Geochemistry and mineralogy of a feldspathic lunar meteorite (regolith breccia), Northwest Africa 2200

The lunar meteorite Northwest Africa (NWA) 2200 is a regolith breccia with a ferroan feldspathic bulk composition (Al₂O₃ = 30.1 wt.%; Mg^# = molar 100 × Mg/(Mg + Fe) = 59.2) and low Th content (0.42 μg/g). Lithologically, NWA 2200 is a diverse mixture of lithic and glassy clasts, mineral fragments, and impact glass spherules, all embedded in a dark glassy matrix. NWA 2200 contains some feldspathic brecciated rock components (ferroan anorthositic granulitic breccia, poikiloblastic granulitic breccia, and glassy melt breccia with an intersertal texture). The bulk compositions of these brecciated components indicate they are derived from ferroan troctolitic or noritic anorthosite lithologies (bulk Al₂O₃ = 26–30 wt.%; bulk FeO/MgO > 1.0). The bulk composition of NWA 2200 is more ferroan and feldspathic than the Apollo feldspathic regolith samples and feldspathic lunar regolith meteorites, and is also more depleted in incompatible elements (e.g., rare earth elements) than Apollo 16 feldspathic regolith samples. We conclude that NWA 2200 originated from a location different to the Apollo landing sites, and may have been sourced from the ferroan KREEP-poor highlands, “KREEP” materials are enriched in such elements as potassium (K), rare earth elements (REE), phosphorus (P).     

The site for r-process nucleosynthesis

Following our hypothesis that each supernova (SN) event triggers star formation in the swept-up gas, so that newly formed stars inherit the elemental abundance pattern of individual SNe, we deduce the production sites and yields for r-process elements. We further show that a strong evidence for the origin of r-process nucleosynthesis products was just there in our backyard - supernova SN1987A -, and conclude that 20 M _⊙ SNe are the predominant production sites for r-process elements. This revised version was published online in September 2006 with corrections to the Cover Date.     

Comparison of toxicity between populations of Gonyaulax tamarensis of eastern North American waters

Isolates of the dinoflagellate Gonyaulax tamarensis were established from benthic cysts or motile cells collected along the north-western Atlantic coast from the Bay of Fundy to Long Island. All clones were grown under the same conditions and assayed in a blind test for toxin content and composition. Differences in toxin content (μmouse unit per cell) spanning two orders of magnitude were found, with decreasing toxicity from north to south. Some isolates had undetectable toxin levels. The low toxicity of southern strains of G. tamarensis may explain the historical absence of paralytic shellfish poisoning (PSP) in areas where cysts and motile cells have been reported. The cause of the observed geographic pattern is unknown, but is does suggest that there may be an environmentally-determined southern limit to the regional PSP problem.Qualitative data on the toxin composition of some clones indicate that saxitoxin, neosaxitoxin and gonyautoxins -II, -III and -IV are generally present. A more quantitative approach (i.e. one which examines each isolate for all of the 12 Gonyaulax toxins) is needed to fully utilize the potential of toxin composition in discriminating between strains.     

Species and concentrations of selenium and nutrients in Tanabe Bay during red tide due toGymnodinium nagasakiense

A red tide due toGymnodinium nagasakiense was observed in August 1988 in Tanabe Bay, Wakayama Prefecture, Japan. The maximum cell concentration ofG. nagasakiense reached 1×10⁵ cells ml^–1 at the surface water. From May to September 1988, the following were monitored: water temperature, salinity, chlorophylla, D.O., dissolved nutrients (NO₂–N, NO₃–N, NH₄–N, PO₄–P DON, DOP), particulate nutrients (PON, POP) and three dissolved selenium species [Se(IV), Se(VI), Organic Se]. Dissolved inorganic nitrogen (NO₃–N, NH₄–N) decreased but PON, POP, DON, DOP and inorganic phosphate increased at the peak of the bloom. The concentration of organic selenium increased up to the bloom initiation period which started on 5 July, and then the concentration of Se(IV) increased as the concentration of organic selenium decreased at the peak of the bloom (3 August). The strong relationship was found between the concentration of Se(IV) and the cell concentration ofG. nagasakiense (r ²=0.98). The Se(IV) requirement ofG. nagasakiense was 2.89×10^–17 moles cell^–1, which was agreed well with 4.4×10^–17 moles cell^–1 found in a laboratory experiment onG. nagasakiense using selenium spiked artificial sea water medium. The average ratio of Se(IV) to dissolved inorganic nitrogen (DIN) during the red tide bloom was 11441, the ratio of Se(IV) to DIN at the surface with the maximum cell concentration ofG. nagasakiense of 1×10⁵ cells ml^–1 was 1137. These results suggested that selenium may play an important role in red tide outbreak ofG. nagasakiense.     

Feldspathic clasts in Yamato-86032: Remnants of the lunar crust with implications for its formation and impact history

Low concentrations of Th and Fe in the Yamato (Y)-86032 bulk meteorite support earlier suggestions that Y-86032 comes from a region of the moon far distant from the Procellarum KREEP Terrain (PKT), probably from the lunar farside. ³⁹Ar–⁴⁰Ar, Rb–Sr, Sm–Nd, and Sm-isotopic studies characterize the chronology of Y-86032 and its precursors in the mega regolith. One of the rock types present in a light gray breccia lithology is an anorthosite characterized by plagioclase with An 93, i.e., more sodic than lunar FANs, but with very low ⁸⁷Rb/⁸⁶Sr and ⁸⁷Sr/⁸⁶Sr similar to those of FANs. (FAN stands for Ferroan Anorthosite). This “An93 anorthosite” has Nd-isotopic systematics similar to those of nearside norites. A FAN-like “An97 anorthosite” is present in a second light-colored feldspathic breccia clast and has a more negative ε_Nd value consistent with residence in a LREE-enriched environment as would be provided by an early plagioclase flotation crust on the Lunar Magma Ocean (LMO). This result contrasts with generally positive values of ε_Nd for Apollo 16 FANs suggesting the possibility of assymetric development of the LMO. Other possible explanations for the dichotomy in ε_Nd values are advanced in the text. The Y-86032 protolith formed at least 4.43 ± 0.03 Ga ago as determined from a Sm–Nd isochron for mineral fragments from the breccia clast composed predominantly of An93 anorthosite and a second clast of more varied composition. We interpret the mineral fragments as being predominatly from a cogenetic rock suite. An ³⁹Ar–⁴⁰Ar age of 4.36–4.41 ± 0.035 Ga for a third clast composed predominantly of An97 anorthosite supports an old age for the protolith. Initial ¹⁴³Nd/¹⁴⁴Nd in that clast was −0.64 ± 0.13 ε-units below ¹⁴³Nd/¹⁴⁴Nd in reservoirs having chondritic Sm/Nd ratios, consistent with prior fractionation of mafic cumulates from the LMO. A maximum in the ³⁹Ar–⁴⁰Ar age spectrum of 4.23 ± 0.03 Ga for a second sample of the same feldspathic breccia clast probably reflects some diffusive ⁴⁰Ar loss. Lack of solar wind and lunar atmosphere implanted Ar in the light gray breccia clast allows determination of an ³⁹Ar/⁴⁰Ar age of 4.10 ± 0.02 Ga, which is interpreted as the time of initial brecciation of this litholgy. After correction for implanted lunar atmosphere ⁴⁰Ar, impact melt and dark regolith clasts give Ar ages of 3.8 ± 0.1 Ga implying melt formation and final breccia assembly 3.8 Ga ago. Some breccia lithologies were exposed to thermal neutron fluences of 2 × 10¹⁵ n/cm², only about 1% of the fluence experienced by some other lunar highlands meteorites. Other lithologies experienced neutron fluences of 1 × 10¹⁵ n/cm². Thus, Y-86032 spent most of the time following final brecciation deeply buried in the megaregolith. The neutron fluence data are consistent with cosmogenic ³⁸Ar_cos cosmic ray exposure ages of 10 Ma. Variations among differing lithologies in the amount of several regolith exposure indicators, including cosmogenic noble gas abundances, neutron capture induced variations in Sm isotopic abundances, and Ir contents, are consistent with a period of early (>3.8 Ga ago) lunar regolith exposure, subsequent deep burial at >5 m depth, and ejection from the moon 7–10 Ma ago.     

Diarrhetic shellfish poisoning in Narragansett Bay

A two-year survey for diarrhetic shellfish poisoning (DSP) was conducted in Narragansett Bay using the mouse assay method. The suspected causative organisms,Dinophysis spp., were monitored at the same time. Only one shellfish sample, in September 1984, yielded an unequivocal positive result at a time when the dinoflagellate population was dominated byD. acuminata. False positive results were suspected in May, when the mussels appeared sexually matured, and in, the summer of 1985, at the time of an unusual massive picoplanktonic bloom. Evidence of toxin production byD. acuminata was obtained from an almost monospecific sample; we calculated that over 5.4×10⁵ cells would be necessary to produce one mouse unit. The specificity and sensitivity of the assay method are questioned and improvements for DSP detection are suggested.     

Formation of chaotic rock units during primary accretion processes: Examples from the Miura–Boso accretionary complex, central Japan

Chaotic rock units exposed in the upper part of the accretionary complex preserve detailed tectonic information related to the periods before, during, and immediately after accretion. Based on the detailed survey in the upper Miocene Miura–Boso accretionary complex, central Japan, three types of chaotic rock units were identified on the basis of the grain sizes and characteristics of blocks and surrounding matrices. The chaotic rock units composed of silt matrices and sandy to pebbly blocks (Type 3) formed by gravity-driven slumping upon the seafloor. The slumping occurred contemporaneously with deposition of the Misaki and Nishizaki Formations within the Izu–Bonin forearc. Vertical variations in the direction of slump vergence represent successive changes from an initially flat seabed to tilting to the northwest and finally to the southeast. Slumping with a northwest vergence indicates landward tilting of the seafloor immediately prior to accretion, whereas vergence to the southeast reflects oceanward tectonic tilting that occurred once the sediments had crossed the deformation front. Other chaotic rock units that have matrices abundant in sand and pebbles (Types 1, 2) formed as a result of subsurface liquefaction and injection associated with large earthquakes that occurred during and after accretion of the sediments. These chaotic rock units are useful in examining surface/subsurface changes such as tectonic tilting of the seafloor and earthquake events during the initial accretion process.     

Rapid tectonics of the Late Miocene Boso accretionary prism related to the Izu–Bonin arc collision

Abstract   The structure, paleomagnetism and biostratigraphy of the Nishizaki and Kagamigaura formations on the southern Boso Peninsula, central Japan, were investigated to determine the chronographic constraints on the accretion, post-Late Miocene rotation and regional tectonics in the Izu–Bonin island arc collision zone. The geological structures on the southern Boso Peninsula are characterized by an east–west trending and south-verging fold and thrust belt that curves toward the northwest–southeast in the northwest extent of the Nishizaki Formation. Two stages of tectonic rotation were revealed by paleomagnetic and structural studies. The first is believed to have occurred after the accretion of the Nishizaki Formation and before the deposition of the Kagamigaura Formation, while the second is confidently correlated with the 1 Ma Izu block collision. The northwest extent of the Nishizaki Formation was rotated clockwise by approximately 65–80°, whereas the rotation was only 25–30° in the east, and 11–13° in the overlying Kagamigaura Formation. Radiolarian biostratigraphy suggests a depositional age of 9.9–6.8 Ma (Upper Miocene period) for the Nishizaki Formation and 4.19-3.75 Ma (Pliocene period) for the lower Kagamigaura Formation. These results indicate that the age of accretion and first-stage rotation of the Nishizaki Formation can be constrained to the interval of 6.80–3.75 Ma. This structure most likely represents the northward bending caused by collisions of the Tanzawa and Izu blocks with the Honshu island arc, and suggests rapid processes of accretion, collision, uplift and the formation of new sedimentary basins within a relatively short period of time (2.61–3.05 my).     

X-ray spectra of various bursts from the rapid burster

About 20 type-I bursts and 3000 type-II bursts were observed with Tenma and Hakucho in 1983. Spectral evolutions were analyzed for both types of bursts and results are presented.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.Purple Mountain Observatory, Academia Sinica, Nanjing, China.     

Sequence-stratigraphic signatures of hemipelagic siltstones in deep-water successions: the Lower Pleistocene Kiwada and Otadai Formations, Boso Peninsula, Japan

Sequence-stratigraphic signatures of hemipelagic siltstones were investigated using profiles of the magnetic susceptibility and selected chemical composition of the Early Pleistocene deep-water successions of the Kiwada and Otadai Formations on the Boso Peninsula, Japan. In the context of an independently developed sequence-stratigraphic framework for the submarine-fan deposits of the Otadai Formation, the magnetic susceptibility and chemical composition, such as the concentrations of TiO₂, MgO and Fe₂O₃, show that the lowstand systems tract deposits have higher values of these parameters than the transgressive and highstand systems tract deposits. In contrast, the CaO contents have inverse relationships with the magnetic susceptibility and are higher in the transgressive and highstand systems tract deposits. The positions of sequence boundaries largely coincide with the horizons from which the magnetic susceptibility and the contents of mafic component increase abruptly. The sequence-stratigraphic variations in the magnetic susceptibility and chemical composition of the submarine-fan hemipelagic siltstones are due to increases in the input of fine-grained, terrigenous clastic sediments from midwater flow suspension, in addition to the direct fluvial supply of relatively unmodified terrigenous clastic sediments during relative sea-level lowstands, although grain size of hemipelagic siltstones does not exhibit any distinct variation through depositional sequences. The Kiwada Formation is characterized by siltstone-dominated basin-plain deposits and its sequence-stratigraphic classification has been difficult when using just lithofacies features. Nevertheless, the profiles of the magnetic susceptibility and chemical composition of the basin-plain deposits are similar to those of the submarine-fan deposits with duration largely equivalent to the 41,000-years obliquity cycle of the Early Pleistocene oxygen isotope sea-level index. This finding indicates that the profiles of the magnetic susceptibility and chemical composition of hemipelagic siltstones reflect sequence-stratigraphic variation in the input of fine-grained terrigenous clastic sediments to the deep-water environments and are crucial for the recognition of cryptic sequence boundaries in hemipelagic successions.