), mostly because we find much smaller total variations in ε⁵³Cr (∼0.2). All bulk chondrites have small ε⁵³Cr excesses (up to 0.3) relative to the Earth, most likely reflecting the sub-chondritic Mn/Cr ratio of the Earth. The ε⁵³Cr variations in chondrites do seem to grossly correlate with Mn/Cr and yield an initial Solar System ⁵³Mn/⁵⁵Mn value of 5.4(±2.4) × 10⁻⁶, corresponding to an absolute age of 4566.4 (±2.2) Ma.Nuclear interactions with cosmic rays result in coupled excesses in ε⁵⁴Cr and ε⁵³Cr with a ∼4:1 ratio in phases with high Fe/Cr. These are most dramatically demonstrated in the iron meteorite Carbo, showing excesses in ε⁵⁴Cr of up to 140ε. These new results show that the Mn-Cr chronometer should be used with caution in samples/minerals with high Fe/Cr and long cosmic ray exposure ages.     

天山地区夏季极端降水特征及气候变化

基于1961—2007年天山地区32站的逐日降水资料,分析了夏季天山地区极端降水事件的气候分布和时间变化特征.结果表明:夏季天山地区的极端降水量、极端降水日和极端降水比分布存在明显的区域差异.局地极端降水频繁,平均3～4d就有1次发生,大范围极端降水较少发生.连续性极端降水以1d为主.极端降水量在天山南北坡均随地形增加而增多,地形高度对降水的影响,北坡要大于南坡.在相同高度范围内,北坡极端降水量基本均大于南坡.天山地区的极端降水事件呈增多趋势,在1970年代中后期至1980年代中前期,极端降水事件为低值期,而1990年代是高值期.     

不同成因类型煤中烷基环己烷和烷基苯的特征探讨

通过对藻煤、烛煤、腐殖煤共生煤层的分析，将不同成因类型煤中的烷基环己烷和烷基苯进行了比较。结果表明，不同成因类型煤中所含的烷基环己烷和烷基苯明显不同。各种成因类型煤中烷基环己烷和烷基苯所提供的母质信息与煤岩结果吻合。氧化环境不利于烷基环己烷和烷基苯的形成。烷基环己烷和烷基苯有时可以作为沉积环境和成熟度的标志。     

三元络合物在光度法测钍中的应用

本文综述了近十几年中三元络合物在光度法测钍中的进展及显色剂的应用。     

星际A型CH_3CH－H_2含超精细能级的碰撞跃迁速率系数的理论计算

本文作者利用ＩＯＳ近似模型，计算了星际分子云条件下Ａ型ＣＨ３ＣＮ－Ｈ２含超精细能级的碰撞跃迁速率系数。温度范围是２０Ｋ－１４０Ｋ。为研究分子云与恒星形成区的物理、化学性质提供了有用的基础分子数据。     

Some characteristics of pulsations in radio bursts at 9.375 GHz

A type of pulsation in a time scale of seconds superimposed on microwave burst at 9.375 GHz has been found during the twenty-second solar active maximum period by us. This phenomenon is quite different from radio spike emission at decimeter and long centimeter wavelengths. The flux level of the bursts rises as the repetition rate of pulsations increases, following an approximate linear relationship. This feature resembles that at mm wavelength, but some other features are different. Some mechanisms for interpretation have been proposed.     

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.     

The masers of E-type methanol in orion KL and SGR B2

Using a simplified model the statistical equilibrium and radiative transfer equations of E-type-CH₃OH are solved for Orion KL and SgrB2. According to our calculation results and the observation data taken by Matsakiset al. (1980) and Morimotoet al. (1985a, b), the physical conditions of both sources are estimated. In theJ ₂-J ₁ E methanol maser region of Orion KL, the density, kinetic temperature, dust temperature, and the fractional abundance are 0.8–2×10⁶ cm^–3, 150, 30–90 K, 0.8–8×10^–6. In the 4_–1-3₀ E and 5_–1-4₀ E methanol maser region of Sgr B2 the correspondance physical conditions above are 10⁴ cm³, 45, 23 K, and 7×10^–7, respectively.     

大地形对正压扰动演变影响

本文着重研究大地形对正压大气迭加在非均匀纬向基本气流上挑动演变的影响。用WKBJ方法推导了正压扰动的频率和频散关系以及波作用量所满足的方程。当基本流场定常且存在无限长的东西向山脉时,则有波作用量守恒。据此,获得了正压不稳定的必要条件:即在所考察的平面域内至少在某点或某些点上含地形效应的某一物理量等于零,扰动就可能得到发展。对波包动能的倚时变化的讨论得知,在无摩擦正压纬向非均匀基流的情形,地形对扰动动能并无直接影响,即导波和曳波分别在西风急流的南侧和北侧得到加强,并分别在西风急流的北侧和南侧强度减弱。扰动的发展由扰动的结构所决定。导波和曳波的波长缩短总伴同其轴线倾向于东西向相联系,而它们的波长伸长总是与其轴线倾向于南北向同时发生。还指出,正压扰动的加强(或减弱)与波长的伸长(或缩短)不是必然的联系,它的成立是有条件的。