Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.     

Nouvelle interprétation structurale de la « faille Nord- Pyrénéenne » en vallée d'Aspe (Pyrénées-Atlantiques). Remise en question d'un plutonisme ophitique danien dans le secteur de Bedous

In the Aspe Valley (western Pyrenees), the Europe/Iberia boundary corresponds to a complex fracturing zone, called the ‘Bielle–Accous Wrench-Faulting Corridor’, which represents the classical ‘North-Pyrenean Fault’. Located between the High Primary Range and the North-Pyrenean Zone, the BAWC shows different south-verging sheets mainly composed of Triassic materials. The Bedous ophite, associated with Muschelkalk and Keuper sediments, is also Triassic in age and involved in the same Pyrenean thrusting structures. So, contrary to a recent interpretation, this magmatic rock cannot be related to a supposed Danian plutonism inducing metamorphic processes in the surrounding Mesozoic formations. To cite this article: J. Canérot et al., C. R. Geoscience 336 (2004).     

Apparent and real bias in numerical transfer functions in palaeolimnology

We present an evaluation of the procedure by which model prediction bias is examined in palaeolimnological transfer function inference models. We argue that most of the prediction biases commonly reported in the literature are, in fact, fallacious, and are the artificial consequence of the inappropriate manner in which residuals are traditionally examined. We show that the extent of the specious model bias is entirely predictable from first principles and is essentially determined by the strength of the predictive model. We suggest that the analysis of residuals should always be examined as a function of the model's predictions and we discuss the implications of the old and new approaches.     

Ekman drift and vortical structures

In this article, the authors study the influence of a constant wind on the displacement of a vortex. The well known Ekman current develops in the surface layer and is responsible for a transport perpendicular to the wind: the Ekman drift.An additional process is, however, evidenced, whose importance is as strong as the Ekman drift. There indeed exists a curl of the wind-driven acceleration along isopycnic surfaces when they are spatially variable (they enter and leave the depth where the wind stress acts), which generates potential vorticity anomalies. This diabatic effect is shown to generate potential vorticity anomalies which acts on the propagation of vortical waves and non linear vortices.It is shown that this effect drastically reduces the effect of the Ekman drift for linear waves and surface intensified vortices, while extending its effect to subsurface vortices. It also generates along wind propagation, whose sign depends on the vortex characteristics.     

Nonlinear Mechanical Behavior Analysis of Flexible Lateritic Pavements of Senegal (West Africa) by FEM for M.-E. Pavement Design

Pavement design in Senegal is based on a linear elastic behavior of pavement materials and the hypothesis of a static loading. However, previous works on the mechanical behavior of road materials showed that this one is reversible after several loading cycles and depends on the applied stress. The described behavior is from then on, purely nonlinear. One of the objectives of this research is to determine the parameters of response of lateritic pavement materials submitted to road traffic by using FEM. Therefore, experiments were made on gravel lateritic soils from Dougar, Sébikotane, Mont-Rolland, Pâ Lo and Ngoundiane. The Young’s modulus of the materials was defined in unconfined compression test while repeated load triaxial test was performed to determine the resilient modulus of the gravels and the appropriate model (Uzan model). An implementation was realized with Cast3M©. The importance of the nonlinearity was revealed in a very clear way and was crucial in the construction of the calculation algorithm. The observations for certain conditions showed that the values of the critical responses are more important for the linear model than for the nonlinear model. However, this trend should be validated by further studies.     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).     

Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H2CO) extended source in Comet C/1995 O1 (Hale-Bopp)

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.