Linking Tarim Basin sea retreat (west China) and Asian aridification in the late Eocene

The Tarim Basin in western China formed the easternmost margin of a shallow epicontinental sea that extended across Eurasia and was well connected to the western Tethys during the Paleogene. Climate modelling studies suggest that the westward retreat of this sea from Central Asia may have been as important as the Tibetan Plateau uplift in forcing aridification and monsoon intensification in the Asian continental interior due to the redistribution of the land‐sea thermal contrast. However, testing of this hypothesis is hindered by poor constraints on the timing and precise palaeogeographic dynamics of the retreat. Here, we present an improved integrated bio‐ and magnetostratigraphic chronological framework of the previously studied marine to continental transition in the southwest Tarim Basin along the Pamir and West Kunlun Shan, allowing us to better constrain its timing, cause and palaeoenvironmental impact. The sea retreat is assigned a latest Lutetian–earliest Bartonian age (ca. 41 Ma; correlation of the last marine sediments to calcareous nannofossil Zone CP14 and correlation of the first continental red beds to the base of magnetochron C18r). Higher up in the continental deposits, a major hiatus includes the Eocene–Oligocene transition (ca. 34 Ma). This suggests the Tarim Basin was hydrologically connected to the Tethyan marine Realm until at least the earliest Oligocene and had not yet been closed by uplift of the Pamir–Kunlun orogenic system. The westward sea retreat at ca. 41 Ma and the disconformity at the Eocene–Oligocene transition are both time‐equivalent with reported Asian aridification steps, suggesting that, consistent with climate modelling results, the sea acted as an important moisture source for the Asian continental interior.     

Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Spatial distribution of solar flares in 23rd solar cycle

H-alpha flares accompanied by the X-radiation f ?? 10^?6 wm^?2 in power are examined; 2331 flares were registered during the first half of the 23rd solar cycle (1997?C2000). The specific power of the X-radiation of the flares monotonically doubles from the minimum to the maximum of the sunspot. An increase in the number of flares in each solar rotation is nonmonotonic and disproportional to the relative number of sunspots. Several longitudinal intervals with increased flare activity can be distinguished in the entire time interval of five to ten rotations. The longitudinal distributions of flares and boundaries of the sector structures of a large-scale magnetic field differ considerably. This confirms the existence of two types of zero lines; the first type is determined by active regions, and the second one is determined by large-scale structures with weak magnetic fields. The flares concentrate near Hale??s zero lines of the first type.     

North Brazil current: vertical structure

On the basis of the data ofin situ measurements of the velocities of currents and basic hydrophysical parameters (such as temperature and salinity) carried out during Cruise 41 of the R/VAkademik Vernadsky, we analyze the structure of the North Brazil Current near the continental slope and in the equatorial abyssal part of the ocean in winter, establish the regularities of changes in the current velocity with depth, and compare the structures of the North Brazil and Guiana Currents. Translated by Peter V. Malyshev and Dmitry V. Malyshev     

Authigenic iron oxide formation in the estuarine mixing zone of the Yangtze River

Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM) (set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone of the Yangtze River.     

Environmental Impact Assessment of the Proposed Titanium Mining Project in Kwale District,Kenya

This article addresses both environmental and socioeconomic issues concerned with the development or operation of the envisaged titanium mining project in Kwale District of Kenya. TIOMIN Resources Inc., of Canada, through its wholly owned Kenyan subsidiary, Kenya Titanium Minerals Ltd., is proposing to develop a titanium sands mine and mineral processing plants which will produce high grades of heavy minerals including rutile, ilmenite, and zircon. In addition, TIOMIN has proposed to develop a ship loading facility at Shimoni, a significant marine habitat in Kenya. When properly designed and implemented, an Environmental Impact Assessment (EIA) is a powerful tool for ensuring that environmental issues are given due consideration during project design, allowing the benefits of the project to be maximized, while reducing the environmental and social costs of development. In Kenya, the EIA has to be conducted according to the requirements of the Kenya Environmental Management and Co-ordination Act (2000) and in compliance with World Bank standards. An EIA document submitted to the enforcement authority, National Environmental Management Authority (NEMA), enables the issuing of an Environmental Impact Assessment License and a Mining License. A number of exploration studies have been undertaken and several sites have been identified for the extraction of titanium minerals and zircon. Many have expressed concern that environmental matters should be considered before a decision about titanium mining is undertaken. Toxic chemicals used in heavy mineral separation processes and disturbance or redistribution of sediment could spell a disaster for the coastal waters. The Wasini channel is home to world class coral reefs, humpback and spotted dolphins, and marine turtles. Another contentious issue is that of radioactivity associated with the minerals zircon and monazite. The coastal zone is a crucial part of the economy, as it supplies a living for a large number of people along the coast. It is envisaged that involuntary resettlement without adequate compensation and viable alternative sites may result in serious socioeconomic consequences.     

Investigation on strength and stability of jointed rock mass using three‐dimensional numerical manifold method

This paper proposes a numerical model for jointed rock masses within the 3‐D numerical manifold method (NMM) framework equipped with a customized contact algorithm. The strength of rock sample containing a few sets of discontinuities is first investigated. The results of models with simple geometries are compared with the available analytical solutions to verify the developed computer code, whereas models with complex geometries are simulated to better understand the fundamental behavior and failure mechanism of jointed rock mass. Furthermore, the stability of jointed rock mass in an underground excavation is studied, where rock failure process is determined by the 3‐D NMM simulation. The simulation results provide valuable guidance on excavation process design and stabilization design in rock engineering practice. Copyright © 2012 John Wiley & Sons, Ltd.     

Using the optical and radar satellite images for the analysis of ecological conditions in the marine environment

Considered are the possibilities for detecting the zones of ecological problems of marine environment using the ocean color sensors data and the radar images. Presented are the peculiarities of satellite data interpretation and the experimental results indicating the spatial and temporal distribution of biogenic slicks and chlorophyll-a concentration as the indicators of ecological conditions in the marine environment. Proposed is the multiparameter correlation graph displaying the relationship between the ecological factors significant for studying the anthropogenic eutrophication.