中国南方存在印支期的油气藏——Re-Os同位素体系的制约

利用Re-Os同位素方法开展富含有机质的沥青、原油等的研究,是确定油气成藏时间和破坏时间有效的但极富挑战性的新途径,在国内尚无研究实例报道。以我国南方最大的古油藏之一的麻江古油藏中的沥青为主要对象,采用Re-Os同位素方法试图限定油气的成藏时间和破坏时间。研究表明,麻江古油藏的固体沥青Re、Os同位素质量分数分别在41.5×10-6～642×10-6和0.21×10-6～12.15×10-6之间,N(187Re)/N(188Os)比值较高,且变化范围较大,在270.90～4074.99之间,Os同位素组成指示中等放射成因,其N(187Os)/N(188Os)比值在0.3400～3.6557之间变化。所有沥青样品的模式年龄在28～144Ma之间变化,集中在85Ma左右。通过沥青Re-Os同位素研究,结合详细地质资料,认为麻江古油藏的成藏时间为印支期—早燕山期(144Ma之前),而油藏破坏时间为燕山晚期即85Ma左右。     

安徽南部桃冲地区铁矿床控矿构造分析

通过对桃冲地区典型铁矿床的赋存环境及构造特征的研究和控矿因素分析,认为红花山背斜两翼的铁矿体产于背斜的层间断裂带中的次级褶曲内,受"碳酸盐岩地层+次级褶曲+层间断裂带"三个控矿因素的制约,环滨江岩体的铁矿床受厚层状矽卡岩接触带的制约。综合桃冲地区控矿因素的特点,提出了找矿有利部位。     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

三叠纪嘉陵江期华蓥山同沉积断层的沉积、储层响应

对于断裂带在地质历史时期活动特点的认识,因多期次、不同活动性质的叠加改造而难以确定。以四川盆地南部嘉陵江组为例,通过三叠纪嘉陵江期华蓥山断裂带两侧的沉积、储层的研究发现沉积、储层响应与断面倾向南东、东侧下降的观点矛盾。主要表现为:在非浅滩化的嘉三期,紧邻断裂带西北侧的下降盘地层异常增厚;浅滩化的嘉一晚期—嘉二1期,东南侧的泸州古隆起地区颗粒岩累计厚度较西北侧增厚;另外,断层东南侧的颗粒岩发育早期岩溶型储层,而在西北侧这类储层欠发育。结果表明在三叠纪嘉陵江期华蓥山断裂带的断面倾向北西,为西侧下降的同沉积正断层。     

Analysis of geocell-reinforced mattress with consideration of horizontal–vertical coupling

Geocell reinforcement has been increasingly applied to road embankment engineering. Deformation calculation is one of the major concerns during the design process. In this paper, the power-series method was employed to investigate the performance of a geocell-reinforced mattress under symmetric loads. The geocell-reinforced mattress was idealized as a beam on a Winkler foundation. In the analysis, the soil–foundation beam interface resistance, related to the horizontal deformation coupling with the vertical deformation, was considered. Semi-analytic solutions were developed to assess the deformations and internal forces of the foundation beam and verified against an existing finite element method [9]. The results of the proposed method were close to the results from the finite element method. Moreover, the effects of various factors, such as height of embankment, horizontal and vertical foundation coefficients, composite elastic modulus and height of geocell-reinforced mattress, on the foundation beam settlement and the tension force within the beam are discussed. It was found that the interface resistance related to the horizontal deformation of the beam has a reduction effect on the embankment settlement, and it is beneficial to reduce the embankment settlement by increasing the beam rigidity and strengthening the subgrade soil body.     

Petrogenesis and tectonic implications of Late Jurassic shoshonitic lamprophyre dikes from the Liaodong Peninsula, NE China

This paper presents detailed mineral chemical, element geochemical and Sr–Nd–Hf isotopic data for the Late Jurassic (155?±?4 Ma) lamprophyre dikes in the Liaodong Peninsula, NE China. The lamprophyres are shoshonitic and geochemically fall into three groups: Group I has relatively high SiO₂ (52.5–57.0 wt.%), low MgO (5.5–8.3 wt.%) and compatible trace element (e.g. Cr?=?128–470 ppm) contents, high initial ⁸⁷Sr/⁸⁶Sr ratios (0.7093–0.7117), and low ε_Nd (T) values (?9.6 to ?12.1); Group II has relatively low SiO₂ (44.8–50.0 wt.%), high MgO (10.8–14.2 wt.%) and compatible trace element (e.g. Cr?=?456–1,041 ppm) contents, low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7073–0.7087), and high ε_Nd (T) values (?1.4 to ?2.9); Group III is transitional between the two in all elemental and isotopic compositions. Interpretation of the elemental and isotopic data suggests that the lamprophyric melts were derived by partial melting of subcontinental lithospheric mantle (SCLM) at a depth of 60–80 km (group I), decompression melting of upwelling asthenosphere at 60–100 km (group II), and mixing between the SCLM-derived and asthenosphere-derived melts (group III). It is assumed that the local SCLM was detached at a depth of 60–80 km by the 155 Ma ago. A continental arc-rifting related to the Palaeo-Pacific plate subduction is favored as a geodynamic force for such a cratonic lithosphere detachment.     

白龙江下游涉核地区的放射性环境水平现状调查

通过对白龙江下游涉核地区及周边地区的汽车能谱测量和地面伽玛能谱测量以及空气中的氡浓度的监测,得出区内各地层中的U、Th、K含量均符合当地各地层的特性,与当地本底基本一致,空气氡浓度范围为183.9~305.8 Bq/m3,均属正常,符合当地的天然放射性环境情况,对环境无任何影响。     

Impacts of hydrological conditions on enzyme activities and phenolic concentrations in peatland soil: An experimental simulation

Impacts of hydrological conditions on peatland soil enzyme activities and phenolic concentrations were investigated using peat cores from two typical peatlands, the forest swamp and the marsh in North-east China, under water level manipulation in the laboratory. The results indicated varied impacts of dry and waterlogged conditions on soil enzyme activities, depending on the confounding factors including the peatland types and the variation frequency of hydrological conditions. Carbon-related enzyme activities, phenol oxidase and β-glucosidase, were much higher in the marsh than in the forest swamp. On the contrary, phenolic concentration was measured to be much higher in the latter. Soil enzyme activities and phenolic concentrations were found to vary between the two peatlands, much more remarkably than within the individual peatlands caused by the changes in the water level. The negative relationship or inconspicuous correlation between phenolics and phenol oxidase was found to vary with specific soil conditions. These results implied that the enzyme activities and phenolic concentrations might be related to the developmental stages or the types of wetlands more than to hydrological conditions.     

新疆沙尔湖煤田煤层特征及对比

沙尔湖煤田含煤地层为中侏罗统西山窑组,根据岩性特征、含煤性以及其组合特征,将西山窑组分为上、中、下三段,可采煤层均分布在中段,煤层层数多,厚度变化较大,可采煤层6～27层,可采煤层总厚114.35～139.90m,根据各煤层之间的沉积间距及其与上、下岩层的旋回韵律,又将其划分为Ⅰ、Ⅱ、Ⅲ煤组。以大量地质资料为基础,总结了主要含煤层段的岩相组合特点,揭示了各煤层间的差异及组合特征,利用有效的对比方法,特别是数字测井在煤层对比中的应用,对可采煤层进行系统对比分析,对煤层对比的可靠性进行评价,保证了层位对比的正确可靠,并解决了勘查工作中终孔层位难以确定的问题,为正确划分煤系地层、准确估算煤炭资源量提供了可靠依据。     

Biosorption of cadmium(II) from aqueous solution onto <Emphasis Type="Italic">Hydrilla verticillata</Emphasis>

Biosorption is an effective method to remove heavy metals from wastewater. In this work, the biosorption of Cd(II) onto Hydrilla verticillata was examined in aqueous solution with parameters of initial pH, adsorbent dosage, contact time, initial Cd(II) concentration, temperature, and co-existing ion. Linear Langmuir and Freundlich models were applied to describe the equilibrium isotherms, and both of the two models were fitted well. The monolayer adsorption capacity of Cd(II) was found to be 50 mg/g at pH 6 and 20°C. Dubinin–Radushkevich isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (11.18 kJ/mol) indicated that the adsorption of Cd(II) onto H. verticillata might be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, including free energy (∆G ⁰), enthalpy (∆H ⁰), and entropy (∆S ⁰) of adsorption, were also calculated. These results showed that the biosorption of Cd(II) onto H. verticillata was a feasible, spontaneous, and exothermic process in nature. Desorption experiments indicated that 0.01 mol/L EDTA and HNO₃ were efficient desorbents for the recovery of Cd(II) from biomass. IR spectrum analysis suggested that amido, hydroxyl, C=O and C–O could combine strongly with Cd(II). EDX spectrum analysis suggested that an ion exchange mechanism might be involved.