Assessment of the coupled effects of vegetation leaf and root characteristics on soil suction: an integrated numerical modeling and probabilistic approach

Acta Geotechnica - Root depth and leaf area ratio are two important features of a plant and exhibit a coupled relation. Assessing their coupled effects on induced soil suction is essential for...     

The energetics of interaction between oxygen vacancies in sillimanite: A model for the mullite structure

A microscopic model is introduced to discuss the modulated structure of mullite. The oxygen vacancies of this aluminosilicate are known to play a central role. In particular, a single vacancy strongly orders its surrounding Al/Si tetrahedral sites. It is shown in this work that if two oxygen vacancies approach too closely to one another, their Al/Si dressing overlap. This situation results in repulsive interaction. The field of interaction between the vacancies is estimated with the use of an atomistic computer simulation. We use a Bragg-Williams type of theory to dicuss the ordering pattern of the vacancies. Due to frustration between the two dominant repulsive interactions, our model predicts a modulated phase transition in agreement with observation.     

The climate of Scotland over the last 5000 years inferred from multiproxy peatland records: inter‐site correlations and regional variability

The mid to late‐Holocene climates of most of Scotland have been reconstructed from seven peat bogs located across north–south and east–west geographical and climatological gradients. The main techniques used for palaeoclimatic reconstruction were plant macrofossil, colorimetric humification, and testate amoebae analyses, which were supported by a radiocarbon‐based chronology, aided by markers such as tephra isochrons and recent rises in pine pollen and in spheroidal carbonaceous particles (SCPs). Field stratigraphy was undertaken at each site in order to show that the changes detected within the peat profiles were replicable. Proxy climate records were reconstructed using detrended correspondence analysis (DCA) of the plant macrofossil data and a mean water table depth transfer function on the testate amoebae data. These reconstructions, coupled with the humification data, were standardised for each site and used to produce a composite record of bog surface wetness (BSW) from each site. The results show coherent wet and dry phases over the last 5000 years and suggest regional differences in climate across Scotland, specifically between northern and southern Scotland. Distinct climatic cycles are identified, all of which record a millennial‐scale periodicity which can be correlated with previously identified marine and ice core Holocene cycles. The key role of the macrofossil remains of Sphagnum imbricatum, a taxon now extinct on many sites, is discussed in relation to the identified climatic shifts. Copyright © 2005 John Wiley & Sons, Ltd.     

Stabilization of swelling clays by Mg(OH)2. Changes in clay properties after addition of Mg-hydroxide

Stabilization of the swelling clay structure is attempted by intercalation of Mg(OH)₂ and the development of a brucite interlayer between the clay layers. The properties of the product obtained by applying the technique, formulated as described in a previous work, are considered here. The materials used were Wyoming bentonite (USA), Fuller's Earth (UK), kaolinite, illite, lignite, and silica gels. The Mg(OH)₂-clay products were examined by the methylene blue dye test, X-ray diffraction analysis (XRD), differential thermal analysis (DTA), and derivative thermogravimetry analysis (DTGA). From the results obtained it is concluded that: the Mg-hydroxide is adsorbed by swelling clays both on their external and internal surface, whereas it is adsorbed on the external surface by non-swelling clays. The internally adsorbed phase of Mg-hydroxide forms an ill-defined interlayer of brucite, retarding swelling, whereas the external phase covers the particles modifying drastically their surface properties, like the adsorption of the MB dye. The material produced after precipitation of Mg-hydroxide on swelling clays (smectites) did not re-expand on wetting or after glycolation. The adsorption of MB dye was also reduced by some 80–90%, due to coating effect, preventing the measurements of the external surface area of the clay by polar molecules. The principal forces involved in the process are believed to be physical adsorption on the external surface, along with chemisorption and some chemical bonding, mostly in the internal surface. Cementation due to crystallization and, in the long term, some pozzolanic reactions take also place. Internal adsorption of the Mg-hydroxide is postulated to be in the form of positively charged mono- and/or small polymers and it is, chiefly, diffusion controlled. Since Mg-hydroxide is internally adsorbed by swelling clays, whereas Ca-hydroxide(lime) is not, and the (Mg, Ca)-clay aggregates are more stable than the Ca-clay or the Mg-one, the combination of the two hydroxides could give better results in soil stabilization than each hydroxide alone.     

Climate induced temperature effects on growth performance, fecundity and recruitment in marine fish: developing a hypothesis for cause and effect relationships in Atlantic cod (Gadus morhua) and common eelpout (Zoarces viviparus)

Effects of global warming on animal distribution and performance become visible in many marine ecosystems. The present study was designed to develop a concept for a cause and effect understanding with respect to temperature changes and to explain ecological findings based on physiological processes. The concept is based on a wide comparison of invertebrate and fish species with a special focus on recent data obtained in two model species of fish. These fish species are both characterized by northern and southern distribution limits in the North Atlantic: eelpout (Zoarces viviparus), as a typical non-migrating inhabitant of the coastal zone and the cod (Gadus morhua), as a typical inhabitant of the continental shelf with a high importance for fisheries.Mathematical modelling demonstrates a clear significant correlation between climate induced temperature fluctuations and the recruitment of cod stocks. Growth performance in cod is optimal at temperatures close to 10°C, regardless of the population investigated in a latitudinal cline. However, temperature specific growth rates decrease at higher latitudes. Also, fecundity is less in White Sea than in North and Baltic Sea cod or eelpout populations. These findings suggest that a cold-induced shift in energy budget occurs which is unfavorable for growth performance and fecundity. Thermal tolerance limits shift depending on latitude and are characterized by oxygen limitation at both low or high temperatures. Oxygen supply to tissues is optimized at low temperature by a shift in hemoglobin isoforms and oxygen binding properties to lower affinities and higher unloading potential. Protective stimulation of heat shock protein synthesis was not observed.According to a recent model of thermal tolerance the downward shift of tolerance limits during cold adaptation is associated with rising mitochondrial densities and, thus, aerobic capacity and performance in the cold, especially in eurythermal species. At the same time the costs of mitochondrial maintenance reflected by mitochondrial proton leakage should rise leaving a lower energy fraction for growth and reproduction. The preliminary conclusion can be drawn that warming will cause a northern shift of distribution limits for both species with a rise in growth performance and fecundity larger than expected from the Q₁₀ effect in the north and lower growth or even extinction of the species in the south. Such a shift may heavily affect fishing activities in the North Sea.     

Contrasting morphodynamics in alluvial fans and fan deltas: effect of the downstream boundary

Alluvial fans and fan deltas can, in principle, have exactly the same upstream conditions, but fan deltas by definition have ponding water at their downstream boundary. This ponding creates effects on the autogenic behaviour of fan deltas, such as backwater adaptation, mouth bars and backward sedimentation, whereas alluvial fans may lack these effects. Hence the present authors hypothesize that morphodynamics on alluvial fans are determined primarily by upstream boundary conditions, whereas morphodynamics on fan deltas are determined by both the upstream and the downstream boundary condition and changes therein. To isolate the effects of the upstream and downstream boundaries, five new alluvial fan experiments are compared with the details of three fan deltas published earlier that were formed under very similar and simple conditions. Similar to the fan deltas, the alluvial fans build up by sheet flow, whilst quasi‐regular periods of incision cause temporary channelized flow. Incision is followed by channel backfilling, after which the fan returns to sheet flow. The channelization and backfilling in alluvial fans is markedly less pronounced and more prone to autogenic disturbance than in fan deltas. The difference is caused by morphodynamics at the downstream boundary. In a fan delta, the flow expansion of the channel causes deposition of all the sediment, which forms a mouth bar and causes strong backfilling. In an alluvial fan, on the other hand, the slope break at the fan perimeter causes some deposition, but transport is not reduced to zero. Consequently, the backfilling in alluvial fans is less pronounced than in fan deltas. Other published experiments support this trend: removal of the mouth bar by a river leads to permanent channelization, whilst pronounced mouth‐bar formation in highly channelized deltas promotes backward sedimentation. The experimental results for this study predict that, when alluvial fans prograde into lakes or deep rivers, they transition to fan deltas with increasingly deeper channels and thicker backfill deposits.     

Kinematics of the Central Taurides during Neotethys closure and collision, the nappes in the Sultan Mountains, Turkey

In the Central Taurides, the Sultan Mountains comprise in ascending order the Çimendere unit and the Ak?ehir, Do?anhisar, Çay nappes composed of metasedimentary sequences deposited from Cambrian to Tertiary. The overthrust of the Çay nappe on the Lutetian Celepta? formation representing the uppermost stratigraphic position in the Çimendere unit indicates that the latest nappe emplacement occurred during the Middle Eocene. The Oligocene and Miocene rocks are in post-tectonic facies in the west Central Taurides. The kinematic data from these nappes related to closure of the Neotethys reveal a top-NE shear sense in the northwest part and a top-SE shear sense in the southeast part of the Sultan Mountains. The Sultan Mountains are located in the north part of the Isparta Angle which was tectonically assembled by the Lycian, Hoyran–Bey?ehir–Hadim and Antalya allochthons on the Bey Da?lar? and Anamas–Akseki autochthons from the Latest Cretaceous to the Late Pliocene. The previous paleomagnetic data showed that the west and east subsections of the Isparta Angle were subjected to post-Eocene 30°–40° anticlockwise and clockwise rotations, respectively. In consideration of these paleomagnetic data, the kinematic data measured in the Sultan Mountains might be restored into approximately E–W-trending linear fabric associated with a top-E shear sense. These new kinematic data from the nappes in the Sultan Mountains disagree with the existing tectonic models that suggest N–S nappe translation over the Central Taurides during the latest Cretaceous–Middle Eocene. The alternative tectonic model for the Antalya nappes in the core of the Isparta Angle related to east–west compression suggests westward and eastward nappe emplacements on the surrounding autochthons. However, the new kinematic data presented here point consistently to a top-E shear sense in all tectonostratigraphic units in the Sultan Mountains currently located in the north part of the Anamas–Akseki autochthon.